1.
Angew Chem Int Ed Engl
; 38(11): 1632-1634, 1999 Jun 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29710973
RESUMO
Encapsulated in a protective [{Fe(pz)3 }4 ] outer layer, which provides the complex with structural stability, the octanuclear complex [Fe8 (µ4 -O)4 (µ-pz)12 Cl4 ] contains a Fe4 O4 core (see drawing) that withstands four consecutive reversible one-electron reductions. Iron-oxygen clusters are shown to possess redox properties which rival those of their better studied iron-sulfur analogues. pz=pyrazolate anion.