RESUMO
Spatial predictions of drift deposits on soil surface were conducted using eight different spatial interpolation methods i.e. classical approaches like the Thiessen method and kriging, and some advanced methods like spatial vine copulas, Karhunen-Loève expansion and INLA. In order to investigate the impact of the number of locations on the prediction, all spatial predictions were conducted using a set of 39 and 47 locations respectively. The analysis revealed that taking more locations into account increases the accuracy of the prediction and the extreme behavior of the data is better modeled. Leave-one-out cross-validation was used to assess the accuracy of the prediction. The Thiessen method has the highest prediction errors among all tested methods. Linear interpolation methods were able to better reproduce the extreme behavior at the first meters from the sprayed border and exhibited lower prediction errors as the number of data points increased. Especially the spatial copula method exhibited an obvious increase in prediction accuracy. The Karhunen-Loève expansion provided similar results as universal kriging and IDW, although showing a stronger change in the prediction as the number of locations increased. INLA predicted the pesticide dispersion to be smooth over the whole study area. Using Delaunay triangulation of the study area, the total pesticide concentration was estimated to be between 2.06% and 2.97% of the total Uranine applied. This work is a first attempt to completely understand and model the uncertainties of the mass balance, therefore providing a basis for future studies.
Assuntos
Poluentes Atmosféricos/análise , Praguicidas/análise , Poluentes do Solo/análise , Solo/química , Colômbia , Monitoramento Ambiental/métodos , Modelos Teóricos , Análise EspacialRESUMO
The adsorption-desorption, hysteresis phenomenon, and leachability of tebuconazole were studied for Inceptisol and Histosol soils at the surface (0-10 cm) and in the subsurface (40-50 cm) of an agricultural region from Colombia by the batch-equilibrium method and mathematical approaches. The experimental Kfa and Kd (L kg-1) values (7.9-289.2) decreased with depth for the two Inceptisols and increased with depth for the Histosol due to the organic carbon content, aryl and carbonyl carbon types. Single-point and desorption isotherms depended on adsorption reversibility and suggested that tebuconazole showed hysteresis; which can be adequately evaluated with the single-point desorption isotherm and the linear model using the hysteresis index HI. The most suitable mathematical approach to estimate the adsorption isotherms of tebuconazole at the surface and in the subsurface was that considering the combination of the n-octanol-water partition coefficient, pesticide solubility, and the mass-balance concept. Tebuconazole had similar moderate mobility potential as compared with the values of other studies conducted in temperate amended and unamended soils, but the risk of the fungicide to pollute groundwater sources increased when the pesticide reached subsurface soil layers, particularly in the Inceptisols.
Assuntos
Adsorção , Modelos Teóricos , Poluentes do Solo/análise , Solo , Triazóis/química , 1-Octanol , Agricultura , Colômbia , Fungicidas Industriais/análise , Fungicidas Industriais/química , Hidrocarbonetos , Praguicidas , Poluentes do Solo/química , Poluentes do Solo/isolamento & purificação , Solubilidade , Triazóis/isolamento & purificaçãoRESUMO
This paper presents an integrative and spatially explicit modeling approach for analyzing human and environmental exposure from pesticide application of smallholders in the potato-producing Andean region in Colombia. The modeling approach fulfills the following criteria: (i) it includes environmental and human compartments; (ii) it contains a behavioral decision-making model for estimating the effect of policies on pesticide flows to humans and the environment; (iii) it is spatially explicit; and (iv) it is modular and easily expandable to include additional modules, crops, or technologies. The model was calibrated and validated for the Vereda La Hoya and was used to explore the effect of different policy measures in the region. The model has moderate data requirements and can be adapted relatively easily to other regions in developing countries with similar conditions.
Assuntos
Agricultura , Exposição Ocupacional/análise , Praguicidas/análise , Agricultura/instrumentação , Agricultura/métodos , Poluentes Atmosféricos/análise , Colômbia , Fazendeiros/estatística & dados numéricos , Humanos , Modelos Teóricos , Poluentes do Solo/análise , Solanum tuberosum/crescimento & desenvolvimento , Recursos HumanosRESUMO
Offsite pesticide losses in tropical mountainous regions have been little studied. One example is measuring pesticide drift soil deposition, which can support pesticide risk assessment for surface water, soil, bystanders, and off-target plants and fauna. This is considered a serious gap, given the evidence of pesticide-related poisoning in those regions. Empirical data of drift deposition of a pesticide surrogate, Uranine tracer, within one of the highest potato-producing regions in Colombia, characterized by small plots and mountain orography, is presented. High drift values encountered in this study reflect the actual spray conditions using hand-held knapsack sprayers. Comparison between measured and predicted drift values using three existing empirical equations showed important underestimation. However, after their optimization based on measured drift information, the equations showed a strong predictive power for this study area and the study conditions. The most suitable curve to assess mean relative drift was the IMAG calculator after optimization.
Assuntos
Agricultura/métodos , Poluentes Atmosféricos/análise , Praguicidas/análise , Poluentes do Solo/análise , Agricultura/instrumentação , Colômbia , Fazendeiros/estatística & dados numéricos , Controle de Insetos , Solanum tuberosum/crescimento & desenvolvimento , Recursos HumanosRESUMO
Quantifying dermal exposure to pesticides in farming systems in developing countries is of special interest for the estimation of potential health risks, especially when there is a lack of occupational hygiene regulations. In this paper we present the results of a dermal exposure assessment for the potato farming system in the highlands of Colombia, where farmers apply pesticides with hand pressure sprayers without any personal protective equipment. The fractioning of the pesticide, in terms of potential and actual dermal exposure, was determined via the whole-body dosimetry methodology, using the tracer uranine as pesticide surrogate, and luminescence spectrometry as analytical method. We assessed the three activities involved in pesticide management: preparation, application, and cleaning; analyzed three types of nozzles: one with a standard discharge and two modified by farmers to increase the discharge; and derived the protection factor given by work clothing. Our results suggest that to reduce the health risk, three aspects have to be considered: (i) avoiding the modification of nozzles, which affects the droplet size spectrum and increases the level of dermal exposure; (ii) using adequate work clothing made of thick fabrics, especially on the upper body parts; and (iii) cleaning properly the tank sprayer before the application activity.
Assuntos
Agricultura/instrumentação , Poluentes Ambientais/toxicidade , Exposição Ocupacional , Praguicidas/toxicidade , Medição de Risco , Pele/efeitos dos fármacos , Adulto , Agricultura/métodos , Colômbia , Países em Desenvolvimento , Monitoramento Ambiental , Poluentes Ambientais/análise , Poluentes Ambientais/química , Fluoresceína/química , Humanos , Exposição Ocupacional/prevenção & controle , Praguicidas/análise , Praguicidas/química , Roupa de Proteção , Pele/química , Solanum tuberosum , Análise EspectralRESUMO
Earthworm avoidance behaviour test is an important screening tool in soil eco-toxicology. This test has been developed and validated under North American and European conditions. However, little research has been performed on the avoidance test in the tropics. This work demonstrates the potential suitability of the avoidance behaviour test as screening method in the highlands of Colombia using Eisenia fetida as the bio-indicator species on contaminated soils with carbofuran and chlorpyrifos. Though for the two active ingredients 100% avoidance was not reached, a curve with six meaningful concentrations is provided. No significant avoidance behaviour trend was found for mancozeb and methamidophos. Tests were conducted in the field yielded similar results to the tests carried out in the laboratory for chlorpyrifos and mancozeb. However, for the case of carbofuran and methamidophos, differences of more than double in avoidance were obtained. Divergence might be explained by soil and temperature conditions.