RESUMO

A selective route for the degradation of the unsaturated side chain of ent-labdanes has been devised, giving two useful synthons: 2beta-acetoxy-14,15,17-trinor-ent-labdane-8,13- dione (5) and 2beta-acetoxy-14,15-dinor-ent-labd-8(17)-en-13-one (7), the use of which for the preparation of terpenylquinone derivatives shall be reported elsewhere.

Assuntos

Diterpenos/química , Diterpenos/metabolismo , Scrophulariaceae/química , Ressonância Magnética Nuclear Biomolecular , Oxirredução