RESUMO

In this study, we have described a miniaturized, simple, and low-cost device for sulfite determination in beverages by coupling Gas Diffusion Microextraction to paper-based analytical devices. The color change of an acid-base indicator - promoted by the generated gaseous SO2 - impregnated onto the paper surface was monitored in the function of time by video recording using a smartphone. The analytical information was related to the Hue, Saturation, Value (HSV) color space extracted from the video file. The complete analytical platform was built using a 3D printer, allowing the easy fabrication of a low-cost tailored device. Under optimized conditions, a linear relation from 5 to 90 mg L-1 was obtained using 30 µL of the reagent, 1 mL of sample, and 10 min of analysis. The relative standard deviation and the limit of detection were 2.2 % and 1.6 mg L-1, respectively. The method was successfully employed in several beverages, such as juices, soda, and coconut water.

Assuntos

Bebidas , Bebidas Gaseificadas , Bebidas/análise , Bebidas Gaseificadas/análise , Smartphone , Sulfitos/análise , Impressão Tridimensional

RESUMO

Colorimetric techniques have been developed and used in routine analyses for over a century and apparently all their potentialities have been exhaustively explored. However, colorimetric techniques have gained high visibility in the last two decades mainly because of the development of the miniaturization concept, for example, paper-based analytical devices that mostly employ colorimetric reactions, and by the advances and popularity of image capture instruments. The impressive increase in the use of these devices was followed by the development and enhancement of different modes of color detection to meet the demands of making qualitative, semi-quantitative, and fully quantitative analyses of multiple analytes. Cameras, scanners, and smartphones are now being used for this purpose and have become suitable alternatives for different approaches to colorimetric analysis; this, in addition to advancements in miniaturized devices. On the other hand, recent developments in optoelectronics technologies have launched more powerful, more stable and cheaper light-emitting diodes (LEDs), which once again have become an interesting tool for the design of portable and miniaturized devices based on colored reactions. Here, we present a critical review of recent developments and challenges of colorimetric detection in modern analytical chemistry in the last five years, and present thoughts and insights towards future perspectives in the area to improve the use of colorimetric detection in different application approaches.