RESUMO
Polymeric waste is an environmental problem, with an annual world production of approximately 368 million metric tons, and increasing every year. Therefore, different strategies for polymer waste treatment have been developed, and the most common are (1) redesign, (2) reusing and (3) recycling. The latter strategy represents a useful option to generate new materials. This work reviews the emerging trends in the development of adsorbent materials obtained from polymer wastes. Adsorbents are used in filtration systems or in extraction techniques for the removal of contaminants such as heavy metals, dyes, polycyclic aromatic hydrocarbons and other organic compounds from air, biological and water samples. The methods used to obtain different adsorbents are detailed, as well as the interaction mechanisms with the compounds of interest (contaminants). The adsorbents obtained are an alternative to recycle polymeric and they are competitive with other materials applied in the removal and extraction of contaminants.
Assuntos
Poluentes Ambientais , Poluentes Químicos da Água , Purificação da Água , Polímeros , Corantes , Adsorção , Purificação da Água/métodosRESUMO
A magnetic solid phase extraction technique followed by liquid chromatography with a fluorescence detector for naproxen analysis in human urine samples was developed. The method includes the extraction of naproxen with a magnetic solid synthetized with magnetite and poly 4-vinylpriridine, followed by the magnetic separation of the solid phase and desorption of the analyte with methanol. Under optimal conditions, the linear range of the calibration curve was 0.05-0.60 µg L-1, with a limit of detection of 0.02 µg L-1. In all cases values of repeatability were lower than 5.0% with recoveries of 99.4 ± 1.3%. Precision and accuracy values are adequate for naproxen (Npx) analysis in urine samples.
Assuntos
Cromatografia Líquida de Alta Pressão/métodos , Magnetismo , Naproxeno/urina , Polímeros/química , Polivinil/química , Extração em Fase Sólida/métodos , HumanosRESUMO
A method is presented for magnetic solid phase extraction of tartrazine from nonalcoholic beverages. The method involves the extraction and clean-up by activated carbon covered with magnetite dispersed in the sample, followed by the magnetic isolation and desorption of the analyte by basified methanol. The tartrazine eluted from the magnetic support was determined by spectrophotometry. Under optimal conditions, the linear range of the calibration curve ranges from 3 to 30 mg L(-1), with a limit of detection of 1 mg L(-1). The method was validated by comparing the results with those obtained by HPLC. A precision of <5.0% was obtained in all cases and no significant differences were observed (P < 0.05).