RESUMO
The interaction of external noise with an electrochemical oscillator (anodic dissolution of iron) has been studied experimentally on both sides of the homoclinic bifurcation. In the oscillatory regime the regularity of the limit cycle behavior was destroyed with increasing noise amplitude until no periodicity was observable any more. In contrast, the response of the excitable state (fixed point regime) became more regular at intermediate noise levels.
RESUMO
We describe the generation of new limit cycles in electrochemical systems under the influence of external periodic perturbations. For certain specific parameters of a nonharmonic forcing function, two coexisting periodic orbits can be generated from a single limit cycle observed in the unperturbed dynamics. This inception of birhythmicity (bistability) is observed in both simulations and actual experiments involving potentiostatic electrodissolution of copper in an acetate buffer.