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1.
Sci Total Environ ; 651(Pt 1): 250-260, 2019 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-30236842

RESUMO

The present dominant trend of retreating and shrinking glaciers is leading to the formation of new soil in proglacial zones. The Cordillera Blanca located in the Peruvian Andes includes the Lake Parón catchment known for the Artesonraju Glacier and its rapid retreat, forming the largest proglacial lake in the region. This work aims to gain knowledge of soil and vegetation development on the most representative proglacial landforms existing in the Parón catchment. Previous research in proglacial environments suggests that soil properties might indicate different ages of ice retreat besides the normalised difference vegetation index (NDVI), which is known to be a powerful tool for assessing vegetation development. In the area surrounding Lake Parón up to the glacier tongue, an altitudinal transect (4200-4700 m a.s.l.) was established for sampling topsoils. A total of 40 surface soil samples (0-3 cm) were collected from the main glacial landforms, moraines, colluvium, glacio-fluvial terraces and alluvial fans, developed after different stages of glacier retreat. Soil organic carbon (SOC) and SOC fractions (active and stable), total nitrogen (TN) and 137Cs were analysed. A multitemporal analysis of NDVI was performed to assess the vegetation dynamics in the Parón catchment and over the different glacial landforms over time (1987-2018). The NDVI increase in recent decades indicates an expansion of vegetation cover and density. We compared NDVI values with the SOC and TN content to assess the relationships with vegetation growth in mountain soils. NDVI and the distribution of SOC and TN content show a positive correlation between vegetation evolution and the enrichment in soil nutrients that are more abundant in older moraines in coincidence with highest NDVI. These results outline the effect of shrinking mountain glaciers on generating new soils in parallel with the growth of vegetation.

2.
Environ Sci Pollut Res Int ; 25(21): 20868-20879, 2018 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-29766420

RESUMO

Identification of hot spots of land degradation is strongly related with the selection of soil tracers for sediment pathways. This research proposes the complementary and integrated application of two analytical techniques to select the most suitable fingerprint tracers for identifying the main sources of sediments in an agricultural catchment located in Central Argentina with erosive loess soils. Diffuse reflectance Fourier transformed in the mid-infrared range (DRIFT-MIR) spectroscopy and energy-dispersive X-ray fluorescence (EDXRF) were used for a suitable fingerprint selection. For using DRIFT-MIR spectroscopy as fingerprinting technique, calibration through quantitative parameters is needed to link and correlate DRIFT-MIR spectra with soil tracers. EDXRF was used in this context for determining the concentrations of geochemical elements in soil samples. The selected tracers were confirmed using two artificial mixtures composed of known proportions of soil collected in different sites with distinctive soil uses. These fingerprint elements were used as parameters to build a predictive model with the whole set of DRIFT-MIR spectra. Fingerprint elements such as phosphorus, iron, calcium, barium, and titanium were identified for obtaining a suitable reconstruction of the source proportions in the artificial mixtures. Mid-infrared spectra produced successful prediction models (R2 = 0.91) for Fe content and moderate useful prediction (R2 = 0.72) for Ti content. For Ca, P, and Ba, the R2 were 0.44, 0.58, and 0.59 respectively.


Assuntos
Agricultura , Monitoramento Ambiental/métodos , Sedimentos Geológicos/química , Solo/química , Argentina , Calibragem , Monitoramento Ambiental/instrumentação , Poluentes do Solo/análise , Espectroscopia de Infravermelho com Transformada de Fourier
3.
Sci Total Environ ; 618: 1114-1124, 2018 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-29055595

RESUMO

Land degradation is a problem affecting the sustainability of commercial forest plantations. The identification of critical areas prone to erosion can assist this activity to better target soil conservation efforts. Here we present the first use of the carbon-13 signatures of fatty acids (C14 to C24) in soil samples for spatial and temporal tracing of sediment transport in river bodies of upland commercial forest catchments in Chile. This compound-specific stable isotope (CSSI) technique was tested as a fingerprinting approach to determine the degree of soil erosion in pre-harvested forest catchments with surface areas ranging from 12 to 40ha. For soil apportionment a mixing model based on a Bayesian inference framework was used (CSSIAR v.2.0). Approximately four potential sediment sources were used for the calculations of all of the selected catchments. Unpaved forestry roads were shown to be the main source of sediment deposited at the outlet of the catchments (30-75%). Furthermore, sampling along the stream channel demonstrated that sediments were mainly comprised of sediment coming from the unpaved roads in the upper part of the catchments (74-98%). From this it was possible to identify the location and type of primary land use contributing to the sediment delivered at the outlet of the catchments. The derived information will allow management to focus efforts to control or mitigate soil erosion by improving the runoff features of the forest roads. The use of this CSSI technique has a high potential to help forestry managers and decision makers to evaluate and mitigate sources of soil erosion in upland forest catchments. It is important to highlight that this technique can also be a good complement to other soil erosion assessment and geological fingerprinting techniques, especially when attempting to quantify (sediment loads) and differentiate which type of land use most contributes to sediment accumulation.

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