RESUMO
This work conducted experimental combustion on a closed chamber using two different materials: mixture (1:1) sugarcane bagasse/straw and pre-treated biomass. The sampling method was an Andersen cascade impactor with eight stages. Tests were carried out on untreated biomass varying the velocities observed in the sampling duct (4.18; 5.20, 6.85, and 8.21 m.s-1). Pre-treated biomass tests were performed at 4.19 m.s-1 because in this condition there is a higher speed stability inside the duct. During the combustion tests, the concentration of emitted particles was higher for the lower speed range, with an order of 4.19 > 5.40 > 6.85 > 8.21 m.s-1. The higher speeds observed inside the duct behaved as a dragging agent for particulate material. For the tests at the speed of 8.21 m.s-1 where the flow inside the duct was 0.088 m3s-1, this behavior is more evident. Considering the fine diameter particles (< 2.5 µm), they were emitted in a higher concentration, due to the biomass combustion process, which results in higher emission of ultrafine particles. The emission factors (EFs) obtained for PM10 for untreated biomass were in the range of 0.414 and 0.840. On the other hand, considering the pre-treated biomass, these factors were 0.70 and 1.51. The EFs of PM from the burning of the pre-treated biomass were higher when compared to untreated biomass, which is mainly due to the higher temperature of the process due to the higher HHV (higher heating value) of this material, caused by the removal of hemicellulose (4.71 times) and a proportional increase in lignin (1.52 times). Biomass combustion has the potential to partially replace fossil fuels in heat and energy generation. Nevertheless, more stringent and comprehensive legislation should be established to ensure that air quality is maintained. Furthermore, the emission factors obtained in this study might be useful as input data for air quality modeling in the context of sugarcane's burning biomass, thus, contributing to the generation of inventories that include emissions of this nature.
Assuntos
Poluentes Atmosféricos , Saccharum , Poluentes Atmosféricos/análise , Celulose , Material Particulado/análise , BiomassaRESUMO
Energy demand has increased worldwide, and biomass burning is one of the solutions most used by industries, especially in countries that have a great potential in agriculture, such as Brazil. However, these energy sources generate pollutants, consisting of particulate matter (PM) with a complex chemical composition, such as sugarcane bagasse (SB) burning. Controlling these emissions is necessary; therefore, the aim was to evaluate PM collection using a rectangular Venturi scrubber (RVS), and its effects on the composition of the PM emitted. Considering the appropriate use of biomass as an industrial fuel and the emerging need for a technique capable of efficiently removing pollutants from biomass burning, this study shows the control of emissions as an innovation in a situation such as the industrial one with the use of a Venturi scrubber in fine particle collection, in addition to using portable and representative isokinetic sampling equipment of these particles. The pilot-scale simulation of the biomass burning process, the representative sampling of fine particles and obtaining parameters to control pollutant emissions for a Venturi scrubber, meets the current situation of concern about air quality. The average collection efficiency values were 96.6% for PM> 2.5, 85.5% for PM1.0-2.5, and 66.9% for PM< 1.0. The ionic analysis for PM< 1.0 filters showed potassium, chloride, nitrate, and nitrite at concentrations ranging from 20.12 to 36.5 µg/m3. As the ethanol and sugar plants will continue to generate electricity with sugarcane bagasse burning, emission control technologies and cost-effective and efficient portable samplers are needed to monitor particulate materials and improve current gas cleaning equipment projects.
Assuntos
Poluentes Atmosféricos , Poluição do Ar , Poluentes Ambientais , Saccharum , Material Particulado/análise , Poluentes Atmosféricos/análise , Celulose/análise , Biomassa , Tamanho da Partícula , Poluição do Ar/análise , Poluentes Ambientais/análise , Monitoramento AmbientalRESUMO
The rate of deforestation in Brazil increased by 29% between 2015 and 2016, resulting in an increase of greenhouse gas emissions (GHG) of 9%. Deforestation fires in the Amazonia are the main source of GHG in Brazil. In this work, amounts of CO2, CO, main hydrocarbon gases and PM2.5 emitted during deforestation fires, under real conditions directly in Brazilian Amazonia, were determined. A brief discussion of the relationship between the annual emission of CO2 equivalent (CO2,eq) and Paris Agreement was conducted. Experimental fires were carried out in Western Amazonia (Candeias do Jamari, Rio Branco and Cruzeiro do Sul) and results were compared with a previous fire carried out in Eastern Amazonia (Alta Floresta). The average total fresh biomass on the ground before burning and the total biomass consumption were estimated to be 591 ton ha-1 and 33%, respectively. CO2, CO, CH4, and non-methane hydrocarbon (NMHC) average emission factors, for the four sites, were 1568, 140, 8, and 3â¯gâ¯kg-1 of burned dry biomass, respectively. PM2.5 showed large variation among the sites (0.9-16â¯gâ¯kg-1). Emissions per hectare of forest were estimated as 216,696â¯kg of CO2, 18,979â¯kg of CO, 1,058â¯kg of CH4, and 496â¯kg of NMHC. The average annual emission of equivalent CO2 was estimated as 301⯱â¯53â¯Mtâ¯year-1 for the Brazilian Amazonia forest. From 2013, the estimated CO2,eq showed a trend to increase in Amazon region. The present study is an alert and provides important information that can be used in the development of the public policies to control emissions and deforestation in the Brazilian Amazonia.
Assuntos
Poluentes Atmosféricos/análise , Monitoramento Ambiental , Incêndios Florestais , Biomassa , Brasil , Dióxido de Carbono/análise , Monóxido de Carbono/análise , Conservação dos Recursos Naturais , Incêndios , Florestas , Gases/análise , Hidrocarbonetos/análise , Metano/análise , Material Particulado/análise , Estações do AnoRESUMO
Two different types of typical Brazilian forest biomass were burned in the laboratory in order to compare their combustion characteristics and pollutant emissions. Approximately 2 kg of Amazon biomass (hardwood) and 2 kg of Araucaria biomass (softwood) were burned. Gaseous emissions of CO2, CO, and NOx and particulate matter smaller than 2.5 µm (PM2.5) were evaluated in the flaming and smoldering combustion phases. Temperature, burn rate, modified combustion efficiency, emissions factor, and particle diameter and concentration were studied. A continuous analyzer was used to quantify gas concentrations. A DataRam4 and a Cascade Impactor were used to sample PM2.5. Araucaria biomass (softwood) had a lignin content of 34.9%, higher than the 23.3% of the Amazon biomass (hardwood). CO2 and CO emissions factors seem to be influenced by lignin content. Maximum concentrations of CO2, NOx and PM2.5 were observed in the flaming phase.