RESUMO
Phytoextraction of Nickel (II) in water by two types of aquatic macrophytes (Lemna minor and Eichhornia crassipes) was investigated using synthetic aqueous solutions of NiSO4 at concentrations of 0.5, 1.5 and 2.5 mg/L. The toxic effects of nickel salt in plants were evaluated through the presence of necrosis and chlorosis. The bioconcentration factor, Nickel (II) removal efficiency and kinetics of removal were also calculated. Results of this study show bioconcentration factors higher than 1000, which categorize L. minor and E. crassipes as hyperaccumulators. Besides, L. minor presented a removal percentage higher than 68%, compared to E. crassipes that did not exceed 50% in any of the three concentrations studied. However, E. crassipes showed better resistance to the effects of nickel and obtained a greater removal capacity during the phytoremediation process that lasted for 10 days. In contrast, L. minor suffered necrosis and chlorosis in a concentration-dependent way. Consequently, both macrophytes are sustainable alternatives for nickel removal from contaminated water.
Assuntos
Anemia Hipocrômica , Araceae , Eichhornia , Poluentes Químicos da Água , Biodegradação Ambiental , Níquel , Água , Poluentes Químicos da Água/toxicidade , Poluentes Químicos da Água/análise , Monitoramento AmbientalRESUMO
Enhancing the thermal comfort of low-income housing in developing countries located in tropical areas is one of the main challenges for engineers and architects worldwide. The coconut mesocarp fibre (coir) has shown enormous potential for improving some properties of modified concretes or mortars, such as low-weight and high-acoustic isolation. In this study, the potential use of modified mortars by coconut fibres as a facade coating layer to enhance thermal comfort in low-income housing structures was evaluated for the city of Cartagena de Indias, Colombia. An actual typical low-income house of 42 m2 was monitored. Temperature and humidity variations were monitored for 39 days, thermal characteristics of coir-modified mortars were also investigated using differential scanning calorimetry (DSC) and an adaptation of the standard test method of the guarded-hot-cartridge apparatus. The EnergyPlus™ software was used to simulate indoor temperature variations in the studied house. Results show that during the period of 4 h of maximum sunlight radiation with outdoor temperatures in the range of 29-34 °C, coating the cement-sand hollow block structure with a layer of coir-modified mortar could reduce indoor room temperatures by 0.5-1.5 °C, approximately. Thus, there is a potential to enhance the thermal comfort in low-income housing structures with coconut fibre modified mortars while reducing annual energy costs of cooling by 16%, making it affordable for low-income families in the Caribbean region of Colombia.
Assuntos
Cocos , Habitação , Região do Caribe , Cidades , ColômbiaRESUMO
Constructed wetlands have become an attractive alternative for wastewater treatment. However, there is not a globally accepted mathematical model to predict their performance. In this study, the VS2DTI software was used to predict the effluent biochemical oxygen demand (BOD) and total nitrogen (TN) in a pilot-scale vertical flow constructed wetland (VFCW) treating domestic wastewater. After a 5-week adaptation period, the pilot system was monitored for another 6 weeks. Experiments were conducted at hydraulic retention times (HRTs) in the range of 2-4 days with Typha latifolia as the vegetation. The raw wastewater concentrations ranged between 144-430 and 122-283 mg L(-1) for BOD5 and TN, respectively. A first-order kinetic model coupled with the advection/dispersion and Richards' equations was proposed to predict the removal rates of BOD5 and TN from domestic wastewater. Two main physical processes were modeled in this study, porous material water flow and solute transport through the different layers of the VFCW to simulate the constructed wetland (CW) conditions. The model was calibrated based on the BOD5 and TN degradation constants. The model indicated that most of BOD and TN (88 and 92%, respectively) were removed through biological activity followed by adsorption. It was also observed that the evapotranspiration was seen to have a smaller impact. An additional data series of effluent BOD and TN was used for model validation. The residual analysis of the calibrated model showed a relatively random pattern, indicating a decent fit. Thus, the VS2DTI was found to be a useful tool for CW simulation.