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Nowadays, there is still a scientific knowledge gap regarding occurrence and distribution of organic contaminants in remote areas. In this study, we have monitored for the first time the presence of a wide range of persistent and emerging organic pollutants in the Atacama Desert coastal region (Chile), a key area in the Humboldt Current System. Nonylphenols (NPs), polycyclic aromatic hydrocarbons (PAHs), pesticides, UV filters, synthetic fragrances, and organophosphate flame retardants (OPFRs) were determined in sediments along the >500 km length Atacama coastline. NPs, well-known endocrine disruptors, were the predominant pollutants in the area (up to 333.5 ng g-1 dw). We identified inputs of different classes of contaminants from anthropogenic activities such as mining, agriculture, direct effluent discharges, harbors, energy plants, recreational activities, and tourism occurring along the coastline. Environmental risk assessment through calculation of hazard quotients (HQs) showed a high ecological risk level for NPs in the three provinces of Atacama (HQ >1). In the case of PAHs, (pyrene, benz(a)anthracene, chrysene, acenaphthene, naphthalene and benzo(a)pyrene) HQ >1 was showed in Copiapó province. Furthermore, estradiol equivalent concentrations (EEQ) were determined to estimate estrogenicity of the environmental sediment samples. The maximum EEQ value was for NPs in H1 (Carrizal Bajo wetland), province of Huasco, where the highest concentration of NPs was found. The sampling point H1 is a particular location because it is the exit of a wetland and a tourist point used as a beach. The potential risks of anthropogenic chemical substances impacting remote regions such as the one studied here highlight the need of expand monitoring efforts worldwide for a better assessment of the global pollution status.

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Learning techniques involve unraveling regression structures, which aim to analyze in a probabilistic frame the associations across variables of interest. Thus, analyzing fraction and/or proportion data may not be adequate with standard regression procedures, since the linear regression models generally assume that the dependent (outcome) variable is normally distributed. In this manner, we propose a statistical model called unit-Lindley regression model, for the purpose of Statistical Process Control (SPC). As a result, a new control chart tool was proposed, which targets the water monitoring dynamic, as well as the monitoring of relative humidity, per minute, of Copiapó city, located in Atacama Desert (one of the driest non-polar places on Earth), north of Chile. Our results show that variables such as wind speed, 24-hour temperature variation, and solar radiation are useful to describe the amount of relative humidity in the air. Additionally, Information Visualization (InfoVis) tools help to understand the time seasonality of the water particle phenomenon of the region in near real-time analysis. The developed methodology also helps to label unusual events, such as Camanchaca, and other water monitoring-related events.

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Ocean contamination mostly comes from anthropogenic contamination in watercourses. However, what happens in desert areas where watercourses are few or nonexistent? Are these coastal areas exempt from contamination? Do the remote locations of desert areas enable pristine coastal areas? Atacama is widely known for its desert aridity and mining resources; however, human impacts in its coastal areas have not been widely studied. Coastal zone uses of this region of Chile were analyzed per province in relation to the population settlements and economic activities on the coastal edge. This study includes a review of the contamination in this desert coastal area in relation to the territorial organization, activities, and land uses. The results determined that most of the coastal edge was used for fishing and aquaculture (52%) and for conservation and protected areas (39%). However, 2% of the coastal edge was susceptible to conflicts due to shared uses. A strong lack of scientific research was detected despite environmental interest (Humboldt Current, diversity hot spots, desert blooming, algae kelps, protected areas, etc.) and economic development (impact of mining, agriculture and tourism) in the area. Most studies focused on metal concentrations in aquatic environments in the north part of the region. Studies on emerging contaminants have not been carried out in the area despite intense human settlement.

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Water fog composition was investigated at a fog harvesting installation in the coast of Atacama (North Chile). Chañaral is historically affected by mining contamination discharges. Hydro-chemical characterization of fog water from top of the mountain (where capture installation is located) and at the bottom of the mountain (after vertical transportation where an aquaponic system is located) revealed many compositional differences that compromise the use of water. High acidity and high concentrations in Cu and As in water collected on top of the mountain were found; meanwhile, acidity and Cu decreased, and As levels overpassed the drinking water standards after the vertical transportation. Collected data was assessed according to national and international regulatory standards, neutralization factors (NF), sodium adsorption ratio (SAR), and ion ratios to determine origin of contamination and suitability of destined for human consumption, irrigation, or aquaculture purposes.

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The Ribeira de Iguape River (Southeast Brazil) is metal contaminated by mining activities. Despite it has been cataloged as "in via of restoration" by the literature, this basin is still a sink of pollution in some segments of the fluvial system. This study aimed to assess the sediment quality in the lower part of the RIR basin. The employed approach was based on biological responses of the freshwater clam Corbicula fluminea after 7-day exposure bioassays using as the reference site the Perequê Ecological Park. Toxic responses (burial activity and lethality) and biochemical biomarkers (GST, GR, GPx, LPO, MTs, AChE and DNA damage) were evaluated and then integrated with metal bioavailability and chemical concentrations to address the sediment quality in the area through the weight-of-evidence approach. A multivariate analysis identified linkages between biological responses and contamination. Results pointed that, despite being below the benchmarks of the US Environmental Protection Agency, there is slight metal contamination in the lower part of the basin which induces oxidative stress in C. fluminea; other toxic responses were sometimes attributed to As and Cr bioaccumulation. The sediment quality values (TEL-PEL values in mg/kg) were calculated for the current study for As (0.63-1.31), Cr (3.5-11.05), Cs (1.0-1.17), Cu (6.32-7.32), Ni (6.78-7.46), Ti (42.0-215), V (1.77-8.00). By comparison with other international guidelines, the sediment quality of the lower basin of the Vale de Ribeira does not identify a significant environmental risk.

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The sediment quality of Ribeira de Iguape River is affected by former Pb extraction mining. Some studies affirm the restoration status of the basin, however, mobility of metals and its associated risk is still questioned. This study integrates the metal concentrations in the lower part of the basin with different contamination source to determine the existence of risks associated with the mobile fractions of the geochemical matrix. Despite concentrations of metals were low and the environmental risk factor values were negative, our results indicated that As, Mn, Pb, and V were present in the most labile forms. The multivariate analysis conducted using metal concentrations, environmental risk factor values and speciation suggested that any risk would be associated with the labile fractions of the analyzed elements, especially for Pb. The station from Registro was stressed by Co, Pb and Zn; with Pb under the reactive fraction that could be associated with high mobility and potential bioavailability.

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