RESUMO
Rate coefficients of the O3-initiated oxidation of allyl methyl sulfide (H2CâCHCH2SCH3, AMS) and allyl ethyl sulfide (H2CâCHCH2SCH2CH3, AES) were determined at atmospheric conditions by "in situ" FTIR. The relative kinetic experiments were performed using methylcyclohexane (McH) and carbon monoxide (CO) as nascent OH radical scavengers and in the absence of any scavenger, to determine the impact that the formation of OH radicals has on the rate coefficients. In the absence of scavengers, values of kAMS+O3 = (5.23 ± 3.57) × 10-18 and kAES+O3 = (5.76 ± 1.80) × 10-18 cm3 molecule-1 s-1 were obtained. In the presence of the scavengers, however, the rates decreased to kAMS+O3+McH = (3.92 ± 1.92) × 10-18 and kAMS+O3+CO = (2.63 ± 0.47) × 10-18 cm3 molecule-1 s-1 for AMS, and kAES+O3+McH = (4.78 ± 1.38) × 10-18 and kAES+O3+CO = (3.50 ± 0.27) × 10-18 cm3 molecule-1 s-1 for AES. On the basis of these results, we have decided to recommend the values obtained using CO as scavenger as those best representing the rate coefficient for the reactions of O3 with AMS and AES. The reaction mechanism was explored using DFT and post-Hartree-Fock computational methods. It is shown that the barrier for the common cyclization to primary ozonide (-3.7 ± 0.1 kcal mol-1) followed by other reactions, as well as that for the reaction with the sulfur atom (-5.1 ± 0.1 kcal mol-1), is small and quite close, meaning that both reaction paths should contribute significantly to the global reaction rate.