RESUMEN
In this study, the possibility of using sawdust, a by-product of primary wood processing, as a filler (WF) for rigid polyurethane (PUR) foams was investigated. The effects of the addition of 5, 10, 15 and 20% of WF particles to the polyurethane matrix on the foaming process, cell structure and selected physical-mechanical properties such as density, thermal conductivity, dimensional stability, water absorption, brittleness, compressive and bending strengths were evaluated. Based on the results, it was found that the addition of WF in the amount of up to 10% does not significantly affect the kinetics of the foam foaming process, allowing the reduction of their thermal conductivity, significantly reducing brittleness and maintaining high dimensional stability. On the other hand, such an amount of WF causes a slight decrease in the compressive strength of the foam, a decrease in its bending strength and an increase in water absorption. However, it is important that in spite of the observed decrease in the values of these parameters, the obtained results are satisfactory and consistent with the parameters of insulation materials based on rigid PUR foam, currently available on the market.
RESUMEN
This work was focused on evaluating the effects of polycarboxylic acid addition and retrogradation phenomenon on tribological performance, thermal, and mechanical properties of both, bioadhesives and sustainable panels. The rheological behavior of adhesives was affected by retrogradation, exhibiting formulations containing CA higher elastic modulus than those with BTCA, regardless of the acid concentration. With regard to tribomechanical properties, panels formulated with CA20 and BTCA80 adhesives presented the lower friction coefficient and wear degree. Thermocompression process induced a crosslinking reaction between wood fibers and starch-based adhesives, leading to more hydrophobic and thermally stable matrices in the presence of BTCA. The selection of the adhesive formulation depends on the moment of its use, since retrogradation limits its performance and that of the derived sustainable panels, being the adhesive CA20 more appropriate in freshly prepared formulations. Meanwhile, when the storage of the adhesive prepared in batch is required, the BTCA80 formulation would be more suitable. Thus, bioinspired materials can provide a valuable insight towards incorporating starch-based adhesives for wood applications.
Asunto(s)
Adhesivos/química , Materiales Biocompatibles/química , Almidón/química , Fenómenos Químicos , Ensayo de Materiales , Fenómenos Mecánicos , Análisis Espectral , TermogravimetríaRESUMEN
The objective of this work was to study Cr(VI) sorption/desorption on two by-products from the wood industry: pine sawdust and oak wood ash. The retention/release experiments were carried out using standard batch-type trials. In the sorption-phase experiments, pine sawdust showed 23% sorption when a concentration of 100 mg Cr(VI)L-1 was added, whereas sorption on oak wood ash was 17%. In the desorption-phase, chromium release was clearly higher from pine sawdust than from oak wood ash (98% and 66%, respectively). Sorption curves were well fitted to the Freundlich and Lineal models. In view of the results, both materials can be considered of very limited value to remove Cr from polluted soil and water, which can be of relevance regarding its appropriate use as biosorbents and recycled by-products.