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1.
Plants (Basel) ; 13(17)2024 Aug 28.
Artículo en Inglés | MEDLINE | ID: mdl-39273885

RESUMEN

A fungicide's ingredients can play a physiological role in crop water-management decisions. Our greenhouse study in 2021 demonstrated that Xyway LFR@FMC at-plant fungicide can significantly improve water-saving potential in corn. In 2022 and 2023, a field study was conducted to validate this finding. The 1.11 L ha-1 of Xyway LFR@FMC and no-fungicide/check were the main plot effects. Three water regimes, high (HI) and low (LO) numbers of irrigation events and rainfed (RF), were the subplot effect. Plants treated with Xyway LFR@FMC had significantly higher plant height, stem diameter, and leaf water potential (LWP), and had 11.9, 13.4, and 18.3% higher yield under RF, LO, and HI, respectively, in 2022. In 2023, there were no significant differences for the yield components and growth parameters when the combined effect of fungicide treatments and water regimes was considered. However, plants treated with the fungicide had a higher number of rows per ear, kernel number per row, and cob diameter compared to the check. There was no significant separation for yield among the water regimes in 2023, but the crop yield was overall higher for the fungicide-treated plots. Our results indicate that Xyway LFR@FMC fungicide has the potential to improve plant growth and protect the yield when limited water is applied.

2.
Isotopes Environ Health Stud ; : 1-17, 2024 Sep 03.
Artículo en Inglés | MEDLINE | ID: mdl-39225440

RESUMEN

Outcrops play an important role in groundwater recharge. Understanding groundwater origins, dynamics and its correlation with different water sources is essential for effective water resources management and planning in terms of quantity and quality. In the case of the Guarani Aquifer System (GAS) outcrop areas are particularly vulnerable to groundwater pollution due to direct recharge processes. This study focuses on the Alto Jacaré-Pepira sub-basin, a watershed near Brotas, a city in the central region of the state of São Paulo, Brazil, where groundwater is vital for supporting tourism, agriculture, urban water supply, creeks, river and wetlands. The area has a humid tropical climate with periods of both intense rainfall and drought, and the rivers remain perennial throughout the year. Therefore, the aim of this study is to investigate the interconnections between a spring and its potential sources of contribution, namely rain and groundwater, in order to elucidate the relationships between the different water sources. To achieve this, on-site monitoring of groundwater depth, rainfall amount, and stable isotope ratios (deuterium (2H) and oxygen-18 (18O)) from rain, spring discharge, and a monitoring well was carried out from 2013 to 2021. The results indicate that the mean and standard deviations for δ18O in rainwater exhibit higher variability, resulting in -4.49 ± 3.18 ‰ VSMOW, while δ18O values from the well show minor variations, similar to those of the spring, recording -7.25 ± 0.32 ‰ and -6.94 ± 0.28 ‰ VSMOW, respectively. The mixing model's outcomes reveal seasonal variations in water sources contribution and indicate that groundwater accounts for approximately 80 % of spring discharge throughout the year. Incorporating stable isotopes into hydrological monitoring provides valuable data for complementing watershed analysis. The values obtained support the significance of the aquifer as a primary source, thereby offering critical insights into stream dynamics of the region.

3.
Environ Monit Assess ; 196(10): 912, 2024 Sep 10.
Artículo en Inglés | MEDLINE | ID: mdl-39251525

RESUMEN

The Guanabara Bay hydrographic region (GBHR) has served as a central hub for human settlement and resource utilization throughout Brazil's history. However, the region's high population density and intense industrial activity have come at a cost, leading to a significant decline in water quality. This work aimed to identify homogeneous regions in GBHR according to water quality parameters in dry and rainy periods. The following water quality monitoring variables were monitored at 49 gauge stations: total phosphorus (TP), nitrate (NO3-), dissolved oxygen (DO), hydrogenionic potential (pH), turbidity (Turb), thermotolerant coliforms (TCol), total dissolved solids (TDS), biochemical oxygen demand (BOD), water temperature (Tw), and air temperature (Ta). The statistical analysis consisted of determining principal components, cluster analysis, seasonal differences, and Spearman's correlation. The water quality parameter correlations were not expressively influenced by seasonality, but there are differences in the concentrations of these parameters in the dry and rainy periods. In the dry period, urban pressure on water quality is mainly due to fecal coliforms. The resulting clusters delimited areas under urban, agricultural, and forestry influence. Clusters located in areas with high demographic density showed high concentrations of TCol and TP, while clusters influenced by forestry and agriculture had better water quality. In the rainy season, clusters with urban influence showed problems with TCol and TP, in addition to some characteristics in each group, such as high TDS, NO3-, and BOD. Forested areas showed high DO, and clusters under agricultural influence had higher concentrations of TCol, BOD, and NO3- concerning forested regions. The troubling state of sanitation in GBHR occurs in metropolitan regions due to lack of a formal sanitation system.


Asunto(s)
Monitoreo del Ambiente , Calidad del Agua , Brasil , Monitoreo del Ambiente/métodos , Bahías , Contaminantes Químicos del Agua/análisis , Fósforo/análisis , Nitratos/análisis , Estaciones del Año , Análisis Multivariante
4.
J Environ Manage ; 367: 122059, 2024 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-39098078

RESUMEN

This study addresses the ongoing debate concerning the environmental implications of cryptocurrencies. Specifically, it investigates the impact of Bitcoin trading volume on water and sanitation (Sustainable Development Goal (SDG) 6) and climate action (SDG 13). The research employs Ordinary Least Squares (OLS) panel data analysis to examine these relationships using a sample of 32 countries with available Bitcoin trading volume data from 2013 to 2020. The findings indicate that Bitcoin trading significantly and positively impacts progress towards SDG 6, suggesting potential benefits for water and sanitation initiatives. However, the study reveals a significant negative impact of higher Bitcoin trading volume on increased carbon emissions, underscoring the environmental costs associated with cryptocurrency activities. Similar impacts are observed for gold reserves, as their mining necessitates substantial energy consumption. These results highlight the need to regulate cryptocurrency trading and promote voluntary sustainable practices, particularly given the disparities between developed and emerging markets based on their governance frameworks. Additionally, the study considers the disparities between countries based on technology exports and economic policy uncertainty as influential determinants. The study's results emphasize the importance of proactive measures to ensure the responsible and sustainable use of cryptocurrencies. While cryptocurrencies offer significant economic returns, their early adoption stage necessitates further investigation into environmentally friendly approaches. Potential strategies include directing financial returns from cryptocurrencies towards alternative energy projects and supporting other environmental SDGs, thereby fostering a positive impact on the overall ecosystem. The study's implications extend to policymakers, regulators, and stakeholders, advocating for comprehensive and collaborative efforts to integrate sustainability into the rapidly evolving cryptocurrency market. This integration is crucial to ensure that the economic benefits of cryptocurrencies do not come at the cost of our environment.


Asunto(s)
Carbono , Desarrollo Sostenible , Conservación de los Recursos Naturales
5.
Sci Total Environ ; 951: 175420, 2024 Nov 15.
Artículo en Inglés | MEDLINE | ID: mdl-39128522

RESUMEN

Farm dams, also known as 'agricultural ponds', are ubiquitous features of agricultural landscapes globally. Those accessed by livestock have high methane (CH4) emissions per unit area relative to other freshwater systems. Fencing dams and installing water troughs to prevent livestock from entering the dams are promising strategies to improve water quality and substantially reduce their carbon footprints. However, previous studies only measured the effects of fencing on methane diffusive emissions without considering ebullitive fluxes (i.e., methane bubbles), which is often the dominant emission pathway in smaller water bodies. Also, data is lacking on how the benefits of fencing farm dams vary across seasons. Using Australia as a test case, this study investigates the benefit of fencing off farm dams by monitoring total CH4 (diffusion + ebullition) and carbon dioxide (CO2) in summer and winter. Fenced dams had 72 % lower CH4 emissions in summer and 92 % lower in winter than unfenced dams. Similarly, CO2-equivalent (CO2 + CH4) fluxes were lower in fenced dams by 59 % in summer and 73 % in winter. Fenced dams had higher water quality, with 51 % less total dissolved nitrogen, 57 % less phosphorous, and 23-49 % more dissolved oxygen. Average daily air temperature was a key predictor of CH4 emissions from farm dams, underscoring the importance of considering temporal dynamics for estimating yearly farm dam emissions. We confirmed that excluding livestock from entering farm dams using fences significantly mitigates CH4 emissions and enhances water quality, and these benefits are maintained seasonally.


Asunto(s)
Contaminantes Atmosféricos , Granjas , Ganado , Metano , Calidad del Agua , Metano/análisis , Animales , Contaminantes Atmosféricos/análisis , Monitoreo del Ambiente , Australia , Agricultura/métodos , Estaciones del Año , Dióxido de Carbono/análisis
6.
Sci Total Environ ; 951: 175514, 2024 Nov 15.
Artículo en Inglés | MEDLINE | ID: mdl-39147039

RESUMEN

Lake restoration usually focuses on reducing external nutrient sources. However, when sediments contain nutrients accumulated over multiple years, internal nutrient release can delay restoration progress. In lake restoration and management, it is important to understand the dynamic relationship between nutrient concentrations in a lake and internal and external nutrient sources. In this study, we quantified external nutrient inputs through measurements and compared them with internal sediment release from simulation using the PCLake+ model. Additionally, we evaluated alterations in the internal nutrient release, lake nutrient concentrations, and algae biomass (chlorophyll-a) within the lake following varying degrees of reduction in external nutrient loads. The results demonstrate that the PCLake+ effectively simulated the lake's nutrient concentration and algae biomass. Based on the PCLake+ estimates, internal nutrient loads accounted for 51 % of the total nitrogen (N) and 80 % of the total phosphorus (P) loadings in Lake Erhai in 2019. In 2020, the total contributions were 43 % for TN and 72 % for TP. We simulated four scenarios where external nutrient inputs were reduced to 25 %, 50 %, 75 %, and 99.99 % of their original levels. The 40-year simulation showed that the lake's ecological system initially exhibited a fast internal response but reached equilibrium after eight years. P concentrations took longer to reach equilibrium compared to N concentrations, probably due to the stronger binding characteristics of P. To meet the water quality target in the future, it is necessary to reduce external N and P inputs into Lake Erhai by at least 23 % and 15 %, respectively, under current conditions. Although reducing external nutrient loads can indirectly lower internal nutrient loads, water management should address both external and internal loads simultaneously, as internal release cannot be effectively reduced by external reductions alone. Additionally, the lake's internal release may continue for several years, even with reductions in external inputs.


Asunto(s)
Monitoreo del Ambiente , Lagos , Nitrógeno , Fósforo , Lagos/química , Fósforo/análisis , Nitrógeno/análisis , Nutrientes/análisis , Contaminantes Químicos del Agua/análisis , China , Biomasa , Modelos Teóricos , Sedimentos Geológicos/química
7.
Sci Total Environ ; 951: 175544, 2024 Nov 15.
Artículo en Inglés | MEDLINE | ID: mdl-39151630

RESUMEN

Water scarcity is a significant constraint in agricultural ecosystems of arid regions, necessitating sustainable development of agricultural water resources. This study innovatively combines Bayesian theory and Water Footprint (WF) to construct a Bayesian Network (BN). Water quantity and quality data were evaluated comprehensively by WF in agricultural production. This evaluation integrates WF and local water resources to establish a sustainability assessment framework. Selected nodes are incorporated into a BN and continuously updated through structural and parameter learning, resulting in a robust model. Results reveal a nearly threefold increase of WF in the arid regions of Northwest China from 1989 to 2019, averaging 189.95 × 108 m3 annually. The region's agricultural scale is expanding, and economic development is rapid, but the unsustainability of agricultural water use is increasing. Blue WF predominates in this region, with cotton having the highest WF among crops. The BN indicates a 70.1 % probability of unsustainable water use. Sensitivity analysis identifies anthropogenic factors as primary drivers influencing water resource sustainability. Scenario analysis underscores the need to reduce WF production and increase agricultural water supply for sustainable development in arid regions. Proposed strategies include improving irrigation methods, implementing integrated water-fertilizer management, and selecting drought-resistant, economically viable crops to optimize crop planting structures and enhance water use efficiency in current agricultural practices in arid regions. This study not only offers insights into water management in arid regions but also provides practical guidance for similar agricultural contexts. The BN model serves as a flexible tool for informed decision-making in dynamic environments.

8.
Ambio ; 2024 Aug 08.
Artículo en Inglés | MEDLINE | ID: mdl-39115747

RESUMEN

The global demand for agricultural commodities has driven extensive land conversion to agriculture in Brazil, especially in the MATOPIBA region. This area encompasses the Rio Grande Basin, a major tributary of the São Francisco Basin that is known for expanding intensive irrigated agriculture and hydropower generation. However, recent data reveal declining precipitation and aquifer recharge, potentially exacerbating ongoing water and land conflicts. This study investigates the long-term sustainability of agricultural expansion amid the worsening water scarcity using a system dynamics model. Findings suggest that rising costs and decreasing profits due to irrigation water shortages may hinder the expansion of irrigated land. By 2040, the irrigation demand may remain partly unmet, while downstream flow and baseflow could decrease. Additionally, agricultural expansion will significantly raise energy demand, posing a developmental challenge. We suggest that ensuring the sustainability of the Rio Grande Basin depends on improved water management and exploring alternative energy sources to address existing constraints.

9.
Environ Sci (Camb) ; 10(4): 767-786, 2024 Apr 01.
Artículo en Inglés | MEDLINE | ID: mdl-39185481

RESUMEN

Premise plumbing water quality degradation has led to negative health impacts from pathogen outbreaks (e.g., Legionella pneumophila and non-tuberculous mycobacteria), as well as chronic effects from exposure to heavy metals or disinfection by-products (DBP). Common water quality management interventions include flushing, heat shock (thermal disinfection), supplemental disinfection (shock or super chlorination), and water heater temperature setpoint change. In this study, a Legionella pneumophila- colonized Leadership in Energy and Environmental Design (LEED) certified building was monitored to study health-relevant water quality changes before and after three controlled management interventions: (1) flushing at several points throughout the building; (2) changing the water heater set point; and (3) a combination of interventions (1) and (2) by flushing during a period of elevated water heater set point (incompletely performed due to operational issues). Microbial (culturable L. pneumophila, the L. pneumophila mip gene, and cATP) and physico-chemical (pH, temperature, conductivity, disinfectant residual, disinfection by-products (DBPs; total trihalomethanes, TTHM), and heavy metals) water quality were monitored alongside building occupancy as approximated using Wi-Fi logins. Flushing alone resulted in a significant decrease in cATP and L. pneumophila concentrations (p = 0.018 and 0.019, respectively) and a significant increase in chlorine concentrations (p = 0.002) as well as iron and DBP levels (p = 0.002). Copper concentrations increased during the water heater temperature setpoint increase alone to 140°F during December 2022 (p = 0.01). During the flushing and elevated temperature in parts of the building in February 2023, there was a significant increase in chlorine concentrations (p = 0.002) and iron (p = 0.002) but no significant decrease in L. pneumophila concentrations in the drinking water samples (p = 0.27). This study demonstrated the potential impacts of short term or incompletely implemented interventions which in this case were not sufficient to holistically improve water quality. As implementing interventions is logistically- and time-intensive, more effective and holistic approaches are needed for informing preventative and corrective actions that are beneficial for multiple water quality and sustainability goals.

10.
Polymers (Basel) ; 16(16)2024 Aug 18.
Artículo en Inglés | MEDLINE | ID: mdl-39204557

RESUMEN

In the last century, the issue of "water reserves" has become a remarkably strategic topic in modern science and technology. In this context, water resource treatment and management systems are being developed in both agricultural and urban area scenarios. This can be achieved using superabsorbent polymers (SAPs), highly cross-linked hydrogels with three-dimensional, hydrophilic polymer structures capable of absorbing, swelling and retaining huge amounts of aqueous solutions. SAPs are able to respond to several external stimuli, such as temperature, pH, electric field, and solution composition and concentration. They can be used in many areas, from sensor technology to drug delivery, agriculture, firefighting applications, food, and the biomedical industry. In addition, new categories of functional SAP-based materials, mainly superabsorbent polymer composites, can also encapsulate fertilizers to efficiently provide the controlled release of both water and active compounds. Moreover, SAPs have great potential in wastewater treatment for the removal of harmful elements. In this respect, in the following review, the most promising and recent advances in the use of SAPs and composite SAPs as tools for the sustainable management and remediation of water resource are reviewed and discussed by identifying opportunities and drawbacks and highlighting new challenges and aims to inspire the research community.

11.
J Environ Manage ; 368: 122236, 2024 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-39191055

RESUMEN

The chemical composition of dissolved organic matter (DOM) exerts significant influence on aquatic energy dynamics, pollutant transportation, and carbon storage, thereby playing pivotal roles in the local water quality and regional-global biogeochemical cycling. However, the effects of natural climate change and local human activities on watershed characteristics and in-river processes have led to uncertainties regarding their contributions to DOM chemistry in coastal rivers, creating challenges for effective water management and the study of organic matter cycling. In this investigation, we employed a combination of stable isotopic analysis, optical techniques, and Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS) to elucidate the sources, optical properties, and molecular composition of DOM in three South China coastal rivers. Our results suggest that terrestrial DOM entering the three rivers through natural or anthropogenic pathways is gradually diluted by in situ primary production as it moves downstream, ultimately being influenced by seawater intrusion near the estuary. Additionally, terrestrial processes influenced by temperature likely govern DOC concentration, while seawater intrusion promotes the natural production of S-containing organic compounds. In contrast, human-altered landcover significantly impacts DOM molecular composition. Increased water areas lead to the enrichment of lignins with high disinfection byproduct formation potential, and agricultural residue burning appears to be the dominant source of pyrogenic DOM in these coastal rivers. Our distinct results suggest that the development of specific water management plans that consider the combined effects of temperature, seawater intrusion, landcover changes, and agricultural practices will be essential to ensure sustainable water resource.


Asunto(s)
Ríos , Ríos/química , Humanos , Monitoreo del Ambiente , Compuestos Orgánicos/análisis , China , Calidad del Agua , Contaminantes Químicos del Agua/análisis , Agua de Mar/química
12.
Environ Monit Assess ; 196(9): 827, 2024 Aug 20.
Artículo en Inglés | MEDLINE | ID: mdl-39162888

RESUMEN

The distribution and availability of water resources have been greatly impacted by global climate change and unsustainable human activities. This has resulted in increased pressure on surface water supplies, human consumption and socioeconomic growth. Although water management requires monitoring, a substantial amount of water consumption globally, including both groundwater and surface water, remains unmeasured. Madhya Pradesh (MP) has a very varied semi-arid geographical region in Central India. Recent studies have found that 36 out of 51 districts in the state of MP have been facing severe hydrological drought conditions. Despite the challenges in the MP region, there is little understanding of the permanent and seasonal changes in surface water and the overall availability of surface water resources in each district. Field-based monitoring of surface water bodies in large regions such as MP poses considerable difficulties. However, gaining knowledge about changes in the distribution of water on the Earth's surface across time and space can be enhanced by analysing data obtained via remote sensing. To understand the long-term changes in surface water in different districts of Madhya Pradesh, India, over the past 38 years, we analysed a publicly accessible global surface water dataset provided by the Joint Research Centre (JRC) European Commission. This dataset is based on Landsat imagery and covers the period from 1984 to 2021. This research study examines the associations between variations in the permanent surface water level and the extent of land being irrigated, the intensity of agricultural activities and the seasonal oscillations in surface water for several districts in Madhya Pradesh. The findings from this research will be beneficial for assessing several significant MP districts in terms of their water footprint and sustainable management.


Asunto(s)
Agricultura , Monitoreo del Ambiente , Abastecimiento de Agua , India , Agricultura/métodos , Abastecimiento de Agua/estadística & datos numéricos , Agua Subterránea/química , Cambio Climático , Conservación de los Recursos Hídricos/métodos , Sequías , Recursos Hídricos , Estaciones del Año
13.
J Environ Manage ; 368: 122139, 2024 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-39146653

RESUMEN

Rice cultivation boasts a rich historical legacy, serving as the primary sustenance for over 50% of the global population. However, the cultivation process gives rise to the emission of methane (CH4) and nitrous oxide (N2O), two potent greenhouse gases. Notably, the global warming potential (GWP) of CH4 and N2O surpasses CO2 by 27-30 times and 273 times over 100 years, respectively. Addressing this environmental challenge necessitates exploring technical approaches and management strategies to curb gas emissions while sustaining rice yields. Several critical factors have been identified and analyzed for their potential to mitigate greenhouse gas production during rice cultivation. These include water management, fertilizer management, biochar application, cultivar selection, straw management, modified planting methods, and integration of new energy machinery. A comprehensive understanding and implementation of these methods can contribute significantly to achieving a dual objective: reducing emissions and maintaining optimal rice yields. Looking ahead, a synergistic integration of these diverse methods and management approaches holds promise for more effective results. Furthermore, the intricate water networks associated with rice cultivation should be carefully considered in the overall strategy. By adopting a holistic approach that addresses both emission reduction and sustainable water usage, the future of rice cultivation can be shaped to align with environmental stewardship and food security.


Asunto(s)
Agricultura , Calentamiento Global , Gases de Efecto Invernadero , Metano , Oryza , Oryza/crecimiento & desarrollo , Oryza/metabolismo , Metano/metabolismo , Metano/biosíntesis , Agricultura/métodos , Óxido Nitroso/metabolismo , Óxido Nitroso/análisis , Fertilizantes
14.
J Hazard Mater ; 477: 135328, 2024 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-39067297

RESUMEN

This study investigated the spatiotemporal dynamics, bioaccumulation, and critical influencing factors of antibiotics in tilapia aquaculture, focusing on source identification and environmental fate within typical farming systems. The results revealed a progressive increase in antibiotic concentrations in pond water and sediments over the cultivation period, with suspended solids and chemical oxygen demand identified as significant environmental factors influencing the distribution and dissemination of antibiotics. The aquaculture water source was the primary contributor of antibiotics in the farming system. Furthermore, the bioaccumulation factor (BAF) calculations indicated varying degrees of antibiotic enrichment in tilapia tissues, with sulfadimethoxine exhibiting the highest BAFs. Correlation analyses, redundancy analysis, and multivariate linear regression analysis provided insights into the relationship between environmental factors and antibiotics, identifying key antibiotics and influencing factors. The study highlighted the importance of managing and treating water sources to reduce the inflow of antibiotics into aquaculture systems and emphasized the need for non-antibiotic aquaculture practices to minimize the impact on the environment and public health. In conclusion, this research contributes valuable information for the development of effective management strategies and policies aimed at curbing antibiotic pollution in aquaculture environments, ensuring the sustainability of the aquaculture industry, and protecting ecosystem and consumer health.


Asunto(s)
Antibacterianos , Acuicultura , Tilapia , Contaminantes Químicos del Agua , Animales , Tilapia/metabolismo , Antibacterianos/análisis , Contaminantes Químicos del Agua/análisis , Contaminantes Químicos del Agua/metabolismo , Bioacumulación , Sedimentos Geológicos/química , Monitoreo del Ambiente
15.
Water Res ; 262: 122085, 2024 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-39042968

RESUMEN

Sustainable urban water management is crucial for meeting the growing demands of urban populations. This study presents a novel approach that combines time series clustering, seasonal analysis, and entropy analysis to uncover residential water consumption patterns and their drivers. Using a three-year dataset from the SmartH2o project, encompassing 374 households, we identify nine distinct water consumption patterns through time series clustering, leveraging Dynamic Time Warping (DTW) as the optimal similarity measure. Multiple linear regression reveals key household characteristics influencing water usage behaviors, such as the number of bathrooms and appliance efficiency ratings. Seasonal analysis uncovers temporal dynamics, highlighting shifts towards lower consumption during summer months and increased variability in transitional seasons. Entropy analysis quantifies the diversity and complexity of water consumption at both cluster and household levels, informing targeted interventions. This comprehensive, granular approach enables the development of personalized water conservation strategies and policies, empowering water utilities to optimize resource management and contribute to sustainable urban water practices.


Asunto(s)
Entropía , Análisis por Conglomerados , Abastecimiento de Agua , Humanos , Población Urbana , Estaciones del Año , Composición Familiar , Conservación de los Recursos Hídricos , Ciudades
16.
Adv Sci (Weinh) ; : e2404350, 2024 Jul 25.
Artículo en Inglés | MEDLINE | ID: mdl-39052888

RESUMEN

Effective water management is crucial for the optimal operation of low-temperature polymer electrolyte membrane fuel cells (PEMFCs). Excessive liquid water production can cause flooding in the gas diffusion electrodes and flow channels, limiting mass transfer and reducing PEMFC performance. To tackle this issue, a nature-inspired chemical engineering (NICE) approach has been adopted that takes cues from the integument structure of desert-dwelling lizards for passive water transport. By incorporating engraved, capillary microchannels into conventional flow fields, PEMFC performance improves significantly, including a 15% increase in maximum power density for a 25 cm2 cell and 13% for a 100 cm2 cell. Electro-thermal maps of the lizard-inspired flow field demonstrate a more uniform spatial distribution of current density and temperature than the conventional design. Neutron radiography provides evidence that capillary microchannels in the lizard-inspired flow field facilitate the efficient transport and removal of generated liquid water, thereby preventing blockages in the reactant channels. These findings present a universally applicable and highly efficient water management strategy for PEMFCs, with the potential for widespread practical implementation for other electrochemical devices.

17.
Environ Sci Technol ; 58(29): 12888-12898, 2024 Jul 23.
Artículo en Inglés | MEDLINE | ID: mdl-39004818

RESUMEN

Antibiotic-resistant bacteria (ARB) have become a major threat to public health and modern medicine. A simple death kinetics-based dose-response model (SD-DRM) was incorporated into a quantitative microbial risk assessment (QMRA) to assess the risks of exposure to reclaimed wastewater harboring antibiotic-resistant E. coli, Legionella pneumophila, and Mycobacterium avium for multiple exposure scenarios. The fractions of ARB and trace antibiotics present in the body were incorporated to demonstrate their impact on infection risks. Both ARB and antibiotic susceptible bacteria, ASB, are assumed to have the same dose-response in the absence of antibiotics but behave differently in the presence of residual antibiotics in the body. Annual risk of L. pneumophila infection exceeded the EPA 10-4 pppy (per person per year) benchmark at concentrations in reclaimed water greater than 103-104 CFU/L, depending on parameter variation. Enteropathogenic E. coli infection risks meet the EPA annual benchmark at concentrations around 105-106 total E. coli. The results illustrated that an increase in residual antibiotics from 0 to 40% of the minimum inhibitory concentration (MIC) reduced the risk by about 1 order of magnitude for E. coli but was more likely to result in an untreatable infection.


Asunto(s)
Antibacterianos , Escherichia coli , Legionella pneumophila , Aguas Residuales , Legionella pneumophila/efectos de los fármacos , Escherichia coli/efectos de los fármacos , Aguas Residuales/microbiología , Medición de Riesgo , Antibacterianos/farmacología , Mycobacterium/efectos de los fármacos , Farmacorresistencia Bacteriana
18.
Heliyon ; 10(12): e33364, 2024 Jun 30.
Artículo en Inglés | MEDLINE | ID: mdl-39027460

RESUMEN

Global water demand has grown intensively over the last three decades, and the predictions suggest this trend will continue. Sustainable Water Management (SWM) defines water-based principles and action frameworks interconnecting societal, economic, and environmental aspects to establish and maintain good practices serving long-term objectives related to water resources. Water scarcity, deterioration of water quality, less effective water technologies, hydrological changes caused by climate change, and increased water demand require the thorough revision of conventional approaches, new methods, and new policy measures. The research methodology in this paper includes a comprehensive review and bibliometric analysis of relevant literature on water management and sustainable development, including empirical studies, theoretical frameworks, and policy documents. The study explores the conceptual context of SWM, reveals the barriers hindering its core progress, evaluates the impact of green innovations on the development of novel operations, and gets an insight into the current policy and regulatory framework for SWM. Besides giving a review of the current practices and perspectives in SWM, the results of this study contribute to a deeper understanding of the complex relationship between sustainable water management and green innovations in the agricultural sector and provide possible directions toward adopting effective strategies and policies to promote a more intense permeation of the SWM approach.

19.
Sci Total Environ ; 946: 174500, 2024 Oct 10.
Artículo en Inglés | MEDLINE | ID: mdl-38971245

RESUMEN

Paddy drainage is the critical period for rice grain to accumulate cadmium (Cd), however, its roles on spatial heterogeneity of grain Cd within individual fields are still unknown. Herein, field plot experiments were conducted to study the spatial variations of rice Cd under continuous and intermittent (drainage at the tillering or grain-filling or both stages) flooding conditions. The spatial heterogeneity of soil moisture and key factors involved in Cd mobilization during drainages were further investigated to explain grain Cd variation. Rice grain Cd levels under continuous flooding ranged from 0.16 to 0.22 mg kg-1 among nine sampling sites within an individual field. Tillering drainage slightly increased grain Cd levels (0.19-0.31 mg kg-1) with little change in spatial variation. However, grain-filling drainage greatly increased grain Cd range to 0.33-0.95 mg kg-1, with a huge spatial variation observed among replicated sites. During two drainage periods, soil moisture decreased variously in different monitoring sites; greater variation (mean values ranged from 0.14 to 0.27 m3 m-3) was observed during grain-filling drainage. Accordingly, 2.9-3.3-fold variation in soil Eh and 0.55-0.67-unit variation in soil pH were observed among those sites. In the soil with low moisture, ferrous fractions such as ferrous sulfide (FeS) were prone to be oxidized to ferric fractions; meanwhile, the followed generation of hydroxyl radicals involved in Cd remobilization was enhanced. Consequently, soil dissolved Cd changed from 2.97 to 8.92 µg L-1 among different sampling sites during grain-filling drainage; thus, large variation was observed in grain Cd levels. The findings suggest that grain-filling drainage is the main process controlling spatial variation of grain Cd, which should be paid more attention in paddy Cd evaluation.


Asunto(s)
Cadmio , Monitoreo del Ambiente , Oryza , Contaminantes del Suelo , Suelo , Cadmio/análisis , Oryza/química , Contaminantes del Suelo/análisis , Suelo/química , Agricultura/métodos , Grano Comestible/química
20.
Water Res X ; 24: 100231, 2024 Sep 01.
Artículo en Inglés | MEDLINE | ID: mdl-39070728

RESUMEN

Chemicals are commonly dosed in sewer systems to reduce the emission of hydrogen sulfide (H2S) and methane (CH4), incurring high costs and environmental concerns. Nitrite dosing is a promising approach as nitrite can be produced from urine wastewater, which is a feasible integrated water management strategy. However, nitrite dosing usually requires strict conditions, e.g., relatively high nitrite concentration (e.g., ∼200 mg N/L) and acidic environment, to inhibit microorganisms. In contrast to "microbial inhibition", this study proposes "microbial utilization" concept, i.e., utilizing nitrite as a substrate for H2S and CH4 consumption in sewer. In a laboratory-scale sewer reactor, nitrite at a relatively low concentrations of 25-48 mg N/L was continuously dosed. Two nitrite-dependent microbial utilization processes, i.e., nitrite-dependent anaerobic methane oxidation (n-DAMO) and microbial sulfide oxidation, successfully occurred in conjunction with nitrite reduction. The occurrence of both processes achieved a 58 % reduction in dissolved methane and over 90 % sulfide removal in the sewer reactor, with microbial activities measured as 15.6 mg CH4/(L·h) and 29.4 mg S/(L·h), respectively. High copy numbers of n-DAMO bacteria and sulfide-oxidizing bacteria (SOB) were detected in both sewer biofilms and sediments. Mechanism analysis confirmed that the dosed nitrite at a relatively low level did not cause the inhibition of sulfidogenic process due to the downward migration of activity zones in sewer sediments. Therefore, the proposed "microbial utilization" concept offers a new alternative for simultaneous removal of sulfide and methane in sewers.

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