RESUMEN
Developing hybrid metal halides with self-trapped exciton (STE) emission is a powerful and promising approach to achieve single-component phosphors for wide-color-gamut display and illumination. Nevertheless, it is difficult to generate STEs and broadband emission in the classical and widely used 3D systems, owing to the great structural connectivity of metal-halogen networks. Here, high pressure is implemented to achieve dual emission and dramatical emission enhancement in 3D metal halide of [Pb3 Br4 ][O2 C(CH2 )2 CO2 ]. The pressure-induced new emission is ascribed to the radiation recombination of STEs from the Pb2 Br2 O2 tetrahedra with the promoted distortion through the isostructural phase transition. Furthermore, the wide range of emission chromaticity can be regulated by controlling the distortion order of different polyhedral units upon compression. This work not only constructs the relationship between structure and optical behavior of [Pb3 Br4 ][O2 C(CH2 )2 CO2 ], but also provides new strategies for optimizing broadband emission toward potential applications in solid-state lighting.
RESUMEN
Copper(I)-based halides have recently attracted increasing attention as a substitute for lead halides, owing to their nontoxicity, abundance, unique structure, and optoelectric properties. However, exploring an effective strategy to further improve their optical activities and revealing structure-optical property relationships still remain a great concern. Here, by using high pressure technique, a remarkable enhancement of self-trapped exciton (STE) emission associated with the energy exchange between multiple self-trapped states in zero-dimensional lead-free halide Cs3 Cu2 I5 NCs is successfully achieved. Furthermore, high-pressure processing endows the piezochromism of Cs3 Cu2 I5 NCs by experiencing a white light and a strong purple light emission, which is able to be stabilized at near-ambient pressure. The distortion of [Cu2 I5 ] clusters composing of tetrahedral [CuI4 ] and trigonal planar [CuI3 ] and the decreased Cu-Cu distance between the adjacent Cu-I tetrahedron and triangle are responsible for the significant STEs emission enhancement under high pressure. The experiments combined with first-principles calculations not only shed light on the structure-optical property relationships of [Cu2 I5 ] clusters halide, but also provide guidance for improving emission intensity that is highly desirable in solid-state lighting applications.
RESUMEN
Understanding the mechanism of the negative differential resistance (NDR) in transition metal dichalcogenides is essential for fundamental science and the development of electronic devices. Here, the NDR of the current-voltage characteristics was observed based on the glutamine-functionalized WS2quantum dots (QDs). The NDR effect can be adjusted by varying the applied voltage range, air pressure, surrounding gases, and relative humidity. A peak-to-valley current ratio as high as 6.3 has been achieved at room temperature. Carrier trapping induced by water molecules was suggested to be responsible for the mechanism of the NDR in the glutamine-functionalized WS2QDs. Investigating the NDR of WS2QDs may promote the development of memory applications and emerging devices.
RESUMEN
In this paper, we establish convergence to equilibrium for a drift-diffusion-recombination system modelling the charge transport within certain semiconductor devices. More precisely, we consider a two-level system for electrons and holes which is augmented by an intermediate energy level for electrons in so-called trapped states. The recombination dynamics use the mass action principle by taking into account this additional trap level. The main part of the paper is concerned with the derivation of an entropy-entropy production inequality, which entails exponential convergence to the equilibrium via the so-called entropy method. The novelty of our approach lies in the fact that the entropy method is applied uniformly in a fast-reaction parameter which governs the lifetime of electrons on the trap level. Thus, the resulting decay estimate for the densities of electrons and holes extends to the corresponding quasi-steady-state approximation.