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1.
Sensors (Basel) ; 24(15)2024 Aug 04.
Artículo en Inglés | MEDLINE | ID: mdl-39124094

RESUMEN

Graphene-based surface plasmon resonance (SPR) biosensors have emerged as a promising technology for the highly sensitive and accurate detection of biomolecules. This study presents a comprehensive theoretical analysis of graphene-based SPR biosensors, focusing on configurations with single and bimetallic metallic layers. In this study, we investigated the impact of various metallic substrates, including gold and silver, and the number of graphene layers on key performance metrics: sensitivity of detection, detection accuracy, and quality factor. Our findings reveal that configurations with graphene first supported on gold exhibit superior performance, with sensitivity of detection enhancements up to 30% for ten graphene layers. In contrast, silver-supported configurations, while demonstrating high sensitivity, face challenges in maintaining detection accuracy. Additionally, reducing the thickness of metallic layers by 30% optimizes light coupling and enhances sensor performance. These insights highlight the significant potential of graphene-based SPR biosensors in achieving high sensitivity of detection and reliability, paving the way for their application in diverse biosensing technologies. Our findings pretend to motivate future research focusing on optimizing metallic layer thickness, improving the stability of silver-supported configurations, and experimentally validating the theoretical findings to further advance the development of high-performance SPR biosensors.


Asunto(s)
Técnicas Biosensibles , Oro , Grafito , Plata , Resonancia por Plasmón de Superficie , Grafito/química , Resonancia por Plasmón de Superficie/métodos , Plata/química , Técnicas Biosensibles/métodos , Técnicas Biosensibles/instrumentación , Oro/química
2.
Sensors (Basel) ; 24(16)2024 Aug 18.
Artículo en Inglés | MEDLINE | ID: mdl-39205036

RESUMEN

The dispute over the authenticity of video has become a hot topic in judicial practice in recent years. Despite detection methods being updated rapidly, methods for determining authenticity have limitations, especially against high-level forgery. Deleting the integral group of pictures (GOP) length in static scenes could remove key information in the video, leading to unjust sentencing. Anyone can conduct such an operation using publicly available software, thus escaping state-of-the-art detection methods. In this paper, we propose a detection method based on noise transfer matrix analysis. A pyramid structure and a weight learning module are adopted to improve the detection rate and reduce the false positive rate. In total, 80 videos were examined through delicate anti-forensic forgery operations to verify the detection performance of the proposed method and three previously reported methods against anti-forensic forgery operations. In addition, two of the latest learning-based methods were included in our experiments to evaluate the proposed method. The experimental results show that the proposed method significantly improves the detection of frame deletion points compared with traditional and learning-based methods, especially in low false positive rate (FPR) intervals, which is meaningful in forensic science.

3.
Sci Rep ; 14(1): 19076, 2024 Aug 17.
Artículo en Inglés | MEDLINE | ID: mdl-39154019

RESUMEN

The current investigation theoretically presents a one-dimensional phononic crystal (PnC) as a fluidic sensor. The sensor under consideration aims to distinguish the concentration of acetic acid. The primary configuration of the proposed sensor is constructed with lead, epoxy, and a defect layer in the middle of the structure, that is filled with acetic acid (vinegar). As a result of the rise in density and decline in the speed of sound at a 100% concentration of acetic acid in comparison to pure water, the peak frequency of the output has shifted towards lower frequencies. Given that the maximum permissible concentration of acetic acid in water for vinegar is above 30%, sensor simulations were conducted within the concentration range of 25-35% with a step size of 1%. Interestingly, the sensitivity of the sensor exhibits a polynomial change in response to the concentration of acetic acid. Consequently, the highest level of sensitivity, which corresponds to the lowest concentration of vinegar, is recorded as 48.44 × 106 (Hz). The proposed system exhibits a remarkable value of the quality factor of 2802.91. Furthermore, the optimal figure of merit (FOM) is achieved when the concentration is at its lowest, with a value of 94.00. Furthermore, the temperature effects are taken into account for a wide range between 10 and 60 °C. A pronouncing sensitivity is obtained for all temperatures changes and the highest one reached the value of 1.57 × 106 (Hz/°C) at a temperature of 25 °C. Considering the present circumstances, the suggested sensor configuration has the potential to cater to a diverse array of other fluids, specifically their concentration and temperature, thereby offering a broad scope of applications.

4.
Sci Rep ; 14(1): 19829, 2024 Aug 27.
Artículo en Inglés | MEDLINE | ID: mdl-39191803

RESUMEN

In this study, a novel gamma-ray radiation sensor has been developed depending on a 1D photonic crystal (1D-PhC). Based on porous silicon (PSi) layer that has been penetrated by a conjugated copolymer (B-co-MP) which consists of BEHP-PPV and MEH-PPV, with a fractional ratio of 60:40. The suggested method for the development of the dosimeter is based on the shift of photonic band-gap to shorter wavelengths, where exposure to gamma-ray radiation at doses ranging from 0 to 20 kGy alters the refractive index of the (B-co-MP) copolymer. The fitted experimental data, the equation of Bruggeman effective medium, and the transfer matrix method (TMM) are the main axes in the framework of the current theoretical approach. The collected data shows that, within the visible range, the suggested sensor's sensitivity (224 nm/RIU) is high and stable over a 0-20 kGy applied-dose range. Also, we compared these results with previous research.

5.
Philos Trans A Math Phys Eng Sci ; 382(2279): 20230362, 2024 Sep 23.
Artículo en Inglés | MEDLINE | ID: mdl-39129402

RESUMEN

This paper presents a study of wave propagation through an infinite periodic structure that consists of elastic Timoshenko beams interconnected with rigid bodies. This is a generalized approach in which the beams are not coaxial and the centre of mass of each rigid body is placed away from the intersection of their neutral axes. An analytical approach is used by applying the transfer matrix method (TMM), along with the Floquet-Bloch theorem for elastic wave propagation. Subsequent parametric analysis is performed with visualization of resulting band diagrams of a representative structure. These results are verified through comparison with solutions obtained using the finite-element method (FEM). In this manner, a comprehensive dynamical analysis of tailored metastructures is provided.This article is part of the theme issue 'Current developments in elastic and acoustic metamaterials science (Part 2)'.

6.
Philos Trans A Math Phys Eng Sci ; 382(2274): 20230107, 2024 Jul 09.
Artículo en Inglés | MEDLINE | ID: mdl-38826051

RESUMEN

Multichannel, infinite-conjugate optical systems easily allow implementation of multiple image paths and imaging modes into a single microscope. Traditional optical alignment methods which rely on additional hardware are not always simple to implement, particularly in compact open-source microscope designs. We present here an alignment algorithm and process to position the lenses and cameras in a microscope using only image magnification measurements. We show that the resulting positioning accuracy is comparable to the axial resolution of the microscope. Ray transfer matrix analysis is used to model the imaging paths when the optics are both correctly and incorrectly aligned. This is used to derive the corresponding image magnifications. We can then extract information about the lens positions using simple image-based measurements to determine whether there is misalignment of the objective lens to sample distance (working distance) and with what magnitude and direction the objective lens needs to be adjusted. Using the M4All open-source 3D printable microscope system in combination with the OpenFlexure microscope, we validate the alignment method and highlight its usability. We provide the model and an example implementation of the algorithm as an open-source Jupyter Notebook. This article is part of the Theo Murphy meeting issue 'Open, reproducible hardware for microscopy'.

7.
Sci Rep ; 14(1): 14650, 2024 Jun 25.
Artículo en Inglés | MEDLINE | ID: mdl-38918414

RESUMEN

An air spring (AS) for ships must have the structural strength of its bellows enhanced considerably to ensure its reliability under high internal pressure and strong impact. In this case, the stiffness of the bellows gradually dominates the overall stiffness of the AS. Nevertheless, the parameterization calculation of stiffness for an AS mainly focuses on its pneumatic stiffness. The bellows stiffness is normally analyzed by virtue of equivalent simplification or numeric simulation. There is not an effective parameterization calculation model for the stiffness of the bellows, making it difficult to achieve the structural optimization design of the bellows. In this paper, the shell theory was borrowed to build a mechanical model for the bellows. Subsequently, the state vector of the bellows was solved by precision integration and boundary condition. Iteration was conducted to identify the complex coupling relationship between the vector of the bellows and other parameters. On this basis, the parameterization calculation method was introduced for the stiffness of the bellows to obtain the vertical and horizontal stiffness of the AS. After that, a dual-membrane low-stiffness structure was designed to analyze the dominating factors affecting the strength and stiffness of the AS, which highlighted the way to the low-stiffness optimization design of high-strength ASs. In the end, three prototypes and one optimized prototype were tested to verify the correctness of the parameterization design model for stiffness as well as the effectiveness of the structural optimization design.

8.
Sci Rep ; 14(1): 14506, 2024 Jun 24.
Artículo en Inglés | MEDLINE | ID: mdl-38914680

RESUMEN

The Daling River Basin is an important ecological functional area in the western region of Liaoning with outstanding environmental problems. The monitoring of ecological and environmental quality in the basin and the analysis of driving factors are of great importance for the protection of the ecological environment and the improvement of economic quality. In this paper, the three periods of Landsat remote sensing images in 1995, 2010 and 2020 are used as the basic data, and platforms and technical means such as RS and GIS are used to decipher and extract the three periods of land use information, and to construct the land use type transfer matrix. The remote sensing ecological index (RSEI) was improved, and the principal component analysis method was applied to construct the improved remote sensing ecological index (IRSEI) model based on the greenness (NDVI), moisture (WET), heat (LST) and new dryness (N-NDBSI), so as to realize the dynamic monitoring of ecological and environmental quality in the study area. Based on the land use change, combined with the trend of improved remote sensing ecological index (IRSEI) of Daling River Basin, thus achieving the purpose of rapid and efficient dynamic monitoring of ecological quality of Daling River Basin from 1995 to 2020. A geoprobe model was then used to systematically assess the drivers of ecological quality in the catchment. The results show that the improved remote sensing ecological index (IRSEI) can efficiently and accurately obtain the spatial distribution pattern and temporal variation trend of IRSEI in the study area, which is more in line with the characteristics of indicators in this study area. The IRSEI in the study area showed an increasing trend from 1995 to 2020, from 0.4794 to 0.5615, and the proportion of benign ecological classes increased year by year during the period. Among the evaluation indicators, NDVI and N-NDBSI are the main factors affecting the environmental and ecological quality of the Daling River Basin, and the increase of vegetation cover, climate regulation and human activities have obvious promoting effects on the improvement of the ecological environment of the Daling River Basin. This study provides a scientific theoretical basis for the implementation of further ecological environmental protection measures.

9.
Entropy (Basel) ; 26(6)2024 May 28.
Artículo en Inglés | MEDLINE | ID: mdl-38920468

RESUMEN

Today, the Ising model is an archetype describing collective ordering processes. As such, it is widely known in physics and far beyond. Less known is the fact that the thesis defended by Ernst Ising 100 years ago (in 1924) contained not only the solution of what we call now the 'classical 1D Ising model' but also other problems. Some of these problems, as well as the method of their solution, are the subject of this note. In particular, we discuss the combinatorial method Ernst Ising used to calculate the partition function for a chain of elementary magnets. In the thermodynamic limit, this method leads to the result that the partition function is given by the roots of a certain polynomial. We explicitly show that 'Ising's roots' that arise within the combinatorial treatment are also recovered by the eigenvalues of the transfer matrix, a concept that was introduced much later. Moreover, we discuss the generalization of the two-state model to a three-state one presented in Ising's thesis, which is not included in his famous paper of 1925 (E. Ising, Z. Physik 31 (1925) 253). The latter model can be considered as a forerunner of the now-abundant models with many-component order parameters.

10.
Sensors (Basel) ; 24(10)2024 May 11.
Artículo en Inglés | MEDLINE | ID: mdl-38793918

RESUMEN

Identifying brain-tissue types holds significant research value in the biomedical field of non-contact brain-tissue measurement applications. In this paper, a layered metastructure is proposed, and the second harmonic generation (SHG) in a multilayer metastructure is derived using the transfer matrix method. With the SHG conversion efficiency (CE) as the measurement signal, the refractive index ranges that can be distinguished are 1.23~1.31 refractive index unit (RIU) and 1.38~1.44 RIU, with sensitivities of 0.8597 RIU-1 and 1.2967 RIU-1, respectively. It can distinguish various brain tissues, including gray matter, white matter, and low-grade glioma, achieving the function of a second harmonic mode sensor (SHMS). Furthermore, temperature has a significant impact on the SHG CE, which can be used to define the switch signal indicating whether the SHMS is functioning properly. When the temperature range is 291.4~307.9 Kelvin (K), the temperature switch is in the "open" state, and the optimal SHG CE is higher than 0.298%, indicating that the SHMS is in the working state. For other temperature ranges, the SHG CE will decrease significantly, indicating that the temperature switch is in the "off" state, and the SHMS is not working. By stimulating temperature and using the response of SHG CE, the temperature-switch function is achieved, providing a new approach for temperature-controlled second harmonic detection.

11.
Materials (Basel) ; 17(3)2024 Jan 24.
Artículo en Inglés | MEDLINE | ID: mdl-38591376

RESUMEN

We investigate the transmittance spectrum of a multichannel filter composed of dielectric (A) and plasma (P) materials in the microwave region within the transfer matrix formalism. Two configurations of the proposed filter are studied under the influence of an applied magnetic field: (1) a periodic structure containing (A/P)N unit cells surrounded by air and (2) the introduction of a second dielectric material (D) acting as a defect layer to produce an (AP)N/2/D/(AP)N/2 structure. Our findings reveal that in the periodic case, the number of resonant states of the transmittance increases with number N; however, the observed blue and red shifts depend on the intensity and orientation of the applied magnetic field. We present contour plots of the transmission coefficients that show the effect of the incident angle on the shifts of the photonic band gaps. Furthermore, we find that the introduction of a defect layer generates additional resonant states and merges the central resonant peak into a miniband of resonances. Moreover, we show that the number of resonant peaks and their locations can be modulated by increasing the unit cell number, N, as well as increasing the width of the inserted defect layer. Our proposed structures enable the design of novel photonic filters using magnetized plasma materials operating in the microwave region.

12.
J Phys Condens Matter ; 36(25)2024 Mar 27.
Artículo en Inglés | MEDLINE | ID: mdl-38484396

RESUMEN

Metal/dielectric multilayer films have important applications in energy-saving glass, stealth materials, solar energy utilization and other fields. In the current study, the thickness of each layer of TiO2/Ag/TiO2/Ag/TiO2film is optimized. The effects of the number of metal/dielectric multilayer films and the incident light angle on their optical properties were investigated. The TiO2/Ag/TiO2/Ag/TiO2film was prepared by electron beam evaporation coating technology, and their reflectance and transmittance were measured. The measurement results show that the visible light transmittance (380-780 nm) of the film can achieve 68.7%, and the infrared reflectance (780-2500 nm) can reach 95.9%. Compared with the traditional dielectric/metal/dielectric three-layer film, the visible light transmittance of the film is higher, and the solar infrared reflectance is greatly improved. In the solar radiation band (280-2500 nm), the average error between the experimental reflectance and transmittance and the theoretical prediction results is less than 0.03. The distribution of electric and magnetic fields inside the film was simulated by finite-difference time-domain method. The simulation results show that the high visible light transmittance is due to the interference resonance of electromagnetic waves inside the film. Taking Shanghai as an example, under our calculation conditions, compared with ordinary SiO2glass, TiO2/Ag/TiO2/Ag/TiO2film can reduce the total energy consumption of buildings by 14.3% and refrigeration energy consumption by 17.2%.

13.
Adv Sci (Weinh) ; 11(19): e2400090, 2024 May.
Artículo en Inglés | MEDLINE | ID: mdl-38482735

RESUMEN

Herein, a Timoshenko-Ehrenfest beam-based reconfigurable elastic metasurface is introduced that can perform multifunctional wave phenomena within a single substrate, featuring high transmission in the ultrabroadband frequency range. Conventional elastic metasurfaces are typically limited to specific purposes and frequencies, thereby imposing significant constraints on their practical application. The approach involves assembly-components with various geometries on a substrate for reconfigurability, enabling to easily control and implement multifunctional wave phenomena, including anomalous-refraction, focusing, self-acceleration, and total-reflection. This is the first study on elastic metasurfaces to theoretically analyze the dispersion relation based on the Timoshenko-Ehrenfest beam theory, which considers shear deformations and rotational inertia. The analytical model is validated by demonstrating an excellent agreement with numerical and experimental results. The findings include full-wave harmonic simulations and experimentally visualized fields for measuring various wave modulations. Furthermore, the practicality of the system is verified by significantly enhancing the piezoelectric energy harvesting performance within the focusing configuration. It is believed that the reconfigurable elastic metasurface and analytical model based on the Timoshenko-Ehrenfest beam theory have vast applications such as structural health monitoring, wireless sensing, and Internet of Things.

14.
Ecol Appl ; 34(3): e2944, 2024 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-38379442

RESUMEN

In China, the Grain for Green Program (GGP) is an ambitious project to convert croplands into natural vegetation, but exactly how changes in vegetation translate into changes in soil organic carbon remains less clear. Here we conducted a meta-analysis using 734 observations to explore the effects of land recovery on soil organic carbon and nutrients in four provinces in Southwest China. Following GGP, the soil organic carbon content (SOCc) and soil organic carbon stock (SOCs) increased by 33.73% and 22.39%, respectively, compared with the surrounding croplands. Similarly, soil nitrogen increased, while phosphorus decreased. Outcomes were heterogeneous, but depended on variations in soil and environmental characteristics. Both the regional land use and cover change indicated by the landscape type transfer matrix and net primary production from 2000 to 2020 further confirmed that the GGP promoted the forest area and regional mean net primary production. Our findings suggest that the GGP could enhance soil and vegetation carbon sequestration in Southwest China and help to develop a carbon-neutral strategy.


Asunto(s)
Carbono , Suelo , Carbono/análisis , Bosques , Grano Comestible , China
15.
Heliyon ; 10(3): e24846, 2024 Feb 15.
Artículo en Inglés | MEDLINE | ID: mdl-38322889

RESUMEN

Quantitative analysis of the process of urban expansion and evolution is of great practical significance for the future planning and development potential of valley cities. Based on GEE cloud platform and Landsat satellite data, this paper analyzed the spatio-temporal change characteristics and transfer rules of land cover in Xining City and its surrounding areas in the past 33 years by using random forest algorithm, spatio-temporal consistency test, land use dynamic attitude, transfer matrix and transfer hot spot analysis methods. The results show that the accuracy range of the preliminary classification of construction land is improved by 1.57%-3.53 % by using the spatio-temporal consistency test algorithm. The characteristics of land cover change in the study area are mainly the increase of construction land and forest area, the decrease of cultivated land and grassland area, the small change of water body and unused land, and the change of land cover type from cultivated land to urban construction land is prominent. The hot areas of construction land have gradually shifted from the central and eastern districts of the city in 1987 to the hot areas dominated by the Haihu New District of the West of the city, the Biological Park and the higher education base of the North District of the city, the South New District of the city, Duoba Town and the Ganhe Industrial Park in 2019.

16.
Phys Med Biol ; 69(7)2024 Mar 21.
Artículo en Inglés | MEDLINE | ID: mdl-38417179

RESUMEN

Objective. The primary aim of our study is to advance our understanding and diagnosis of cardiac diseases. We focus on the reconstruction of myocardial transmembrane potential (TMP) from body surface potential mapping.Approach. We introduce a novel methodology for the reconstruction of the dynamic distribution of TMP. This is achieved through the integration of convolutional neural networks with conventional optimization algorithms. Specifically, we utilize the subject-specific transfer matrix to describe the dynamic changes in TMP distribution and ECG observations at the body surface. To estimate the TMP distribution, we employ LNFISTA-Net, a learnable non-local regularized iterative shrinkage-thresholding network. The coupled estimation processes are iteratively repeated until convergence.Main results. Our experiments demonstrate the capabilities and benefits of this strategy. The results highlight the effectiveness of our approach in accurately estimating the TMP distribution, thereby providing a reliable method for the diagnosis of cardiac diseases.Significance. Our approach demonstrates promising results, highlighting its potential utility for a range of applications in the medical field. By providing a more accurate and dynamic reconstruction of TMP, our methodology could significantly improve the diagnosis and treatment of cardiac diseases, thereby contributing to advancements in healthcare.


Asunto(s)
Cardiopatías , Corazón , Humanos , Potenciales de la Membrana , Corazón/diagnóstico por imagen , Diagnóstico por Imagen , Miocardio , Algoritmos , Cardiopatías/diagnóstico por imagen , Procesamiento de Imagen Asistido por Computador/métodos
17.
J Biomed Opt ; 29(Suppl 1): S11514, 2024 Jan.
Artículo en Inglés | MEDLINE | ID: mdl-38169937

RESUMEN

Significance: A Fabry-Perot (FP) polymer film sensor can be used to detect acoustic waves in a photoacoustic endoscope (PAE) if the dimensions can be adequately scaled down in size. Current FP sensors have limitations in size, sensitivity, and array configurability. Aim: We aim to characterize and demonstrate the imaging performance of a miniature FP sensor to evaluate the effects of reduced size and finite dimensions. Approach: A transfer matrix model was developed to characterize the frequency response of a multilayer miniature FP sensor. An analytical model was derived to describe the effects of a substrate with finite thickness. Finite-element analysis was performed to characterize the temporal response of a sensor with finite dimensions. Miniature 2×2 mm2 FP sensors were designed and fabricated using gold films as reflective mirrors on either side of a parylene C film deposited on a glass wafer. A single-wavelength laser was used to interrogate the sensor using illumination delivered by fiber subprobes. Imaging phantoms were used to verify FP sensor performance, and in vivo images of blood vessels were collected from a live mouse. Results: The finite thickness substrate of the FP sensor resulted in echoes in the time domain signal that could be removed by back filtering. The substrate acted as a filter in the frequency domain. The finite lateral sensor dimensions produced side waves that could be eliminated by surface averaging using an interrogation beam with adequate diameter. The fabricated FP sensor produced a noise-equivalent pressure = 0.76 kPa, bandwidth of 16.6 MHz, a spectral full-width at-half-maximum = 0.2886 nm, and quality factor Q=2694. Photoacoustic images were collected from phantoms and blood vessels in a live mouse. Conclusions: A miniature wafer-based FP sensor design has been demonstrated with scaled down form factor for future use in PAE.


Asunto(s)
Acústica , Polímeros , Animales , Ratones , Polímeros/química , Análisis Espectral , Fantasmas de Imagen , Endoscopía Gastrointestinal
18.
Nanotechnology ; 35(13)2024 Jan 09.
Artículo en Inglés | MEDLINE | ID: mdl-38100835

RESUMEN

The importance of light management for perovskite solar cells (PSCs) has recently been emphasized because their power conversion efficiency approaches their theoretical thermodynamic limits. Among optical strategies, anti-reflection (AR) coating is the most widely used method to reduce reflectance loss and thus increase light-harvesting efficiency. Monolayer MgF2is a well-known AR material because of its optimal refractive index, simple fabrication process, and physical and chemical durabilities. Nevertheless, quantitative estimates of the improvement achieved by the MgF2AR layer are lacking. In this study, we conducted theoretical and experimental evaluations to assess the AR effect of MgF2on the performance of formamidinium lead-triiodide PSCs. A sinusoidal tendency to enhance the short-circuit current density (JSC) was observed depending on the thickness, which was attributed to the interference of the incident light. A transfer matrix method-based simulation was conducted to calculate the optical losses, demonstrating the critical impact of reflectance loss on theJSCimprovement. The predictedJSCs values, depending on the perovskite thickness and the incident angle, are also presented. The combined use of experimental and theoretical approaches offers notable advantages, including accurate interpretation of photocurrent generation, detailed optical analysis of the experimental results, and device performance predictions under unexplored conditions.

19.
Micromachines (Basel) ; 14(11)2023 Oct 31.
Artículo en Inglés | MEDLINE | ID: mdl-38004896

RESUMEN

As demand for haptic feedback increases, piezoelectric materials have become one of the best candidate materials due to their small size, high electromechanical coupling coefficient, and fast response. A stacked piezoelectric cymbal vibrator is proposed based on the common cymbal-type transducer, which is composed of a piezoelectric stack to drive and a cymbal disk to amplify displacement. A coupling theoretical model between the piezoelectric stack and the cymbal-type structure is established. The longitudinal and radial displacements of the stacked piezoelectric cymbal vibrator are calculated in the low frequency range (<1000 Hz) by the theoretical model and the finite element method. The theoretical and numerical results are in good agreement. The results show that the radial displacement can be converted into longitudinal displacement and then effectively amplified by the cymbal disk with an amplification ratio of 30. The feature is conducive to its widespread application in the field of consumer electronics.

20.
Materials (Basel) ; 16(18)2023 Sep 07.
Artículo en Inglés | MEDLINE | ID: mdl-37763386

RESUMEN

Recently, the development of tandem devices has become one of the main strategies for further improving the efficiency of photovoltaic modules. In this regard, combining well-established Si technology with thin film technology is one of the most promising approaches. However, this imposes several limitations on such thin film technology, such as low prices, the absence of scarce or toxic elements, the possibility to tune optical properties and long lifetime stability. Therefore, to show the potential of kesterite/silicon tandems, in this work, a 2 terminal (2T) structure using pure germanium kesterite was simulated with combined SCAPS and transfer matrix methods. To explore the impact of individual modifications, a stepwise approach was adopted to improve the kesterite. For the bottom sub cell, a state-of-the-art silicon PERC cell was used with an efficiency of 24%. As a final result, 19.56% efficiency was obtained for the standalone top kesterite solar cell and 28.6% for the tandem device, exceeding standalone silicon efficiency by 4.6% and justifying a new method for improvement. The improvement observed could be attributed primarily to the enhanced effective lifetime, optimized base doping, and mitigated recombination at both the back and top layers of the CZGSSe absorber. Finally, colorimetric analysis showed that color purity for such tandem structure was low, and hues were limited to the predominant colors, which were reddish, yellowish, and purple in an anti-reflective coating (ARC) thickness range of 20-300 nm. The sensitivity of color variation for the whole ARC thickness range to electrical parameters was minimal: efficiency was obtained ranging from 28.05% to 28.63%.

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