RESUMEN

Ferrous alloys, particularly steels, form a specialized class of metallic materials extensively employed in industrial sectors to combat deterioration and failures caused by wear. Despite their commendable mechanical properties, steels are not immune to wear-induced degradation. In this context, surface nanocrystallization (SNC) technologies have carved a distinct niche for themselves by enabling the nanostructuring of the surface layer (with grain sizes < 100 nm). This process enhances overall mechanical properties to a level desirable for wear resistance while preserving the chemical composition. Existing literature has consistently highlighted the efficacy of various SNC methods in improving the wear resistance of ferrous alloys, positioning SNC as a promising tool to extend materials' service life in practical applications. This review provides a comprehensive examination of the SNC techniques employed in surface treatment of ferrous alloys and their impact on wear behavior. We delved into the underlying mechanisms governing wear in SNC-treated Fe-based alloys and concluded with a discussion on current challenges and future perspectives in this evolving field.

RESUMEN

A crashworthiness design of foam-filled local nanocrystallized thin-walled tubes (FLNTs) is proposed by using foam-filled structures and ultrasonic impact surface treatment. The crashworthiness and deformation modes of FLNTs are studied using an experiment and numerical analysis. A finite element numerical model of FLNTs is established, and the processing and test platform of FLNTs is set up to verify the numerical predication and analytical design. The results show that local nanocrystallization is an effective method to enhance crashworthiness for hexagonal FLNTs. The FLNTs with four circumferential continuous stripes of surface nanocrystallization exhibit a level of 47.12% higher specific energy absorption than the untreated tubes in numerical simulations for tubes with a 50% ratio of nanocrystallized area. Inspired by the strength mechanism, a novel nested foam-filled local surface nanocrystallization tube is further designed and studied in detail.

RESUMEN

The surface nano-crystallization of Ni2FeCoMo0.5V0.2 medium-entropy alloy was realized by rotationally accelerated shot peening (RASP). The average grain size at the surface layer is ~37 nm, and the nano-grained layer is as thin as ~20 µm. Transmission electron microscopy analysis revealed that deformation twinning and dislocation activities are responsible for the effective grain refinement of the high-entropy alloy. In order to reveal the effectiveness of surface nano-crystallization on the Ni2FeCoMo0.5V0.2 medium-entropy alloy, a common model material, Ni, is used as a reference. Under the same shot peening condition, the surface layer of Ni could only be refined to an average grain size of ~234 nm. An ultrafine grained surface layer is less effective in absorbing strain energy than a nano-grain layer. Thus, grain refinement could be realized at a depth up to 70 µm in the Ni sample.

RESUMEN

AZ91D Mg alloy was treated by ultrasonic surface rolling processing (USRP) and subsequent recovery treatment at different temperatures. The dry sliding friction test was performed to investigate the effects of USRP and subsequent recovery treatment on the wear resistance of AZ91D Mg alloy by a ball-on-plate tribometer. The microstructure, properties of plastic deformation layer and worn morphology were observed by optical microscope (OM), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD) analysis and microhardness tester. Results illustrate that the grains of AZ91D Mg alloy surface layer are refined to nanocrystallines. The maximum microhardness of the top surface of the USRP sample reaches 102.3 HV. When USRP samples are treated by recovery treatment at 150 °C, 200 °C and 250 °C, the microhardness of the top surface decreases to 90.68 HV, 79.29 HV and 75.06 HV, respectively. The friction coefficient (FC) and wear volume loss of the USRP-R-150 sample are the lowest among all the samples. The worn surface morphology of the USRP-R-150 sample is smoother than that of other samples, indicating that the wear resistance of AZ91D Mg alloy treated by USRP and recovery treatment at 150 °C is improved significantly.

RESUMEN

The objective of the given work was to investigate abrasive wear behaviours of titanium (Ti) treated by ultrasonic surface rolling processing (USRP) pre-treatment and plasma nitriding (PN). Simulated lunar regolith particles (SLRPs) were employed as abrasive materials during characterization of tribological performances. The experimental results showed that SLRPs cause severe abrasive wear on Ti plasma-nitrided at 750 °C via the mechanism of micro-cutting. Due to the formation of a harder and thicker nitriding layer, the abrasive wear resistance of the Ti plasma-nitrided at 850 °C was enhanced, and its wear mechanism was mainly fatigue. USRP pre-treatment was effective at enhancing the abrasive wear resistance of plasma-nitrided Ti, due to the enhancement of the hardness and thickness of the nitride layer. Nevertheless, SLRPs significantly decreased the friction coefficient of Ti treated by USRP pre-treatment and PN, because the rolling of small granular abrasives impeded the adhesion of the worn surface. Furthermore, USRP pre-treatment also caused the formation of a dimpled surface with a large number of micropores which can hold wear debris during tribo-tests, and finally, polishing and rolling the wear debris resulted in a low friction coefficient (about 0.5).

RESUMEN

Ti6Al4V (TC4) alloy has long been used as a bone interfacing implant material in dentistry and orthopedics due to its excellent biocompatibility and mechanical properties. The performance of TC4 can be further tailored by altering its grain structures. In this study, by means of sliding friction treatment (SFT), a nano-grained (NG) surface layer with an average grain size of ≤100 nm on the topmost surface was successfully generated on coarse-grained (CG) TC4 alloy sheet. It was shown that the NG surface possessed notably enhanced corrosion resistance in physiological solution compared to the CG surface, due to the formation of thicker and denser passive film facilitated by surface nanocrystallization. Additionally, the NG surface with stronger hydrophilicity favorably altered the absorption of anchoring proteins such as fibronectin (Fn) and vitronectin (Vn) that can mediate subsequent osteoblast functions. The in vitro results indicated that the NG surface exhibited remarkable enhancement in osteoblast adherence, spreading and proliferation, and obviously accelerated the osteoblast differentiation as compared to CG surface. Moreover, the NG surface also demonstrated good hemocompatibility. These findings suggest that SFT can endure bio-metals with advanced multifunctional properties for biomedical applications.

Asunto(s)

Materiales Biocompatibles/química , Materiales Biocompatibles/farmacología , Nanoestructuras/química , Titanio/química , Titanio/farmacología , Adsorción , Fosfatasa Alcalina/metabolismo , Aleaciones , Adhesión Celular/efectos de los fármacos , Muerte Celular/efectos de los fármacos , Proliferación Celular/efectos de los fármacos , Forma de la Célula/efectos de los fármacos , Células Cultivadas , Colágeno Tipo I/metabolismo , Corrosión , Espectroscopía Dieléctrica , Técnicas Electroquímicas , Matriz Extracelular/metabolismo , Fibronectinas/química , Regulación de la Expresión Génica , Hemólisis/efectos de los fármacos , Humanos , Ensayo de Materiales , Minerales/química , Nanoestructuras/ultraestructura , Osteoblastos/metabolismo , Osteocalcina/metabolismo , Osteogénesis/genética , Osteopontina/metabolismo , Adhesividad Plaquetaria/efectos de los fármacos , Vitronectina/química , Humectabilidad

RESUMEN

Substrate grain structure and topography play major roles in mediating cell and bacteria activities. Severe plastic deformation techniques, known as efficient metal-forming and grain refining processes, provide the treated material with novel mechanical properties and can be adopted to modify nanoscale surface characteristics, possibly affecting interactions with the biological environment. This in vitro study evaluates the capability of severe shot peening, based on severe plastic deformation, to modulate the interactions of nanocrystallized metallic biomaterials with cells and bacteria. The treated 316L stainless steel surfaces were first investigated in terms of surface topography, grain size, hardness, wettability and residual stresses. The effects of the induced surface modifications were then separately studied in terms of cell morphology, adhesion and proliferation of primary human osteoblasts (bone forming cells) as well as the adhesion of multiple bacteria strains, specifically Staphylococcus aureus, Staphylococcus epidermidis, Pseudomonas aeruginosa, and ampicillin-resistant Escherichia coli. The results indicated a significant enhancement in surface work hardening and compressive residual stresses, maintenance of osteoblast adhesion and proliferation as well as a remarkable decrease in the adhesion and growth of gram-positive bacteria (S. aureus and S. epidermidis) compared to non-treated and conventionally shot peened samples. Impressively, the decrease in bacteria adhesion and growth was achieved without the use of antibiotics, for which bacteria can develop a resistance towards anyway. By slightly grinding the surface of severe shot peened samples to remove differences in nanoscale surface roughness, the effects of varying substrate grain size were separated from those of varying surface roughness. The expression of vinculin focal adhesions from osteoblasts was found to be singularly and inversely related to grain size, whereas the attachment of gram-positive bacteria (S. aureus and S. epidermidis) decreased with increasing nanoscale surface roughness, and was not affected by grain refinement. Ultimately, this study demonstrated the advantages of the proposed shot peening treatment to produce multifunctional 316L stainless steel materials for improved implant functions without necessitating the use of drugs.

Asunto(s)

Adhesión Bacteriana , Nanoestructuras/química , Osteoblastos/citología , Acero Inoxidable/química , Materiales Biocompatibles , Adhesión Celular , Proliferación Celular , Fuerza Compresiva , Escherichia coli , Humanos , Metales/química , Microscopía Electrónica de Rastreo , Microscopía Fluorescente , Oseointegración , Osteoblastos/metabolismo , Osteoblastos/microbiología , Pseudomonas aeruginosa , Staphylococcus aureus , Staphylococcus epidermidis , Propiedades de Superficie , Humectabilidad , Difracción de Rayos X

RESUMEN

The study addresses how surface nanostructuring of AISI 304 stainless steel (SS) by surface mechanical attrition treatment (SMAT) influences its characteristic properties and corrosion behavior in Ringer's solution. SMAT of 304 SS induced plastic deformation, enabled surface nanocrystallization, refined the grain size, transformed the austenite phase to strain induced α'-martensite phase, increased the surface roughness, induced defects/dislocations, imparted compressive residual stresses at the surface, decreased the contact angle, and increased surface energy. The change in properties of 304 SS following treatment using 5 and 8 mm ⌀ balls for 15, 30, 45, and 60 min has caused a deleterious influence on its corrosion resistance in Ringer's solution, while an improvement in corrosion behavior is observed for those treated using 2 mm ⌀ balls. The increase in surface roughness, transformation of the austenite to α'-martensite phase, a higher extent of deformation, and the presence of larger number of defects/dislocations are main factors responsible for the lower corrosion resistance observed for 304 SS treated using 5 and 8 mm ⌀ balls in Ringer's solution. In spite of having these attributes with a relatively lower extent, 304 SS treated using 2 mm ⌀ balls offered a better corrosion resistance and exhibits a better passivity. For those treated using 2 mm ⌀ balls, the ability of the nanocrystalline surface to promote passivation outweighs the deleterious influences caused by the limited amount of deformation and defects/dislocations. Based on the findings of this study, it is recommend that SMAT of 304 SS using 2 mm ⌀ balls for 15-30 min is the optimum condition to achieve the suitable surface profile, surface characteristics with better corrosion resistance.

RESUMEN

In this study, microstructural characterization of Ti-6Al-4V alloy, subjected to the duplex surface mechanical attrition treatment (SMAT)/nitriding treatment, leading to improve its mechanical properties, was carried out through novel and original samples preparation methods. Instead of acid etching which is limited for morphological characterization by scanning electron microscopy (SEM), an original ion polishing method was developed. Moreover, for structural characterization by transmission electron microscopy (TEM), an ion milling method based with the use of two ions guns was also carried out for cross-section preparation. To demonstrate the efficiency of the two developed methods, morphological investigations were done by traditional SEM and field emission gun SEM. This was followed by structural investigations through selected area electron diffraction (SAED) coupled with TEM and X-ray diffraction techniques. The results demonstrated that ionic polishing allowed to reveal a variation of the microstructure according to the surface treatment that could not be observed by acid etching preparation. TEM associated to SAED and X-ray diffraction provided information regarding the nanostructure compositional changes induced by the duplex SMAT/nitriding process.