RESUMEN

Blending poly(l-lactide) (PLLA) with elastic polymers is an efficient way to obtain highly ductile materials (> 300 %), but it is accompanied by a significant reduction in strength. In this work, a special alternating multilayered composites with alternating stereocomplex crystallite (SC) (PLLA/poly(d-lactide) (PDLA) layer) and highly oriented Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) ribbons (PLLA/PHBV layer) is in situ constructed during laminated structuring process. Experimental results show that in situ formed PHBV ribbons are limitedly distributed in the thickness direction and align parallel to the layer interfaces. More interestingly, not only highly oriented shish crystals but also sparse lamellae of PLLA, which are arrested by SC, shish crystals, and PHBV ribbons, are in situ formed. Compared with sea-island structured composites prepared by traditional compression molding, the alternating multilayered composites show an increase in elongation at break from 8.7 % to 345.1 % and an increase in yield strength from 61.4 MPa to 73.2 MPa. During the tensile testing, the PLLA/PHBV layers firstly form micro-fibrils and micro-voids, driving the molecular chains of the PLLA/PDLA layer to respond in time to external forces through stress transfer of rich continuous layer interfaces. Since shear yielding and plastic deformation can easily penetrate the entire matrix, the alternating multilayered composites go a brittle-ductile transformation and the ductility is improved significantly. The increased strength of the alternating multilayered material is ascribed to the stiff shish crystals and SC. This work provides important guidance for the durable application of strong and ductile PLLA-based materials.

Asunto(s)

Materiales Biocompatibles , Poliésteres , Materiales Biocompatibles/química , Poliésteres/química

RESUMEN

Q960 high-strength steel is widely used in pressure vessels, bridges, offshore platforms and other important steel structural components because of its high strength and good plastic toughness, but alloy elements added to this kind of steel have strong hardenability, especially after welding, so the strength and toughness cannot meet the requirements, which limits its application in a wider range. In this paper, from the point of view of the metallurgical treatment of the weld, the goal is to improve the strength and toughness of the Q960 high strength steel weld metal In order to analyze the influence of Zr on the welding process of Q960 steel and the strengthening and toughening effect of weld metal, this paper takes Fe-Mn-Mo-Cr-Ni as the main alloy system, BaF2-CaF2-Al-Mg as the basic slag system, and adopts the method of melting consumable electrode self-shielded for welding, and analyzes the welding process, microstructure, tensile property and impact toughness of the welded joint. The experimental results show that when the weld metal contains 0.0061% Zr, the minimum spatter rate is only 7%, the maximum slag removal rate is 95%, the maximum hardness is 357HV, the maximum elongation is 34%, and the impact toughness is the highest. At this time, the acicular ferrite content in the weld microstructure is the highest, and there is a certain amount of equiaxed fine-grained ferrite, and the content of proeutectoid ferrite is the least, which effectively improves the strength and toughness of the weld metal.