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1.
J Am Stat Assoc ; 119(546): 798-810, 2024.
Artículo en Inglés | MEDLINE | ID: mdl-39280355

RESUMEN

Medical imaging is a form of technology that has revolutionized the medical field over the past decades. Digital pathology imaging, which captures histological details at the cellular level, is rapidly becoming a routine clinical procedure for cancer diagnosis support and treatment planning. Recent developments in deep-learning methods have facilitated tumor region segmentation from pathology images. The traditional shape descriptors that characterize tumor boundary roughness at the anatomical level are no longer suitable. New statistical approaches to model tumor shapes are in urgent need. In this paper, we consider the problem of modeling a tumor boundary as a closed polygonal chain. A Bayesian landmark-based shape analysis model is proposed. The model partitions the polygonal chain into mutually exclusive segments, accounting for boundary roughness. Our Bayesian inference framework provides uncertainty estimations on both the number and locations of landmarks, while outputting metrics that can be used to quantify boundary roughness. The performance of our model is comparable with that of a recently developed landmark detection model for planar elastic curves. In a case study of 143 consecutive patients with stage I to IV lung cancer, we demonstrated the heterogeneity of tumor boundary roughness derived from our model effectively predicted patient prognosis (p-value < 0.001).

2.
Cureus ; 16(8): e67019, 2024 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-39280469

RESUMEN

Background Restorative dentists frequently deal with the prosthesis coming loose after placing multiple crowns. The luting cement holds indirect restorations to the prepared tooth. However, the success of the restorations is impacted by mastication pressures and other undesired factors. Therefore, escape is required to increase the crown's life. Mechanical locking of the prepared tooth surface is one technique to address this issue, in addition to cement adherence, to extend the life of the restoration. Aims and objective The objective of the study was to evaluate the influence of surface roughness of prepared teeth on the retention of metal crowns. Methodology This in-vitro investigation was carried out on freshly extracted maxillary first premolars that were defect-free and had the same crown size. Using multiple grifts of varied coarseness, different surface roughness was created, allowing for the observation of an important factor like retention (black at 180-250 µm [micrometer], blue at 125-150 µm, green at 106-125 µm, red at 53-63 µm, yellow at 20-30 µm). Results IBM Corp. Released 2011. IBM SPSS Statistics for Windows, Version 20.0. Armonk, NY: IBM Corp. was used to perform the statistical analysis. Compounds were done before it began to guarantee that the study would have 80% power. There is a mean and a standard deviation for each quantitative variable. A one-way ANOVA was used for quantitative variables, and Tukey's post hoc analysis was conducted afterward. A probability value of less than 0.05 was used to determine statistical significance. According to the statistical findings, the prosthesis's retentive qualities improve as coarseness increases. Conclusion The resistance and retention form of the preparation is critical to the longevity of the prosthesis, based on the findings of the previously described study. Surface roughness, pins, slots, grooves, and other preparation modifications can enhance retention on the prepared tooth surface. The research findings indicate no need to polish the prepared tooth surface.

3.
Materials (Basel) ; 17(17)2024 Aug 28.
Artículo en Inglés | MEDLINE | ID: mdl-39274640

RESUMEN

With the rapid advancement of 3D-printing technology, additive manufacturing using FDM extrusion has emerged as a prominent method in manufacturing. However, it encounters certain limitations, notably in surface quality and dimensional accuracy. Addressing issues related to stability and surface roughness necessitates the integration of 3D-printing technology with traditional machining, a strategy known as the hybrid technique. This paper presents a study of the surface geometric parameters and microstructure of plastic parts produced by FDM. Sleeve-shaped samples were 3D-printed from polyethylene terephthalate glycol material using variable layer heights of 0.1 mm and 0.2 mm and then subjected to the turning process with PVD-coated DCMT11T304 turning inserts using variable cutting parameters. The cutting depth was constant at 0.82 mm. Surface roughness values were correlated with the cutting tool feed rate and the printing layer height applied. The selected specimen's microstructure was studied with a Zeiss EVO MA 15 scanning electron microscope. The roundness was measured with a Keyence VR-6200 3D optical profilometer. The research results confirmed that the additional application of turning, combined with a reduction in the feed rate (0.0506 mm/rev) and the height of the printed layer (0.1 mm), reduced the surface roughness of the sleeve (Ra = 1.94 µm) and increased its geometric accuracy.

4.
Materials (Basel) ; 17(17)2024 Aug 30.
Artículo en Inglés | MEDLINE | ID: mdl-39274708

RESUMEN

Hollow sinking experiments and tensile tests were conducted to clarify the evolution of surface roughness during hollow sinking. Stainless steel tubes (outer diameter: 1.5 mm; wall thickness: 0.045 mm) featuring a single grain spanning the wall thickness achieved via annealing as the starting material. The tube was drawn without an internal tool using a draw bench by controlling the tube drawing speed ratio of the die entrance and exit sides. The surface roughnesses of the inner and outer surfaces at the die entrance and exit sides of the drawn tube were compared with the surface roughnesses of the inner and outer surfaces under the uniaxial tensile deformation of the starting material. As a result, two major findings were revealed; the surface roughness formation behavior during the hollow sinking; the uniaxial tensile deformation exhibits a tube on both sides of the entrance and the exit of a die. Former uniaxial tensile deformation forms surface roughness of the tube at the die-entrance-side. However, hollow sinking reduces the roughness. The tube keeps its small roughness even though it is applied the later uniaxial tensile deformation behind the die exit. Furthermore, the conventional formula to predict the surface roughness of a metal sheet caused by the uniaxial tensile deformation can predict the surface roughness of a tube in the hollow sinking. At both die entrance and exit sides, the roughness of the inner surface was larger than that of the outer surface at the die entrance and exit side. The outer surface of the tube contacts the inside of a die when the tube passes through the die. The height of the convex parts decreased at that moment. Hollow sinking suppressed the increase in surface roughness of the inner surface as the outer surface was smoothed in the die. However, due to the formation of surface roughness after leaving the die, there is an overall increasing trend in inner surface roughness.

5.
BMC Oral Health ; 24(1): 1055, 2024 Sep 09.
Artículo en Inglés | MEDLINE | ID: mdl-39251975

RESUMEN

BACKGROUND: The purpose of this in vitro study was to investigate the effect of polishing post-treatment process on the torque loss ratio and microgap of Selective Laser Melting (SLM) abutments before and after mechanical cycling test through improving the surface roughness of the implant-abutment interface. MATERIALS AND METHODS: Forty SLM abutments were fabricated, with 20 underwent minor back-cutting, designated as polishing, in the implant-abutment interface. The abutments were divided into three groups: SLM abutments (group A), original abutments (group B), and polished SLM abutments (group C), each containing 20 abutments. Surface roughness was evaluated using a laser microscope. Implant-abutment specimens were subjected to mechanical cycling test, and disassembly torque values were measured before and after. Scanning electron microscope (SEM) was used to measure microgap after longitudinal sectioning of specimens. Correlation between surface roughness, torque loss ratio, and microgap were evaluated. LSD's test and Tamhane's T2 comparison were used to analyze the data (α = 0.05). RESULTS: The Sz value of polished SLM abutments (6.86 ± 0.64 µm) demonstrated a significant reduction compared to SLM abutments (26.52 ± 7.12 µm). The torque loss ratio of polished SLM abutments (24.16%) was significantly lower than SLM abutments (58.26%), while no statistically significant difference that original abutments (18.23%). The implant-abutment microgap of polished SLM abutments (2.38 ± 1.39 µm) was significantly lower than SLM abutments (8.69 ± 5.30 µm), and this difference was not statistically significant with original abutments (1.87 ± 0.81 µm). A significant positive correlation was identified between Sz values and the ratio of torque loss after cycling test (r = 0.903, P < 0.01), as well as Sz values and the microgap for all specimens in SLM abutments and polished SLM abutments (r = 0.800, P < 0.01). CONCLUSION: The findings of this study indicated that the polishing step of minor back-cutting can lead to a notable improvement in the roughness of SLM abutments interface, which subsequently optimized the implant-abutment fit. It can be seen that the application of minor back-cutting method has advanced the clinical use of SLM abutments.


Asunto(s)
Pilares Dentales , Diseño de Implante Dental-Pilar , Pulido Dental , Rayos Láser , Microscopía Electrónica de Rastreo , Propiedades de Superficie , Torque , Técnicas In Vitro , Pulido Dental/métodos , Humanos , Ensayo de Materiales , Análisis del Estrés Dental
6.
Nanomaterials (Basel) ; 14(17)2024 Sep 03.
Artículo en Inglés | MEDLINE | ID: mdl-39269101

RESUMEN

Exploring the phonon characteristics of novel group-IV binary XC (X = Si, Ge, Sn) carbides and their polymorphs has recently gained considerable scientific/technological interest as promising alternatives to Si for high-temperature, high-power, optoelectronic, gas-sensing, and photovoltaic applications. Historically, the effects of phonons on materials were considered to be a hindrance. However, modern research has confirmed that the coupling of phonons in solids initiates excitations, causing several impacts on their thermal, dielectric, and electronic properties. These studies have motivated many scientists to design low-dimensional heterostructures and investigate their lattice dynamical properties. Proper simulation/characterization of phonons in XC materials and ultrathin epilayers has been challenging. Achieving the high crystalline quality of heteroepitaxial multilayer films on different substrates with flat surfaces, intra-wafer, and wafer-to-wafer uniformity is not only inspiring but crucial for their use as functional components to boost the performance of different nano-optoelectronic devices. Despite many efforts in growing strained zinc-blende (zb) GeC/Si (001) epifilms, no IR measurements exist to monitor the effects of surface roughness on spectral interference fringes. Here, we emphasize the importance of infrared reflectivity Rω and transmission Tω spectroscopy at near normal θi = 0 and oblique θi ≠ 0 incidence (Berreman effect) for comprehending the phonon characteristics of both undoped and doped GeC/Si (001) epilayers. Methodical simulations of Rω and Tω revealing atypical fringe contrasts in ultrathin GeC/Si are linked to the conducting transition layer and/or surface roughness. This research provided strong perspectives that the Berreman effect can complement Raman scattering spectroscopy for allowing the identification of longitudinal optical ωLO phonons, transverse optical ωTO phonons, and LO-phonon-plasmon coupled ωLPP+ modes, respectively.

7.
J Clin Pediatr Dent ; 48(5): 131-137, 2024 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-39275830

RESUMEN

Recently, interest in tooth-colored fluoride-releasing dental materials has increased. Although physical and mechanical properties such as surface hardness, elastic modulus and surface roughness of the restorative materials have been investigated, the effect of different immersion media on these properties is still controversial. The aim of this study was to evaluate the nanohardness, elastic modulus and surface roughness of the fluoride release of tooth-colored restorative materials after immersion in acidic beverages. Prepared samples of three restorative materials (a highly viscous glass ionomer (EQUIA Forte; GC, Tokyo, Japan), a compomer (Dyract XP; Dentsply, Weybridge, UK), and a bioactive restorative material (Activa BioACTIVE; Pulpdent, MA, USA)) were randomly divided and immersed in distilled water, a cola and an orange juice for one week. The HYSITRON T1 950 TriboIndenter device (Hysitron, USA) with the Berkovich diamond indenter tip was used for all measurements. The nanohardness and elastic modulus of the samples were measured by applying a force of 6000 µN to five different points on the sample surface. Surface roughness measurements were evaluated on random samples by scanning five random 40 × 40 µm areas. The properties were measured at the initial and one week after immersion. The values of nanohardness, elastic modulus and surface roughness were tested for significant differences using a two-way analysis of variance (ANOVA) with repeated measures (p < 0.05). Tukey's honest significant difference (HSD) test was used for multiple comparisons. AB (Activa BioACTIVE) had the highest initial mean values for nanohardness. After post-immersion, the highest mean value for elastic modulus was the initial AB value. The lowest mean value for roughness of 100.36 nm was obtained for the initial DX (Dyract XP) measurement. Acidic beverages had a negative effect on the nanohardness, elastic modulus and surface roughness of the restorative materials.


Asunto(s)
Bebidas Gaseosas , Módulo de Elasticidad , Fluoruros , Dureza , Ensayo de Materiales , Propiedades de Superficie , Fluoruros/química , Compómeros/química , Humanos , Materiales Dentales/química , Jugos de Frutas y Vegetales , Resinas Acrílicas/química , Restauración Dental Permanente/métodos , Agua/química , Cariostáticos/química , Cementos de Ionómero Vítreo/química , Citrus sinensis/química , Inmersión , Resinas Compuestas/química , Dióxido de Silicio
8.
Cureus ; 16(8): e66054, 2024 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-39224719

RESUMEN

Introduction Canal preparation is a critical step in endodontic therapy. Introducing nickel-titanium (NiTi) rotary instruments has significantly reduced the likelihood of errors in curved canals. However, due to their price, these instruments are often reused following autoclaving. The aim of this study is to compare and evaluate the surface characteristics of two designs of rotary NiTi files used in curved canals and subjected to multiple autoclaving cycles, utilizing an atomic force microscope for detailed analysis. Methods A total sample size of 24 files was taken, 12 files of Hyflex EDM (Coltene/Whaledent, Germany) files and WaveOne Gold (Dentsply Sirona, USA) files were then divided into four groups (n=6) as follows: Group I: Hyflex EDM control group; Group II: WaveOne Gold control group; Group III: Hyflex EDM experimental group; Group IV: WaveOne Gold experimental group. Sterilization using an autoclave was performed thrice for Groups I and II files. The files in Groups III and IV were used in simulated curved canals three times and autoclaved after each use. Atomic force microscopy was used to assess the surface roughness of the files after the first and third autoclave cycles. Results The results showed that, without statistical significance, Hyflex EDM exhibited the highest surface roughness after the first usage among the two file systems. Conclusion It can be concluded that both Hyflex EDM and WaveOne Gold files produced similar levels of surface changes when subjected to multiple usage and autoclaving cycles.

9.
Chem Rec ; : e202400065, 2024 Sep 09.
Artículo en Inglés | MEDLINE | ID: mdl-39248661

RESUMEN

A superhydrophobic surface is defined as having a contact angle exceeding 150 °C, indicating a remarkable ability to repel water. Generally, superhydrophobicity originates from the utilization of low-surface-energy materials with unique micro- and nanostructures. Superhydrophobic surfaces have gained considerable recognition and are widely employed in diverse areas for anti-icing, oil-water separation, anticorrosion, self-cleaning, blood-repellent, and antibacterial applications. These surfaces can greatly enhance industrial processes by yielding significant performance improvements. In this review, we introduce the basic theories that provide a foundation for understanding the hydrophobic properties of superhydrophobic surfaces. We then discuss current techniques for fabricating superhydrophobic coatings, critically analyzing their strengths and limitations. Furthermore, we provide an overview of recent progress in the application of superhydrophobic materials. Finally, we summarize the challenges in developing superhydrophobic materials and future trends in this field. The insights provided by this review can help researchers understand the basic knowledge of superhydrophobic surfaces and obtain the latest progress and challenges in the application of superhydrophobic surfaces. It provides help for further research and practical application of superhydrophobic surfaces.

10.
Int Orthod ; 22(4): 100915, 2024 Sep 05.
Artículo en Inglés | MEDLINE | ID: mdl-39241604

RESUMEN

BACKGROUND: The removal of adhesive remnants after bracket debonding has been shown to cause damaging effects on the enamel surface. This study aimed to investigate the efficacy of stained adhesive remnant removal (ARR) on enamel roughness compared to translucent composite. MATERIAL AND METHODS: Thirty extracted premolar teeth were divided equally into three groups; conventional composite control group (CC), stained composite group (SC) and stained bonding solution group (SB). The buccal surface of each tooth was cleaned, dried and the surface roughness (Ra) was evaluated using a contact prophylometer (T0). After bracket debonding, a high-speed carbide bur under a water-cooling system was used for ARR in one direction and the time consumed for ARR was recorded. After ARR, the second mean Ra values were recorded (T1). The samples were then polished using polishing paste with low-speed rubber cup and the third mean Ra values were recorded (T2). RESULTS: Repeated one-way ANOVA revealed a significant difference in the mean Ra values at T0, T1 and T2 within each group P˂0.05. A statistically significant difference in the changes of the mean Ra values after ARR (T1-T0) and after polishing (T1-T2) was found between the CC group and both SC and SB groups. A significant difference in the time consumed for ARR was found between the three groups with CC group being the most time-consuming group. CONCLUSION: Stained composite material followed by the stained bonding solution provided better visibility during ARR with lower mean Ra values and less time for ARR compared totranslucent composite material.

11.
Cureus ; 16(8): e66371, 2024 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-39246859

RESUMEN

Introduction Zirconia is a widely used restorative material in dentistry due to its superior aesthetic and mechanical properties. The oral cavity is a complex ecosystem with various components, which affect the teeth, as well as artificial restorative materials. Various personal and professional interventions carried out can severely affect the properties of restorative materials, thus altering the longevity of the prosthesis; 1.23% acidulated phosphate fluoride (APF) gel is one such professionally applied topical fluoride agent used to prevent caries. The interaction of this APF gel with highly aesthetic restorative material such as zirconia crowns is unknown. Objective The objective of this study is the evaluation of the surface deterioration of prefabricated zirconia crowns on exposure to deionised water and 1.23% acidulated phosphate fluoride (APF) gel with field emission scanning electron microscope (FE-SEM) and mass loss analysis. Material and method Sixty prefabricated paediatric zirconia crowns were taken, 10 samples were immersed in deionised water, 40 samples were immersed in 1.23% APF gel and 10 samples were used as control. Surface morphology and mass loss analysis were carried out at time intervals of four minutes, 24 hours, 48 hours and 72 hours using FE-SEM and digital weighing machine. Results No visual change was observed in the samples immersed in deionised water at the time interval of 72 hours. There was a marked visual change in samples immersed in 1.23% APF gel at the time interval of four minutes to 72 hours; this change involved a loss of gloss to the appearance of chalkiness. FE-SEM analysis for the control group and samples immersed in deionised water showed a smooth, continuous, undisrupted top layer, while samples immersed in 1.23% APF gel showed changes ranging from surface etching, to pinhole porosities, to crack formation and disruption of the surface depending upon the exposure time. Conclusions On the immersion of zirconia crowns in an aqueous acidic medium of 1.23% APF gel, the crowns showed flaws, imperfections and uneven superficial layers. It has been observed that surface grains are disrupted and micropores have been formed. This degraded superficial surface when undergoes cyclic mechanical loading can accelerate the ageing phenomenon of zirconia. Mechanical forces along with a dynamic electrochemical environment can degrade the material properties of zirconia.

12.
Cureus ; 16(8): e66484, 2024 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-39246916

RESUMEN

Background and objective Silicone has emerged as the most widely accepted material for facial prosthesis fabrication. However, silicone materials have certain limitations. Several techniques have been investigated to lessen the degradation of the polymer, such as the use of nanoparticles and nano-oxides, etc. In this study, we aimed to evaluate the effect of various chemical disinfectants on color stability, hardness, and surface roughness of maxillofacial silicone, after the addition of silver nanoparticles. Materials and methods This was an in vitro study carried out in the Department of Prosthodontics, Sharad Pawar Dental College and Hospital; 80 samples of maxillofacial silicone incorporated with silver nanoparticles (in a concentration of 20 ppm) were fabricated in a mold of 3 x 10 mm dimension disc. The samples were then tested for surface roughness (using a digital roughness tester), Shore A hardness (using a durometer), and color stability (using a spectrophotometer). The samples were then classified into four groups according to various disinfectants used: sodium hypochlorite (1% w/w), chlorhexidine gluconate (0.2%), and neutral soap, and distal water was deemed the control group. After 48 hours, the samples underwent retesting to assess for changes in readings under the same parameters (i.e., surface roughness, Shore A hardness, and color stability) to obtain results, i.e., the samples were tested after fabrication, before immersion, and 48 hours after immersion in disinfectants. Results When taking into account the surface roughness, the maximum roughness value was observed in the sodium hypochlorite group and the least roughness value in distilled water (mean % change of 38.359 to negligible change in the distilled water group). As for the Shore A hardness, the maximum hardness value was seen in the sodium hypochlorite group and the least hardness value in distilled water (mean % change of 15.780 to 2.125 in distilled water). Regarding color stability, the maximum increase in color values was seen in the sodium hypochlorite group (mean: 2.4) followed by the neutral soap group (mean: 1.653); the chlorhexidine gluconate group (mean: -0.287) showed the maximum decrease in color value from the initial to the final phase. Conclusions Based on our findings, surface roughness altered the most when samples were immersed in 1% sodium hypochlorite disinfectant and the least when samples were immersed in neutral soap disinfectant. Shore A hardness altered the most when samples were immersed in 1% sodium hypochlorite disinfectant, but altered the least when samples were immersed in neutral soap disinfectant. Color stability altered the most when samples were immersed in neutral soap disinfectant, but altered the least when samples were immersed in 0.2% chlorhexidine gluconate. Disinfection with neutral soap seems to lead to fewer changes in physical properties (i.e., surface roughness and Shore A hardness) and hence is recommended as a disinfectant for silicone prosthesis. However, our study also showed that 0.2% chlorhexidine gluconate had the least effect on the parameter of color stability, and hence it could be the disinfectant of choice for prostheses with high esthetic requirements.

13.
Biochem Biophys Res Commun ; 734: 150612, 2024 Aug 30.
Artículo en Inglés | MEDLINE | ID: mdl-39217813

RESUMEN

The morphology-dependent antibacterial activity of zinc oxide (ZnO) nanoparticles with three different morphologies, nanowall (NW), nanosphere (NS), and, nanorod (NR) was rigorously investigated to elucidate the influence of shape and size on their performance. Their morphological, surface, and structural characteristics were meticulously analyzed using SEM, BET, and XRD techniques. The antibacterial activity of synthesized ZnO samples was initially investigated and validated through in silico docking studies against nine bacterial strains, specifically targeting 1GCI, 2DCJ, 6KMM and 3T07, 6KVQ, 1MWT from gram-positive Bacillus sp. and Staphylococcus sp. respectively, 6N38, 6CRT, 6GRH from gram-negative E. coli. The docking simulations were performed using Autodock 4.2 software, yielding promising results characterized by negative binding energies, indicative of favorable interactions. The invitro studies were assessed against three same bacteria mentioned above using the disk diffusion method. The results demonstrated a pronounced dependency of antibacterial activity on the surface area, average crystallite size, and surface roughness of ZnO samples. ZnO (NW) exhibited markedly superior antibacterial properties. This enhanced efficacy is attributed to their higher surface area to volume ratio, smaller average crystallite size and increased surface roughness facilitating more efficient interactions with bacterial cell membranes. ZnO (NR) nanoparticles exhibited enhanced antibacterial activity despite minimal surface area.

14.
Dent Mater J ; 2024 Aug 30.
Artículo en Inglés | MEDLINE | ID: mdl-39218687

RESUMEN

This study aimed to investigate the effect of acidulated phosphate fluoride (APF) application on filler-free polymethyl methacrylate (PMMA)-based resin blocks for computer-aided design/computer-aided manufacturing (CAD-CAM), focusing on their use in pediatric crowns. Three types of PMMA-based blocks for CAD-CAM were evaluated, and a composite resin block for CAD-CAM was used as a control. Statistical analysis (p<0.05) of the data revealed that all PMMA-based blocks showed significantly higher gloss levels than the composite resin blocks. Two PMMA-based blocks also demonstrated significantly lower Ra and Sa values. SEM images showed no irregular changes in the surface properties of the PMMA-based blocks compared to those of the composite resin block. These results are significant in meeting the increasing demand for esthetic restorative treatments in pediatrics, where APF is commonly used for caries prevention. PMMA-based resin blocks for CAD-CAM are an effective alternative to prevent esthetic degradation from gloss reduction and plaque accumulation.

15.
Dent Mater J ; 2024 Aug 30.
Artículo en Inglés | MEDLINE | ID: mdl-39218688

RESUMEN

This study investigates the surface quality and bacterial adhesion properties of various dental materials, including indirect composites, veneering composites, direct composites, polyether ether ketone (PEEK), and two millable polymethyl methacrylate (PMMA). Material specimens were processed following manufacturer instructions, initially evaluated for surface roughness and Streptococcus sanguinis (S. sanguinis) adhesion. Subsequently, toothbrushing simulation was employed to simulate aging, and changes in material surfaces were assessed via roughness measurements and bacterial adhesion testing. Prior to simulated aging, direct and indirect composites exhibited the lowest roughness values. However, after the simulated toothbrushing, veneering composites displayed the highest roughness levels. Both PMMA materials demonstrated the highest S. sanguinis adhesion levels, both before and after artificial aging. Interestingly, the indirect composite material showed a reduction in bacterial adhesion following toothbrushing simulation. Surprisingly, this study did not reveal a clear correlation between roughness and bacterial adhesion.

16.
Orthop Traumatol Surg Res ; : 103991, 2024 Sep 07.
Artículo en Inglés | MEDLINE | ID: mdl-39251063

RESUMEN

BACKGROUND: Y-TZP zirconia heads were recalled by the Food and Drug Administration (FDA) in 2001 and zirconia alone was no longer used in orthopedics. Tunnel furnace sintering was suspected of producing defects responsible for early material failure. As Zirconia Toughened Alumina (ZTA) matrices are widely used as bearing material and contain zirconia grains, there remains a need to better understand the in vivo ageing process of zirconia and its clinical implications when the material is produced by batch furnace sintering, the validated sintering process. QUESTIONS/OBJECTIVES: Is there an association between the ageing of batch furnace produced zirconia and THA revision? METHODS: 45 retrieved femoral heads, batch furnace sintered only, were analyzed. Roughness was measured by 3D profilometry, phase transfer by µRaman spectroscopy. Clinical data were compared with material characteristics. RESULTS: Irrespective of the cause of revision, all heads showed a crystallographic phase transition from tetragonal to monoclinic over 19.5%. A correlation was found between the phase change, roughness increase and aseptic loosening, with a threshold set at 24.5% of monoclinic phase. CONCLUSIONS: The ageing process of zirconia may lead to aseptic loosening, which, in the absence of contrary evidence, prohibits its use as the sole component of orthopedic materials. ZTA matrices should be clinically monitored, especially in young patients, and better in vitro modelling needs to be performed. LEVEL OF EVIDENCE: IV; Case series.

17.
Proc Inst Mech Eng H ; : 9544119241277697, 2024 Sep 10.
Artículo en Inglés | MEDLINE | ID: mdl-39257086

RESUMEN

Explant analysis can provide important understanding of how artificial joints perform in the human body. The articulating surfaces of the metacarpal head and the radius cup from a chromium nitride coated metal-on-metal Motec wrist implant were analysed. Due to bone resorption and aseptic loosening, the implant was removed after 6 years in the patient, and metallosis was observed during removal. Visually, some areas of the articulating surfaces appeared polished, others were dulled. A chemical composition analysis of the metacarpal head showed that the polished surfaces were chromium rich, implying this surface was the original chromium nitride coating, whereas the dulled surfaces were cobalt rich, indicating the underlying cobalt chromium substrate. In addition, the underlying cobalt chromium substrate was an order of magnitude rougher than the polished surface, indicating the scale of damage to it. It is speculated that the loss of the coating, and the subsequent damage to the underlying substrate due to a third-body wear process, led to osteolysis and the metallosis seen at revision surgery.

18.
Cureus ; 16(7): e64009, 2024 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-39109127

RESUMEN

BACKGROUND AND OBJECTIVES: Surface roughness is one of the most important factors that play an important role in increasing the connection between the surface of the tooth and the applied restoration. Due to the increased interest in zirconia and the improvement of its mechanical and aesthetic properties, studies have increased that work to improve and increase its surface roughness so that it can be used as a veneer in the future. This study aims to compare the effect of two types of lasers on the surface of highly transparent zirconia to evaluate the surface roughness resulting from the two techniques. METHODOLOGY: The study sample consisted of 20 ceramic cubes made of translucent zirconia (DD cubeX2, Dental Direct, Germany). It was made using a CAD-CAM Zircodenta device (Imes-Icore, Germany) and a zirconia sintering furnace (Imes-Icore, Germany). The study sample was divided into two groups; the first group consisted of 10 cubes exposed to Nd:YAG laser and the second group consisted of 10 discs exposed to continuous wave CO2 laser. The surface roughness test was conducted for the study samples in each of the groups using a surface roughness tester. Data were collected and analyzed using SPSS v25 software. RESULTS: The surface roughness was measured and its mean was 1.208±0.22 in the Nd:YAG laser group and 0.809±0.21 in the CO2 laser group. There was a significant difference between the study groups according to the independent sample T-test. CONCLUSION: This study concluded that the Nd:YAG laser surface roughens of zirconia is greater than the continuous wave CO2 laser, with a substantially significant difference.

19.
Appl Spectrosc ; : 37028241267938, 2024 Aug 02.
Artículo en Inglés | MEDLINE | ID: mdl-39094005

RESUMEN

This study investigates the combined effects of nanoscale surface roughness and electron-phonon interaction on the vibrational modes of cadmium telluride (CdTe) using resonant Raman spectroscopy. Raman spectra simulations aided in identifying the active phonon modes and their dependence on roughness. Our results reveal that increasing surface roughness leads to an asymmetric line shape in the first-order longitudinal optical (1LO) phonon mode, attributed to an increase in the electron-phonon interaction. This asymmetry broadens the entire Raman spectrum. Conversely, the overtone (second-order longitudinal optical [2LO]) mode exhibits a symmetrical line shape that intensifies with roughness. Additionally, we identify and discuss the contributions of surface optical phonon mode and multiphonon modes to the Raman spectra, highlighting their dependence on roughness. This work offers a deeper understanding of how surface roughness and electron-phonon scattering influence the line shape of CdTe resonant Raman spectra, providing valuable insights into its vibrational properties.

20.
Discov Nano ; 19(1): 123, 2024 Aug 06.
Artículo en Inglés | MEDLINE | ID: mdl-39105979

RESUMEN

Resin cement integrated with zein-incorporated magnesium oxide nanoparticles has previously been found to inhibit oral microbes and decrease bacterial biofilm. However, the bond strength and surface features of this biomaterial have yet to be investigated. The objective of this study was to evaluate the shear bond strength, mode of fracture, and surface roughness of resin cement modified with zein-incorporated magnesium oxide nanoparticles. Characterization of the cement was performed by X-ray diffraction, field emission scanning electron microscopy, and Fourier transform infrared spectroscopy. 126 human teeth were divided into 3 groups and cemented to lithium disilicate ceramic using resin cement with zein-incorporated magnesium oxide nanoparticles at concentrations of 0%, 1%, and 2% (n = 42). 21 samples of each group were subjected to the shear bond strength test, while the other 21 underwent thermocycling for 10,000 cycles before the test, after which all samples were evaluated for the mode of fracture. To assess surface roughness, resin cement disks were analyzed by a profilometer before and after undergoing thermocycling for 10,000 cycles. The shear bond strength of the cement with 1% and 2% nanoparticles was significantly higher than the control before thermocycling. The mode of fracture was found to be mainly adhesive with all groups, with the unmodified cement presenting the highest cohesive failure. There was no significant difference in surface roughness between the groups before or after thermocycling. The addition of zein-incorporated magnesium oxide nanoparticles to resin cement improved or maintained the shear bond strength and surface roughness of the resin cement.

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