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1.
Chemosphere ; 336: 139227, 2023 Sep.
Artículo en Inglés | MEDLINE | ID: mdl-37327825

RESUMEN

We report on the synthesis of silver oxide/reduced graphene oxide nanocomposites (Ag/rGO NCs) using a hydrothermal technique. This paper presents a simple method for synthesizing Ag/rGO hybrid nanocomposites, which can be used for environmentally treating hazardous organic pollutants. The photocatalytic degradation of model artificial Rhodamine B dye and bisphenol A was assessed under visible light illumination. The crystallinity, binding energy, and surface morphologies of the synthesized samples were determined. The silver oxide loading sample resulted in a decrease in the rGO crystallite size. SEM and TEM images demonstrate strong adhesion of the Ag NPs to the rGO sheets. XPS analysis validated the binding energy and elemental composition of the Ag/rGO hybrid nanocomposites. The objective of the experiment was to enhance the photocatalytic efficiency of rGO in the visible region using Ag nanoparticles. The synthesized nanocomposites in the visible region exhibited good photodegradation percentages of approximately 97.5% and 98.6% after 120 min of irradiation for pure rGO, Ag NPs, and Ag/rGO nanohybrid, respectively. Furthermore, the Ag/rGO nanohybrid maintained their degradation ability for up to three cycles. The synthesized Ag/rGO nanohybrid demonstrated enhanced photocatalytic activity, expanding their potential for environmental remediation. Based on the investigations, Ag/rGO nanohybrid proved to be an effective photocatalyst and holds promise as an ideal material for future applications in preventing water pollution.


Asunto(s)
Nanopartículas del Metal , Nanopartículas del Metal/química , Plata , Luz , Agua
2.
Sensors (Basel) ; 19(13)2019 Jul 05.
Artículo en Inglés | MEDLINE | ID: mdl-31284475

RESUMEN

Graphene and its chemically exfoliated derivatives-GO and rGO-are the key members of graphene family materials (GFM). The atomically thick crystal structure and the large continuous π conjugate of graphene imparts it with unique electrical, mechanical, optical, thermal, and chemical properties. Although those properties of GO and rGO are compromised, they have better scalability and chemical tunability. All GFMs can be subject to noncovalent modification due to the large basal plane. Besides, they have satisfying biocompatibility. Thus, GFMs are promising materials for biological, chemical and mechanical sensors. The present review summarizes how to incorporate GFMs into different sensing system including fluorescence aptamer-based sensors, field-effect transistors (FET), and electrochemical sensors, as well as, how to covalently and/or non-covalently modify GFMs to achieve various detection purpose. Sensing mechanisms and fabrication strategies that will influence the sensitivity of different sensing system are also reviewed.


Asunto(s)
Técnicas Biosensibles/instrumentación , Técnicas Electroquímicas/instrumentación , Grafito/química , Transistores Electrónicos , Acústica/instrumentación , Animales , Antibacterianos/química , Antibacterianos/farmacología , Técnicas Biosensibles/métodos , Técnicas Electroquímicas/métodos , Fluorescencia , Gases/análisis , Grafito/farmacología , Grafito/toxicidad , Humanos
3.
Spectrochim Acta A Mol Biomol Spectrosc ; 204: 603-610, 2018 Nov 05.
Artículo en Inglés | MEDLINE | ID: mdl-29980062

RESUMEN

In the present report, rGO sheets (rG1) and disk (rG2) like structures of reduced graphene oxide (rGO) were synthesized using sugar cane juice as green reducing agent. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier-transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-vis.) spectroscopy and photoluminescence (PL) spectroscopy techniques. The transition of electrons localized in different sized sub-domain of the sp2 bonded carbons having different values of highest occupied molecular orbital (HOMO) -lowest unoccupied molecular orbital (LUMO) gap may likely to be responsible for the observed PL emission in rG1 and rG2 at different excitation wavelengths. The rG1 and rG2 were also used as photocatalyst materials for the degradation of phenanthrene (PHE) under the UV irradiation. The rG2 shows better photocatalytic degradation compared to rG1 by degrading the PHE up to 30%.


Asunto(s)
Grafito/química , Fenantrenos , Sustancias Reductoras/química , Saccharum/química , Tecnología Química Verde , Óxidos/química , Fenantrenos/análisis , Fenantrenos/química , Fenantrenos/efectos de la radiación , Fotólisis , Extractos Vegetales/química , Espectroscopía Infrarroja por Transformada de Fourier
4.
Adv Mater ; : e1802733, 2018 Jul 19.
Artículo en Inglés | MEDLINE | ID: mdl-30024065

RESUMEN

The goal of this work is to develop an inexpensive low-temperature process that provides polymer-free, high-strength, high-toughness, electrically conducting sheets of reduced graphene oxide (rGO). To develop this process, we have evaluated the mechanical and electrical properties resulting from the application of an ionic bonding agent (Cr3+ ), a π-π bonding agent comprising pyrene end groups, and their combinations for enhancing the performance of rGO sheets. When only one bonding agent was used, the π-π bonding agent is much more effective than the ionic bonding agent for improving both the mechanical and electrical properties of rGO sheets. However, the successive application of ionic bonding and π-π bonding agents maximizes tensile strength, toughness, long-term electrical stability in various corrosive solutions, and resistance to mechanical abuse and ultrasonic dissolution. Using a combination of ionic bonding and π-π bonding agents, high tensile strength (821 MPa), high toughness (20 MJ m-3 ), and electrical conductivity (416 S cm-1 ) were obtained, as well as remarkable retention of mechanical and electrical properties during ultrasonication and mechanical cycling by both sheet stretch and sheet folding, suggesting high potential for applications in aerospace and flexible electronics.

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