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1.
Sensors (Basel) ; 24(17)2024 Aug 28.
Artículo en Inglés | MEDLINE | ID: mdl-39275495

RESUMEN

This article introduces a novel petal-like SAW topology insulator, which can transmit sound waves with low loss and high flexibility in an ultra-wide frequency band by simultaneously adjusting multiple structural parameters of phononic crystals. Using finite element analysis, it was found that adjusting these parameters can generate a broadband gap of 55.8-65.7 MHz. This structure can also achieve defect immunity and sharp bending in waveguide transmission. When this topology insulator is applied to resonators, compared to traditional designs, the insertion loss is reduced by 22 dB, the on-load quality factor is increased by 227%, the off-load quality factor is increased by 1024.5%, and the quality sensitivity is improved by 3.7 times compared to bare devices.

2.
Adv Sci (Weinh) ; : e2405165, 2024 Aug 09.
Artículo en Inglés | MEDLINE | ID: mdl-39120061

RESUMEN

Triboelectric nanogenerators (TENGs) have recently emerged as a promising technology for efficient water wave energy harvesting. However, there is a paucity of clear guidance regarding the optimal designs of TENGs and their shells to achieve efficient absorption and conversion of water wave energy in real random waves. Herein, from the perspective of wave-body interaction and energy transfer, this paper proposes a structural quality factor (Qunit) for the quantitative evaluation of both the motion of floating triboelectric nanogenerator (Flo-TENG) shells and their capability to absorb and convert water wave energy efficiently. The factor is further subdivided into the amplitude structural quality factor (Qacc), which characterizes shell motion amplitude, and the frequency structural quality factor (Qf), which describes shell motion frequency. This paper systematically investigates the impact of various shell parameters such as bow shapes, curvatures, inclinations, and immersion ratios on Qacc and Qf. The findings indicate that variations in shell shape result in distinct Qunit values along different axial directions of wave propagation. These variations directly influence energy absorption efficiency in these directions. These results provide fundamental guidance for the design of high-performance Flo-TENG shells and the selection of internal energy harvesting directions to enable more efficient energy conversion.

3.
Sci Rep ; 14(1): 18861, 2024 Aug 14.
Artículo en Inglés | MEDLINE | ID: mdl-39143263

RESUMEN

The microstructure of concrete can be affected by many factors, from non-destructive environmental factors through to destructive damage induced by transient stresses. Coda wave interferometry is a technique that is sensitive enough to detect weak changes within concrete by evaluating the ultrasonic signal perturbation compared to a reference state. As concrete microstructure is sensitive to many factors, it is important to separate their contributions to the observables. In this study, we characterize the relationships between the concrete elastic and inelastic properties, and temperature and relative humidity. We confirm previous theoretical studies that found a linear relationship between temperature changes and velocity variation of the ultrasonic waves for a given concrete mix, and provide scaling factors per Kelvin for multiple settings. We also confirm an anti-correlation with relative humidity using long-term conditioning. Furthermore, we explore beyond the existing studies to establish the relationship linking humidity and temperature changes to ultrasonic wave attenuation.

4.
Sensors (Basel) ; 24(15)2024 Aug 04.
Artículo en Inglés | MEDLINE | ID: mdl-39124094

RESUMEN

Graphene-based surface plasmon resonance (SPR) biosensors have emerged as a promising technology for the highly sensitive and accurate detection of biomolecules. This study presents a comprehensive theoretical analysis of graphene-based SPR biosensors, focusing on configurations with single and bimetallic metallic layers. In this study, we investigated the impact of various metallic substrates, including gold and silver, and the number of graphene layers on key performance metrics: sensitivity of detection, detection accuracy, and quality factor. Our findings reveal that configurations with graphene first supported on gold exhibit superior performance, with sensitivity of detection enhancements up to 30% for ten graphene layers. In contrast, silver-supported configurations, while demonstrating high sensitivity, face challenges in maintaining detection accuracy. Additionally, reducing the thickness of metallic layers by 30% optimizes light coupling and enhances sensor performance. These insights highlight the significant potential of graphene-based SPR biosensors in achieving high sensitivity of detection and reliability, paving the way for their application in diverse biosensing technologies. Our findings pretend to motivate future research focusing on optimizing metallic layer thickness, improving the stability of silver-supported configurations, and experimentally validating the theoretical findings to further advance the development of high-performance SPR biosensors.


Asunto(s)
Técnicas Biosensibles , Oro , Grafito , Plata , Resonancia por Plasmón de Superficie , Grafito/química , Resonancia por Plasmón de Superficie/métodos , Plata/química , Técnicas Biosensibles/métodos , Técnicas Biosensibles/instrumentación , Oro/química
5.
ACS Nano ; 18(32): 21211-21220, 2024 Aug 13.
Artículo en Inglés | MEDLINE | ID: mdl-39079002

RESUMEN

In photonics, achieving high-quality (Q) resonance is crucial for high-sensitivity devices used in applications, such as switching, sensing, and lasing. However, high-Q resonances are highly susceptible to internal losses of plasmonic devices, impeding their integration into broader systems across terahertz and visible light bands. Here, we overcome this challenge by proposing a low-Q plasmonic metasurface for ultrasensitive terahertz (THz) switching and sensing. Theoretically, we reveal an approach to constructing a low-Q resonator possessing high sensitivity to nonradiative losses. Leveraging this mechanism, we design a highly sensitive plasmonic metasurface induced by strong coupling between a quasi-bound state in the continuum and a dipole mode. By hybridizing with the germanium layer, the metadevice exhibits an ultralow pump threshold of 192 µJ/cm2 and an ultrafast switching cycle time of 7 ps. Furthermore, it also shows a high sensitivity of 224 GHz/RIU in refractive index sensing. The proposed paradigm of constructing low-Q and high-sensitivity photonic devices can be applied to biosensing, wide-band filters, and sensitive modulators.

6.
Nanomaterials (Basel) ; 14(13)2024 Jul 03.
Artículo en Inglés | MEDLINE | ID: mdl-38998749

RESUMEN

The vibrations in functionally graded porous Cu-Si microcantilever beams are investigated based on physical neutral plane theory, modified coupled stress theory, and scale distribution theory (MCST&SDT). Porous microcantilever beams define four pore distributions. Considering the physical neutral plane theory, the material properties of the beams are computed through four different power-law distributions. The material properties of microcantilever beams are corrected by scale effects based on modified coupled stress theory. Considering the fluid driving force, the amplitude-frequency response spectra and resonant frequencies of the porous microcantilever beam in three different fluids are obtained based on the Euler-Bernoulli beam theory. The quality factors of porous microcantilever beams in three different fluids are derived by estimating the equation. The computational analysis shows that the presence of pores in microcantilever beams leads to a decrease in Young's modulus. Different pore distributions affect the material properties to different degrees. The gain effect of the scale effect is weakened, but the one-dimensional temperature field and amplitude-frequency response spectra show an increasing trend. The quality factor is decreased by porosity, and the degree of influence of porosity increases as the beam thickness increases. The gradient factor n has a greater effect on the resonant frequency. The effect of porosity on the resonant frequency is negatively correlated when the gradient factor is small (n<1) but positively correlated when the gradient factor is large (n>1).

7.
ACS Nano ; 18(27): 17492-17499, 2024 Jul 09.
Artículo en Inglés | MEDLINE | ID: mdl-38940269

RESUMEN

The optimization of nanoscale optical devices and structures will enable the exquisite control of planar optical fields. Polariton manipulation is the primary strategy in play. In two-dimensional heterostructures, the ability to excite mixed optical modes offers an additional control in device design. Phonon polaritons in hexagonal boron nitride have been a common system explored for the control of near-infrared radiation. Their hybridization with graphene plasmons makes these mixed phonon polariton modes in hexagonal boron nitride more appealing in terms of enabling active control of electrodynamic properties with a reduction of propagation losses. Optical resonators can be added to confine these hybridized plasmon-phonon polaritons deeply into the subwavelength regime, with these structures featuring high quality factors. Here, we show a scalable approach for the design and fabrication of heterostructure nanodisc resonators patterned in chemical vapor deposition-grown monolayer graphene and h-BN sheets. Real-space mid-infrared nanoimaging reveals the nature of hybridized polaritons in the heterostructures. We simulate and experimentally demonstrate localized hybridized polariton modes in heterostructure nanodisc resonators and demonstrate that those nanodiscs can collectively couple to the waveguide. High quality factors for the nanodiscs are measured with nanoscale Fourier transform infrared spectroscopy. Our results offer practical strategies to realize scalable nanophotonic devices utilizing low-loss hybridized polaritons for applications such as on-chip optical components.

8.
Micromachines (Basel) ; 15(5)2024 Apr 27.
Artículo en Inglés | MEDLINE | ID: mdl-38793154

RESUMEN

This paper presents a biosensor based on the resonant optical tunneling effect (ROTE) for detecting a carcinoembryonic antigen (CEA). In this design, sensing is accomplished through the interaction of the evanescent wave with the CEA immobilized on the sensor's surface. When CEA binds to the anti-CEA, it alters the effective refractive index (RI) on the sensor's surface, leading to shifts in wavelength. This shift can be identified through the cascade coupling of the FP cavity and ROTE cavity in the same mode. Experimental results further show that the shift in resonance wavelength increases with the concentration of CEA. The biosensor responded linearly to CEA concentrations ranging from 1 to 5 ng/mL with a limit of detection (LOD) of 0.5 ng/mL and a total Q factor of 9500. This research introduces a new avenue for identifying biomolecules and cancer biomarkers, which are crucial for early cancer detection.

9.
Artículo en Inglés | MEDLINE | ID: mdl-38652647

RESUMEN

The complex resonance of dielectric quality factor Q, combined with a capacitance tunability n higher than 3:1 without any dispersion, was achieved in the voltage-tunable interdigital capacitors (IDCs) based on epitaxial Ba0.8Sr0.2TiO3 ferroelectric thin films across the microwave L (1-2 GHz), S (2-4 GHz), and C (4-8 GHz) bands at room temperature. The resonant Q and n features were driven by the microwave responses of the ferroelectric nanodomains engineered in the films. To promote their application in space radiation environments, the evolutions of Q and n both as functions of frequency f (1-8 GHz) and applied electric field E (0-240 kV/cm) were systematically investigated under a series of gamma-ray irradiations up to 100 kGy. The robust capacitance tunability was accompanied by the emergence of an additional Q resonance at 2.3 GHz in most post-irradiated devices, which is ascribed to extra polar nanoregions of expanded surface lattices associated with oxygen vacancies induced by irradiations.

10.
J Chromatogr A ; 1721: 464848, 2024 Apr 26.
Artículo en Inglés | MEDLINE | ID: mdl-38569299

RESUMEN

The largest peak capacity (n) that LC analysis can generate in isocratic or gradient elution analysis of a given sample in a given time at a given pressure is proportional to the quality factor (qmax) of its column structure. In this study, the multi-channel structures with open pseudo-planar channels (OPPC) and open circular channels (OCC) where compared with PC2 - a typical core-shell column packed with 2 µm particles. These columns have qmax of 1.27, 1.17 and 0.41, respectively. The former two qmax are the highest among all known column structures - about 3 times higher than qmax of PC2. This means that the OPPC and OCC can generate about 3 times higher n compared to what a PC2 can in the same analysis time (tanal) at the same pressure, or they require about 81 times shorter tanal (81 is the 4th power of 3) to generate the same n as a PC2 can at the same pressure. However, while PC2 is a commercially available column, there are substantial challenges in manufacturing the OPPC and OCC that can compete with PC2 in practical applications. In order to be competitive with PC2, the OPPC and OCC should have sub-1µm characteristic dimensions (e.g., the inter-pillar distance, g, in OPPC-based pillar array columns, internal diameters of OCC). Thus, in order to compete with PC2 in one scenario, an OPPC requires g ≤ 0.14 µm. Additionally, to be competitive with PC2, OPPC and OCC should be able to sustain the same high pressure. Highlighting the challenges of their design and manufacturing might help to develop the manufacturable columns substantially superior to the packed ones.


Asunto(s)
Tamaño de la Partícula , Cromatografía Líquida de Alta Presión/métodos , Porosidad
11.
J Magn Reson Imaging ; 60(2): 777-788, 2024 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-38305462

RESUMEN

BACKGROUND: The minimum admissible detuning efficiency (DE) of a receive coil is an essential parameter for coil designers. A receive coil with inefficient detuning leads to inhomogeneous B1 during excitation. Previously proposed criteria for quantifying the DE rely on indirect measurements and are difficult to implement. PURPOSE: To present an alternative method to quantify the DE of receive-only surface coils. STUDY TYPE: Theoretical study supported by simulations and phantom experiments. PHANTOMS: Uniform spherical (100 mm diameter) and cylindrical (66 mm diameter) phantoms. FIELD STRENGTH/SEQUENCE: Dual repetition time B1 mapping sequence at 1.5T, and Bloch-Siegert shift B1 mapping sequence at 3.0T. ASSESSMENT: One non-planar (80 × 43 mm2) and two planar (40 and 57 mm diameter) surface coils were built. Theoretical analysis was performed to determine the minimum DE required to avoid B1 distortions. Experimental B1 maps were acquired for the non-planar and planar surface coils at both 1.5T and 3.0T and visually compared with simulated B1 maps to assess the validity of the theoretical analysis. STATISTICAL TESTS: None. RESULTS: Based on the theoretical analysis, the proposed minimum admissible DE, defined as DEthr = 20 Log (Q) + 13 dB, depended only on the quality factor (Q) of the coil and was independent of coil area and field strength. Simulations and phantom experiments showed that when the DE was higher than this minimum threshold level, the B1 field generated by the transmission coil was not modified by the receive coil. DATA CONCLUSION: The proposed criterion for assessing the DE is simple to measure, and does not depend on the area of the coil or on the magnetic field strength, up to 3T. Experimental and simulated B1 maps confirmed that detuning efficiencies above the theoretically derived minimal admissible DE resulted in a non-distorted B1 field. EVIDENCE LEVEL: 2 TECHNICAL EFFICACY: Stage 1.


Asunto(s)
Simulación por Computador , Diseño de Equipo , Imagen por Resonancia Magnética , Fantasmas de Imagen , Imagen por Resonancia Magnética/instrumentación , Reproducibilidad de los Resultados , Humanos , Procesamiento de Imagen Asistido por Computador , Algoritmos , Modelos Teóricos
12.
Sensors (Basel) ; 24(4)2024 Feb 18.
Artículo en Inglés | MEDLINE | ID: mdl-38400481

RESUMEN

Resonators are passive time-invariant components that do not produce a frequency shift. However, they respond to an excitation signal close to resonance with an oscillation at their natural frequencies with exponentially decreasing amplitudes. If resonators are connected to antennas, they form purely passive sensors that can be read remotely. In this work, we model the external excitation of a resonator with different excitation signals and its subsequent decay characteristics analytically as well as numerically. The analytical modeling explains the properties of the resonator during transient response and decay behavior. The analytical modeling clarifies how natural oscillations are generated in a linear time-invariant system, even if their spectrum was not included in the stimulation spectrum. In addition, it enables the readout signals to be optimized in terms of duration and bandwidth.

13.
Nanomaterials (Basel) ; 14(2)2024 Jan 05.
Artículo en Inglés | MEDLINE | ID: mdl-38251095

RESUMEN

In aviation, aerospace, and other fields, nanomechanical resonators could offer excellent sensing performance. Among these, graphene resonators, as a new sensitive unit, are expected to offer very high mass and force sensitivity due to their extremely thin thickness. However, at present, the quality factor of graphene resonators at room temperature is generally low, which limits the performance improvement and further application of graphene resonators. Enhancing the quality factor of graphene resonators has emerged as a pressing research concern. In a previous study, we have proposed a new mechanism to reduce the energy dissipation of graphene resonators by utilizing phononic crystal soft-supported structures. We verified its feasibility through theoretical analysis and simulations. This article focuses on the fabrication of a phononic crystal soft-supported graphene resonator. In order to address the issues of easy fracture, deformation, and low success rate in the fabrication of phononic crystal soft-supported graphene resonators, we have studied key processes for graphene suspension release and focused ion beam etching. Through parameter optimization, finally, we have obtained phononic crystal soft-supported graphene resonators with varying cycles and pore sizes. Finally, we designed an optical excitation and detection platform based on Fabry-Pérot interference principle and explored the impact of laser power and spot size on phononic crystal soft-supported graphene resonators.

14.
Adv Mater ; 36(5): e2306513, 2024 Feb.
Artículo en Inglés | MEDLINE | ID: mdl-37823403

RESUMEN

For decades, mechanical resonators with high sensitivity have been realized using thin-film materials under high tensile loads. Although there are remarkable strides in achieving low-dissipation mechanical sensors by utilizing high tensile stress, the performance of even the best strategy is limited by the tensile fracture strength of the resonator materials. In this study, a wafer-scale amorphous thin film is uncovered, which has the highest ultimate tensile strength ever measured for a nanostructured amorphous material. This silicon carbide (SiC) material exhibits an ultimate tensile strength of over 10 GPa, reaching the regime reserved for strong crystalline materials and approaching levels experimentally shown in graphene nanoribbons. Amorphous SiC strings with high aspect ratios are fabricated, with mechanical modes exceeding quality factors 108 at room temperature, the highest value achieves among SiC resonators. These performances are demonstrated faithfully after characterizing the mechanical properties of the thin film using the resonance behaviors of free-standing resonators. This robust thin-film material has significant potential for applications in nanomechanical sensors, solar cells, biological applications, space exploration, and other areas requiring strength and stability in dynamic environments. The findings of this study open up new possibilities for the use of amorphous thin-film materials in high-performance applications.

15.
ACS Nano ; 18(1): 506-514, 2024 Jan 09.
Artículo en Inglés | MEDLINE | ID: mdl-38109362

RESUMEN

Manipulation of magnetic dipole emission with resonant photonic nanostructures is of great interest for both fundamental research and applications. However, obtaining selective control over the emission properties of magnetic dipole transitions is challenging, as they usually occur within a manifold of spectrally close emission lines associated with different spin states of the involved electronic levels. Here we demonstrate spectrally selective directional tailoring of magnetic dipole emission using designed photonic nanostructures featuring a high quality factor. Specifically, we employ a hybrid nanoscale optical system consisting of a Eu3+ compound coupled to a designed broken-symmetry TiO2 metasurface to demonstrate directional color routing of the compound's emission through its distinct electric and magnetic-dominated electronic transition channels. Using low numerical aperture collection optics, we achieve a fluorescence signal enhancement of up to 33.13 for the magnetic-dominated dipole transition at 590 nm when it spectrally overlaps with a spectrally narrow resonance of the metasurface. This makes the, usually weak, magnetic dipole transition the most intense spectral line in our recorded fluorescence spectra. By studying the directional emission properties for the coupled system using Fourier imaging and time-resolved fluorescence measurements, we demonstrate that the high-quality-factor modes in the metasurface enable free-space light routing, where forward-directed emission is established for the magnetic-dominated dipole transition, whereas the light emitted via the electric dipole transition is mainly directed sideways. Our results underpin the importance of magnetic light-matter interactions as an additional degree of freedom in photonic and optoelectronic systems. Moreover, they facilitate the development of spectrometer-free and highly integrated nanophotonic imaging, sensing, and probing devices.

16.
Nano Lett ; 23(24): 11601-11607, 2023 Dec 27.
Artículo en Inglés | MEDLINE | ID: mdl-38063776

RESUMEN

Two-dimensional (2D) semiconductors have attracted great attention as a novel class of gain materials for low-threshold, on-chip coherent light sources. Despite several experimental reports on lasing, the underlying gain mechanism of 2D materials remains elusive due to a lack of key information, including modal gain and the confinement factor. Here, we demonstrate a novel approach to directly determine the absorption coefficient of monolayer WS2 by characterizing the whispering gallery modes in a van der Waals microdisk cavity. By exploiting the cavity's high intrinsic quality factor of 2.5 × 104, the absorption coefficient spectrum and confinement factor are experimentally resolved with unprecedented accuracy. The excitonic gain reduces the WS2 absorption coefficient by 2 × 104 cm-1 at room temperature, and the experimental confinement factor is found to agree with the theoretical prediction. These results are essential for unveiling the gain mechanism in emergent, low-threshold 2D-semiconductor-based laser devices.

17.
Nanomaterials (Basel) ; 13(24)2023 Dec 14.
Artículo en Inglés | MEDLINE | ID: mdl-38133032

RESUMEN

MXenes, as a typical graphene-like material, excels in the realm of humidity sensing owing to its two-dimensional layer structure, high electrical conductivity, tunable chemical properties, hydrophilicity, and large specific surface area. This study proposed a quartz crystal microbalance (QCM) humidity sensor using a nanochitin/Ti3C2Tx MXene composite as a humidity-sensing material. The morphology, nanostructure, and elemental composition of nanochitin, Ti3C2Tx MXene, and nanochitin/Ti3C2Tx MXene composite materials were characterized using transmission electron microscopy, Fourier transform infrared spectroscopy, and X-ray diffraction. Compared to the pure Ti3C2Tx MXene-coated QCM humidity sensor, the nanochitin/Ti3C2Tx MXene-coated QCM humidity sensor exhibited a higher sensitivity (20.54 Hz/%RH) in the humidity range of 11.3% to 97.3%. The nanochitin/Ti3C2Tx Mxene-coated QCM humidity sensor also demonstrated low humidity hysteresis (2.12%RH), very fast response/recovery times (4.4/4.1 s), a high quality factor (37 k), and excellent repeatability and sustained stability over time. Eventually, a bimodal exponential kinetics adsorption model was utilized for the analysis of the response mechanism of the nanochitin/Ti3C2Tx MXene composite material-based QCM humidity sensor. This study provides new ideas for optimizing the moisture-sensitive performance of MXene-based QCM humidity sensors.

18.
Micromachines (Basel) ; 14(12)2023 Nov 22.
Artículo en Inglés | MEDLINE | ID: mdl-38138307

RESUMEN

The unique double-cantilever beam structure and vibration mode of the tuning fork enable the measuring of fluid density and viscosity synchronously in a decoupling manner. Therefore, it is widely employed in oil and gas development and in petrochemical, food, textile, and other industries. In this paper, quality factors are used to characterize the energy losses of lithium niobate tuning forks when vibrating in a fluid, and the influence parameters, such as length, width, and thickness of the tuning fork arm, etc., of different quality factors are examined with a focus on the viscous quality factor of the fluid. The optimized design of lithium niobate tuning fork dimensions is carried out on this premise, and the analytical solution of the optimal dimension of the lithium niobate tuning fork in the air is obtained. Secondly, the optimal dimension of the lithium niobate tuning fork in fluids is given out by finite element simulation, and the sensitivity of the optimized fork to the viscosity of fluids is investigated. The results show that the optimized tuning fork has a higher quality factor, and thus has a larger parameter measurement range as well as being more sensitive to the change in the fluid density and viscosity. Therefore, the results are of great significance for guiding the preparation and practical application of lithium niobate tuning forks.

19.
Micromachines (Basel) ; 14(11)2023 Oct 31.
Artículo en Inglés | MEDLINE | ID: mdl-38004892

RESUMEN

The quality factor of microelectromechanical resonators is a crucial performance metric and has thus been the subject of numerous studies aimed at maximizing its value by minimizing the anchor loss. This work presents a study on the effect of elastic wave reflectors on the quality factor of MEMS clamped-clamped flexural beam resonators. The elastic wave reflectors are a series of holes created by trenches in the silicon substrate of the resonators. In this regard, four different shapes of arrayed holes are considered, i.e., two sizes of squares and two half circles with different directions are positioned in proximity to the anchors. The impact of these shapes on the quality factor is examined through both numerical simulations and experimental analysis. A 2D in-plane wave propagation model with a low-reflecting fixed boundary condition was used in the numerical simulation to predict the behavior, and the MEMS resonator prototypes were fabricated using a commercially available micro-fabrication process to validate the findings. Notably, the research identifies that half-circle-shaped holes with their curved sides facing the anchors yield the most promising results. With these reflectors, the quality factor of the resonator is increased by a factor of 1.70× in air or 1.72× in vacuum.

20.
Artículo en Inglés | MEDLINE | ID: mdl-37922369

RESUMEN

BiScO3-PbTiO3-based ceramics show great potential in high-temperature piezoelectric applications. However, their high dielectric loss tan δ and low mechanical quality factor Qm have to be optimized. In this paper, a ceramic system of (1-y)Bi(Sc0.975Zr0.025)O3-yPb(Ti1-xNix)O3 (BSZ-yPT-xNi, x = 0, 0.015, 0.025, and 0.035 and y = 0.62, 0.63, 0.64, and 0.65) was systematically investigated. Increase in x or y values leads to the enhancement of the tetragonal phase and tetragonal lattice distortion. The rhombohedral/tetragonal morphotropic phase boundary (MPB) locates in the vicinity of y = 0.64 for the x = 0 and 0.015 samples, and y = 0.63 for the x = 0.025 and 0.035 samples. For these MPB samples, the substitution of Ni2+ for Ti4+ causes domain refinement, evolving from the submicrometer lamellar domains to hierarchical domains, and finally to the high-density stripe-like nanodomains, which benefits the domain wall motion and makes the coercive field reduced. However, the alignment of defect dipoles (NiTi''-VO••) after the sufficient poling and aging treatment induces the noticeable internal bias field, which increases with the addition of Ni2+. Apparent piezoelectric "hardening" occurred, evidenced by the increase in Qm and the reduction in tan δ. Among the MPB samples, the x = 0.025/y = 0.63 ceramic shows the superior comprehensive electromechanical performance with the d33 of 380 pC/N, kt of 0.51, Qm of 112, and tan δ of 0.010. Besides, excellent temperature stability was achieved with the d33 of 367-380 pC/N, Qm of 106-112, and tan δ ≤ 0.010 in the temperature range of 25-250 °C.

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