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The addition of carbon-rich materials, such as raw feedstocks (RAW) and biochars, to agricultural soils is on the rise. This activity has many advantages, such as improving fertility, increasing water retention, and sequestering carbon. However, they can also increase the sorption of residual herbicides in the soil, reducing the effectiveness of weed control. Thus, the objective of this study was to evaluate soil improvement and the sorption-desorption process of diclosulam in soil unamended and amended with RAW from olive stone and their biochars produced in two pyrolysis temperatures (300 and 500 °C). Oxisol was used in this study, unamended and amended with RAW and biochars (BC300 and BC500) in a rate of 10% (w w-1). The sorption-desorption process was assessed by batch-equilibrium experiments and the analysis was performed using high-performance liquid chromatography (HPLC). The addition of the three materials to the soil increased the contents of pH, organic carbon, P, K, Ca, Mg, Zn, Fe, Mn, Cu, B, cation exchange capacity, base saturation and decreased H + Al. The unamended soil had Kf (Freundlich sorption coefficient) values of diclosulam sorption and desorption of 1.56 and 12.93 mg(1 - 1/n) L1/n Kg-1, respectively. Unamended soil sorbed 30.60% and desorbed 13.40% of herbicide. Soil amended with RAW, BC300, and BC500 sorbed 31.92, 49.88, and 30.93% of diclosulam and desorbed 13.33, 11.67, and 11.16%, respectively. The addition of RAW and biochars from olive stone has the potential to change the soil fertility, but does not interfere with the bioavailability of diclosulam in weed control under field conditions, since the materials slightly influenced or did not alter the sorption-desorption of diclosulam.

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Ceiba aesculifolia is an important species in Mexico that generates significant amounts of biomass waste during its exploitation, which can be utilized to produce energy. This study presents the characterization of this waste based on chemical (proximal and elemental) and thermal analyses (TGA-DTG) at different heating rates (ß = 10-30 °C/min (283-303 K/min)) in the presence of nitrogen and in a temperature range of 25-900 °C. Kinetic parameters were calculated and analyzed as well. Activation energy (Ea) and the pre-exponential factor (A) were determined using the Friedman (132.03 kJ/mol, 8.11E + 10 s -1), FWO (121.65 kJ/mol, 4.30E + 09), KAS (118.14 kJ/mol, 2.41E + 09), and Kissinger (155.85 kJ/mol, 3.47E + 11) kinetic methods. Variation in the reaction order, n (0.3937-0.6141), was obtained by Avrami's theory. We also calculated the thermodynamic parameters (ΔH, ΔG, ΔS) for each kinetic method applied. The results for Ea, A, n, ΔH, ΔG, and ΔS show that this biomass waste is apt for use in pyrolysis. Moreover, the moisture (<10%), ash (<2%), volatile material (>80%), and HHV (>19%) contents of C. aesculifolia allowed us to predict acceptable performance in generating energy and fuels. Finally, infrared spectroscopy analysis (FT-IR) allowed us to identify important functional groups, including one that belongs to the family of the aliphatic hydrocarbons.

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In this research work, we examined the decomposition mechanisms of N-substituted diacetamides. We focused on the substituent effect on the nitrogen lone-pair electron delocalization, with electron-withdrawing and electron donor groups. DFT functionals used the following: B1LYP, B3PW91, CAMB3LYP, LC-BLYP, and X3LYP. Dispersion corrections (d3bj) with Becke-Johnson damping were applied when necessary to improve non-covalent interactions in the transition state. Pople basis sets with higher angular moments and def2-TZVP basis sets were also applied and were crucial for obtaining consistent thermodynamic parameters. The proposed mechanism involves a six-membered transition state with the extraction of an α hydrogen. Several conformers of N-diacetamides were used to account for the decrease in entropy in the transition state in the rate-determining state. All calculations, including natural bond orbital (NBO) analyses, were performed using the Gaussian16 computational package and its GaussView 6.0 visualizer, along with VMD and GNUPLOT software. The isosurfaces and IBSIs were calculated using MultiWFN and IGMPlot, respectively.

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Anhydroecgonine Methyl Ester (AEME), also known as methylecgonidine, is the main pyrolysis product of smoking cocaine (cocaine base paste or basuco, crack, or freebase). This review aims to synthesize the available scientific evidence on the toxicokinetic and toxicodynamic effects of AEME. A search of scientific articles published in Science Direct, SCOPUS, and MEDLINE up to May 2024 was conducted. Twenty-four articles, including 13 experimental animal studies, 2 clinical trials, and 3 observational studies, were reviewed. AEME is readily deposited in the alveoli; its absorption improves in combination with cocaine and has a broad tissue distribution. It is metabolized primarily in the liver, with a half-life of approximately one hour, and is mainly excreted through urine. Moreover, AEME acts as a partial agonist of M1 and M3 muscarinic cholinergic receptors, influences dopaminergic system neuroadaptation, increases the production of reactive oxygen species, imbalances the activity of glutathione-associated enzymes, and reduces melatonin levels, affecting its antioxidant regulatory properties. When combined with cocaine, AEME activates the non-apoptotic pathway of caspase-9 and then, the apoptotic pathway via caspase-8, reducing neuronal viability in half the time of cocaine. AEME plays a significant role in cocaine toxicity and AEME itself.

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The solar pyrolysis of materials has emerged as a promising technology for their efficient conversion into solid char, syngas and oil. The technology has its challenges, however, as constraints such as solar intermittence and scalability must be overcame for solar pyrolysis to thrive. The present work presents a review of the developments in solar pyrolysis considering a such as development by country, solar technology employed, etcetera. Moreover, details on the challenges and potential future developments are presented. It was found that most of the development in solar pyrolysis has been focused on waste-handling, and that a particular challenge exists in an adequate control system to achieve the desired end products.

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Catalytic biomass pyrolysis is one of the most promising routes for obtaining bio-sustainable products that replace petroleum derivatives. This study evaluates the production of aromatic compounds (benzene, toluene, and xylene (BTX)) from the catalytic pyrolysis of lignocellulosic biomass (Pinus radiata (PR) and Eucalyptus globulus (EG)). Chilean natural zeolite (NZ) was used as a catalyst for pyrolysis reactions, which was modified by double ion exchange (H2NZ) and transition metals impregnation (Cu5H2NZ and Ni5H2NZ). The catalysts were characterized by nitrogen adsorption, X-ray diffraction (XRD), ammonium programmed desorption (TPD-NH3), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDS). Analytical pyrolysis coupled with gas chromatography/mass spectrometry (Py-GC/MS) allowed us to study the influence of natural and modified zeolite catalysts on BTX production. XRD analysis confirmed the presence of metal oxides (CuO and NiO) in the zeolite framework, and SEM-EDS confirmed successful metal impregnation (6.20% for Cu5H2NZ and 6.97% for Ni5H2NZ). Py-GC/MS revealed a reduction in oxygenated compounds such as esters, ketones, and phenols, along with an increase in aromatic compounds in PR from 2.92% w/w (without catalyst) to 20.89% w/w with Ni5H2NZ at a biomass/catalyst ratio of 1/5, and in EG from 2.69% w/w (without catalyst) to 30.53% w/w with Ni5H2NZ at a biomass/catalyst ratio of 1/2.5. These increases can be attributed to acidic sites within the catalyst pores or on their surface, facilitating deoxygenation reactions such as dehydration, decarboxylation, decarbonylation, aldol condensation, and aromatization. Overall, this study demonstrated that the catalytic biomass pyrolysis process using Chilean natural zeolite modified with double ion exchange and impregnated with transition metals (Cu and Ni) could be highly advantageous for achieving significant conversion of oxygenated compounds into hydrocarbons and, consequently, improving the quality of the condensed pyrolysis vapors.

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The increasing water contamination by toxic heavy metals, particularly hexavalent chromium, has become a significant environmental concern. This study explores the pyrolysis of termite-processed biomass, specifically Pinus elliottii particleboard and its termite droppings (TDs), to produce biochar and its application for chromium (VI) adsorption. Termite droppings, rich in lignin, and particleboard, rich in cellulose, were pyrolyzed at various temperatures to assess the effect of biomass composition on biochar properties. The study found that lignin-rich termite droppings produced biochar with higher fixed carbon content and specific surface area than cellulose-rich particleboard biochar. FTIR and Raman spectroscopy revealed significant molecular structure changes during pyrolysis, which influenced the adsorption capabilities of the biochar. Adsorption experiments demonstrated that TD biochar exhibited significantly higher chromium (VI) adsorption capacity, attributed to its distinct chemical composition and enhanced surface properties due to higher lignin content. These findings underscore the crucial role of lignin in producing efficient biochar for heavy metal adsorption, highlighting the practical applicability of termite-processed biomass in water purification technologies.

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This work intends to identify pollution sources along the margins of Guanabara Bay (GB; SE Brazil) through a multiproxy approach and Bayesian stable isotopic mixture model (BSIMM). For this purpose, 33 surface sediment samples were collected and analyzed for granulometry, geochemistry (heavy metals, total organic carbon-TOC, stable isotopes of carbon and nitrogen-δ13C and δ15N, Rock-Eval pyrolysis parameters-REPP), and physicochemical parameters. Metal concentrations (E) dissolved in water (EW), adsorbed by organic matter (EOM) and by Mn hydroxides (EMn), and total extracted concentrations (ET) were analyzed. Sampling was conducted in 2018 after an oil spill from Reduc Oil Refinery. Potential Ecological risk index (PERI), based on metals, classified 85% of the analyzed stations as having moderate to considerable ecological risk. The metals with the potential to cause the highest ecological risk were CdW, CdOM, PbOM, and HgOM. The combination of BSIMM and REPP data was an effective proxy for oil spill detection by indicating the presence of polycyclic aromatic hydrocarbons (PAHs). Relatively high TOC contents suggested that the analyzed stations are eutrophicated environments. BSIMM discriminated three groups of stations with different sources of organic matter (OM), endorsing the result previously shown by the cluster analysis: (A) Niterói region, Botafogo marina, Glória marina, Fiscal and Fundão islands with diffuse sources of OM, including marine phytoplankton and material of continental origin from highly polluted rivers and domestic sewage; (B) region near Fundão and Governador islands and Mangue Channel outlet with OM (≃70%) supplied by highly polluted streams and a small contribution of PAHs; (C) Duque de Caxias and Botafogo-Urca inlet with significant contributions of PAHs, materials from C-3 plants and rivers polluted by urban sewage. Results of linear regressions in conjunction with BSIMM indicate that HgMn and PbOM mainly affect Group A's stations. Although the eastern margin of GB (Niterói; Group A) showed greater oceanic interaction than the other groups, it presented substantial concentrations of metals, potentially harmful (i.e., Hg and Pb) to marine biota and human health.

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Lignocellulosic biomass conversion applying thermochemical routes has been postulated as an alternative for generating renewable energy. This research compares energy-driven biorefineries based on two thermochemical routes addressed to upgrade rice husk and rice straw produced in the Department of Sucre-Colombia. Initially, this research analyzes the physico-chemical and structural characterization of the rice residues. Four different scenarios were proposed to compare the energy-driven biorefineries based on fast pyrolysis and gasification considering technical, economic, and environmental metrics. These biorefineries were simulated using the Aspen Plus V.14.0 software. The novelty of this research is focused on the identification of the biorefinery with the best techno-economic, energetic, and environmental performance in the Colombian context. Economic and environmental analyses were done by using economic metrics and emissions. From an economic perspective, the stand-alone gasification process did not have a positive economic margin. In contrast, the fast pyrolysis process has the best economic performance since this process has a positive profit margin. Indeed, scenario 1 (fast pyrolysis of both rice residues) presented an economic margin of 13.75% and emissions of 2170.92 kgCO2eq/kg for 10 years. However, this scenario was not energetically the best, holding second place due to the feedstock requirements, compared to gasification. The biorefinery scenario 1 has the best performance.

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In this study, an experimental strategy to obtain biochar and activated carbon from torrefied palm kernel shell as an efficient material for CO2 removal was evaluated. Biochar was obtained by slow pyrolysis of palm kernel shell at different temperatures (350 °C, 550 °C, and 700 °C) and previously torrefied palm kernel shell at different temperatures (220 °C, 250 °C, and 280 °C). Subsequently, activated carbons were prepared by physical activation with CO2 from previously obtained biochar samples. The CO2 adsorption capacity was measured using TGA. The experimental results showed that there is a correlation between the change in the O/C and H/C ratios and the functional groups -OH and C=O observed via FTIR in the obtained char, indicating that both dehydration and deoxygenation reactions occur during torrefaction; this favors the deoxygenation reactions and makes them faster through CO2 liberation during the pyrolysis process. The microporous surface area shows a significant increase with higher pyrolysis temperatures, as a product of the continuous carbonization reactions, allowing more active sites for CO2 removal. Pyrolysis temperature is a key factor in CO2 adsorption capacity, leading to a CO2 adsorption capacity of up to 75 mg/gCO2 for biochar obtained at 700 °C from non-torrefied palm kernel shell (Char700). Activated carbon obtained from torrefied palm kernel shell at 280 °C (T280-CHAR700-AC) exhibited the highest CO2 adsorption capacity (101.9 mg/gCO2). Oxygen-containing functional groups have a direct impact on CO2 adsorption performance due to electron interactions between CO2 and these functional groups. These findings could provide a new experimental approach for obtaining optimal adsorbent materials exclusively derived from thermochemical conversion processes.

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This work aims to obtain recycled carbon fibre and develop an application for this new material. The carbon fibres were obtained by recycling aerospace prepreg waste via the pyrolysis process. The recycled fibres were combined with an Araldite LH5052/Aradur LY5053 epoxy resin/hardener system using manual lay-up and vacuum bagging processes. For comparison, the same resin/hardener system was used to produce a composite using commercial carbon fibre. The recycled and commercial composites were subjected to flexural, tensile and Mode I testing. Fracture aspects were analysed via scanning electron microscopy (SEM). The pyrolysis process did not affect the fibre surface as no degradation was observed. The fracture aspect showed a mixture of failure in the recycled composite laminate and interlaminar/translaminar failure near the surface of the commercial composite caused by flexural stress. Flexural and tensile tests showed a loss of mechanical strength due to the recycling process, but the tensile values were twice as high. The sand ladder platform was the project chosen for the development of a product made with recycled carbon fibres. The product was manufactured using the same manufacturing process as the specimens and tested with a 1243 kg car. The method chosen to design, manufacture and test the prototype sand ladder platform made of recycled carbon fibre was appropriate and gave satisfactory results in terms of high mechanical strength to bending and ease of use.

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The concentration of environmental pollutants needs to be monitored constantly by reliable analytical methods since they pose a public health risk. Developing simple and affordable sensors for such pollutants can allow for large-scale monitoring economically. Here, we develop a simple electrochemical sensor for sulfanilamide (SFD) quantification using a phenolic resin substrate and a CO2 laser to pyrolyze the sensor geometry over the substrate. The sensors are modified with carbon nanotubes via a simple drop-casting procedure. The carbon nanotube loading effect the electrochemical performance toward a redox probe and analytical performance for SFD detection is investigated, showing no net benefit beyond 1 mg L-1 of carbon nanotubes. The effects of the modification on the SFD oxidation are shown to be more than just an electrode area effect and possibly attributed to the fast electron transfer kinetics of the carbon nanotubes. SFD detection is performed at small solution volumes under static (800 µL) and hydrodynamic conditions (3 mL) in a fully integrated, miniaturized batch-injection analyses cell. Both methods have a similar linear range from 10.0 to 115.0 µmol L-1 and high selectivity for SFD determination. Both systems are used to quantify SFD in real samples as a proof of concept, showcasing the proposed device's applicability as a sensor for environmental and public health monitoring of SFD.

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The increasing emissions of gaseous pollutants of anthropogenic origin, such as carbon dioxide (CO2), which causes global warming, have raised great interest in developing and improving processes that allow their mitigation. Among them, adsorption on porous materials has been proposed as a sustainable alternative. This work presents a study of CO2 equilibrium adsorption at low temperatures (0, 10, and 20 °C) over a wide range of low pressures, on activated carbon derived from Eucalyptus (ES) and Patula pine (PP) forest waste, and carbonaceous material derived from waste tires (WT). The precursors of these materials were previously prepared, and their physicochemical properties were characterized. ES and PP were thermochemically treated with phosphoric acid, and WT was oxidized with nitric acid. Additionally, these materials were used to obtain monoliths using uniaxial compaction techniques and different binding agents, with better results obtained with montmorillonite. A total of six adsorbent solids had their textural and chemical properties characterized and were tested for CO2 adsorption. The highest specific surface area (1405 m2 g-1), and micropore properties were found for activated carbon derived from Eucalyptus whose highest adsorption capacity ranged from 2.27 mmol g-1 (at 0 °C and 100 kPa) to 1.60 mmol g-1 (at 20 °C and 100 kPa). The activated carbon monoliths presented the lowest CO2 adsorption capacities; however, the studied materials showed high potential for CO2 capture and storage applications at high pressures. The isosteric heats of adsorption were also estimated for all the materials and ranged from 16 to 45 kJ mol-1 at very low coverage explained by the energetic heterogeneity and weak repulsive interactions among adsorbed CO2 molecules.

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Graphene-based materials have increasingly attracted attention in recent years. It is a material is recognized worldwide due to its numerous applications in several sectors. However, graphene production involves several challenges: scalability, high costs, and high-quality production. This study synthesized graphene-like porous carbon nanosheets (GPCNs) through a thermochemical process under a nitrogen atmosphere using grape bagasse as a precursor. Three temperatures (700, 800, and 900 ºC) of the pyrolysis process were studied. Chemical graphitization and activation were used to form high-specific surface area materials: FeCl3.6H2O(aq) and ZnCl2(s) in a simultaneous activation-graphitization (SAG) method. The materials obtained (GPCN700, GPCN800, and GPCN900) were compared to previously produced chars (C700, C800, and C900). A high specific surface area and total pore volume were obtained for GPCN materials, and GPCN900 presented the highest values: 1062.7 m2g-1 and 0.635 cm3 g-1, respectively. The GPCN and char materials were classified as mesoporous and applied as adsorbents for CO2(g). The GPCN800 presented the best CO2(g) adsorbent, with a CO2(g) adsorption capacity of 168.71 mg g-1.

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This work describes the spray pyrolysis deposition of PbSe films, using as-prepared PbSe colloids as the starting solution. The PbSe colloids were prepared by using the alkahest approach, where Pb and Se precursors were made to react with the following green polyols: glycerin, ethylene glycol, and propylene glycol, to subsequently spray them onto glass substrates. The results of the characterization indicated that amine or thiol groups-free and single-phase rock-salt cubic PbSe powder was obtained, producing nanocrystals 16-30 nm in size. X-ray diffraction also showed that the PbSe films containing PbSeO3 and PbO·xH2O as impurity phases were produced during the deposition. The morphology of the powders and films was developed by a self-assembly process, in which the primary PbSe nanoparticles self-assemble to produce peanut-like microstructures. Additionally, a non-continuous and porous feature was formed in the thick films. Certain films revealed optical structures characterized by broad- and low-intensity bands resembling an exciton-like behavior. This could be attributed to the presence of nanocrystals with a size less than the Bohr radius, indicating reminiscent quantum effects. The results suggest that the usage of colloidal dispersions as spray solutions represents an effective approach to forming PbSe films, as well as that the synthesis method allows for the elimination of thiol and amine groups before deposition, significantly simplifying the process.

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Pinus radiata (PR) and Eucalyptus globulus (EG) are the most planted species in Chile. This research aims to evaluate the pyrolysis behaviour of PR and EG from the Bío Bío region in Chile. Biomass samples were subjected to microwave pretreatment considering power (259, 462, 595, and 700 W) and time (1, 2, 3, and 5 min). The maximum temperature reached was 147.69 °C for PR and 130.71 °C for EG in the 700 W-5 min condition, which caused the rearrangement of the cellulose crystalline chains through vibration and an increase in the internal energy of the biomass and the decomposition of lignin due to reaching its glass transition temperature. Thermogravimetric analysis revealed an activation energy (Ea) reduction from 201.71 to 174.91 kJ·mol-1 in PR and from 174.80 to 158.51 kJ·mol-1 in EG, compared to the untreated condition (WOT) for the 700 W-5 min condition, which indicates that microwave pretreatment improves the activity of the components and the decomposition of structural compounds for subsequent pyrolysis. Functional groups were identified by Fourier transform infrared spectroscopy (FTIR). A decrease in oxygenated compounds such as acids (from 21.97 to 17.34% w·w-1 and from 27.72 to 24.13% w·w-1) and phenols (from 34.41 to 31.95% w·w-1 and from 21.73 to 20.24% w·w-1) in PR and EG, respectively, was observed in comparison to the WOT for the 700 W-5 min condition, after analytical pyrolysis. Such results demonstrate the positive influence of the pretreatment on the reduction in oxygenated compounds obtained from biomass pyrolysis.

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The pyrolysis process consists of the thermal decomposition of biomass in an inert atmosphere, which produces a liquid (bio-oil) composed of a complex mixture of organic compounds, including an oil and water phase. The aqueous fraction can reach up to 45% w/w, and understanding its composition is of utmost importance in determining its intended destination, whether for the reuse of compounds in industrial applications or for treating the effluent for disposal. In this study, a fast, direct, and efficient method using ultra-high-performance supercritical fluid chromatography (UHPSFC) was developed and optimized for monitoring phenols in aqueous samples obtained from the pyrolysis processing of six different biomass sources. The following parameters were evaluated for method optimization: stationary phase type, mobile phase flow, organic modifier, sample diluent, temperature, pressure, and modifier gradient time. With a total analysis time of 26 min, out of the fourteen (14) investigated phenolic compounds, eleven (11) were successfully separated after method optimization, and among them, five (5) were quantified in all six aqueous fractions. The aqueous fractions of residue from cowpea pod (1.89 mg.mL-1), sugar apple (3.09 mg.mL-1), and acerola (4.79 mg.mL-1) presented lower concentrations compared to grape (8.16 mg.mL-1), pine nuts (6.68 mg.mL-1), and guava (6.05 mg.mL-1) fractions. However, even at lower concentrations, all biomasses showed promising results regarding the phenolic compound content, analytes that have high added value for the chemical industry.

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To achieve a waste-free clean production, the present study aimed to valorize an underused agroindustrial byproduct (rice bran) by mealworms bioconversion and produce bio-oil from pyrolysis of insect excreta (frass) as bioinsecticide. To reach the first goal, the suitability of rice bran (RB) versus standard diet, wheat bran (WB), was examined by determining feed conversion, growth performance, and nutritional profile of T. molitor larvae. RB diet was an appropriate feed substrate for breeding mealworms, as evidenced by their high survival rates, optimal feed conversion parameters, and its capability to support the growth and life cycle of this insect. Besides, RB did not affect soluble larval protein content but modified crude fat content and fatty acid profile. In order to address the second aim, egested frass from RB and WB were subjected to pyrolysis to obtain bio-oils. The main compound was acetic acid (≈37%) followed by 1,6-anhydro-ß-d-glucopyranose (from 16 to 25%), as measured by GC-MS analysis. Nitrogen-containing chemicals accounted for ≈10%. Frass bio-oils could represent a novel source of bioinsecticides due to their bioeffectiveness in insect pests of economic importance (Plodia interpunctella and Tribolium castaneum) and medical interest (Culex pipiens pipiens). For P. interpunctella adults, frass bio-oils produced insecticidal activity by fumigant and contact exposure whereas for T. castaneum adults, just fumigant. By a miniaturized model that simulates semireal storage conditions, it was seen that, on T. castaneum, frass RB bio-oil generated higher repellent effect than frass WB. Finally, bio-oils proved to have larvicidal activity against Cx. p. pipiens.

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Sustainable management of non-edible agricultural residues of cashew nut production is a concern in Colombia. Therefore, this study aimed to study the fatty acid content of a pyrolytic liquid obtained from cashew nut shells (CNSs) from the Vichada region in Colombia. Transesterification of pyrolytic liquid was conducted to obtain biodiesel at the micro-scale as the first approach for this valorization route. Proximal analysis of samples was carried out using advanced analytical techniques (UHPLC-MS and CG-MS) whereas phenolic content and antioxidant activity were determined. The production yield of pyrolytic liquid was 69.15 ± 5.07% weight (wt.), at 550 °C and 2h of pyrolysis and the liquid was rich in fatty acids (∼70% wt.) and long-chain phenols (∼18% wt.). Among the phenolic compounds in liquid, mainly unsaturated C15:4 cardanol was identified (82.1 ± 5.5 mg/g), whereas the antioxidant activity of pyrolytic liquid was 0.714 ± 0.030 TE/g. Moreover, the biodiesel yield was 81% using catalyst sodium methoxide (12% v), and 50 °C and 26 min for the reaction. The obtained biodiesel in the hexane fraction was rich in methyl trans-8-octadecanoate (20.9 % wt.) and methyl palmitate (14.3 % wt.), being the representative compounds in the biodiesel. Therefore, the results indicated that thermal conversion of CNSs for obtaining biodiesel on a one-step process is a suitable strategy for the management of toxic and non-edible cashew residues. Finally, this is the first work of its kind that propose in detail the composition of pyrolytic liquid obtained from Colombian cashew nut residues under the proximate analysis approach and using advanced analytical techniques.

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Plastic waste consumption increases exponentially every year, mainly in the last three years due to the COVID-19 pandemic. The rapid growth of plastic products has exceeded the world's capacity to deal with this type of trash. Thus, it has become a substantial environmental concern in modern society. Another dire concern is the improper disposal of used supercapacitors, leading to serious environmental impacts. Consequently, critical action to tackle this issue is to transform trash into high-valued materials, such as carbon nanomaterial supercapacitors. Considering several methodologies of recycling, pyrolysis stands out due to its simplicity and easy handling of mixed plastic waste to produce carbonaceous materials with different dimensions (0, 1, 2, and 3D). Thus, from this technology, it is possible to create new opportunities for using plastic waste and other types of waste to produce cheaper carbon-based materials for supercapacitors. This review aims to provide readers with a sustainability-driven view regarding the reutilization of plastic trash, discusses the environmental consequences of not doing so, and shows plastic waste solutions. Despite the broad scope of the topic, this review focuses on identifying the currently studied strategies to convert plastic waste into carbon-based electrodes, using less expensive and more efficient competitive protocols, besides emphasizing the diverse types (0, 1, 2, and 3D) of nanostructures. This review also proposes promising options for a sustainable cycle of plastic waste and supercapacitor.