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In this work, to improve the performance of peroxodisulphate-advanced oxidation, an electrochemical oxidation-assisted UV light-activated peroxodisulphate system (E/UV/PDS) was used to degrade carbamazepine. The degradation of carbamazepine by PDS, E/PDS, UV/PDS and E/UV/PDS systems was compared, and their synergistic effects were analysed. The influence of single factors, such as PDS addition, initial pH, DS voltage, target initial concentration, etc., on the degradation of the E/UV/PDS system was discussed, and the optimal degradation process parameters were given. The active substances were determined by free radical inhibition experiments, such as 1O2, SO4-⋅ and ⋅OH. It was proved that 1O2 contributes much more to the degradation of carbamazepine than SO4-⋅ and ⋅OH. The degradation pathway of carbamazepine was proposed. Finally, the degradation mechanism of carbamazepine in the E/UV/PDS system was speculated. The results indicate that the electrochemical combined with the E/UV/PDS system is of great potential application value in the removal of antibiotic drug pollution and environmental purification.

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Persulphates, an advanced oxidation process, has been recently used as an alternative pretreatment method to enhance short-chain fatty acids (SCFAs) yield from waste-activated sludge (WAS) anaerobic fermentation (AF). But so far, the effects of peroxydisulphate (PDS) dosages on mesophilic anaerobic fermentation are still not studied fully. Herein, we explored the influences of potassium PDS addition on mesophilic AF of WAS. Notably, the addition of PDS could drastically accelerate WAS solubilization and hydrolysis, which was proportional to the amount of PDS. The maximal total SCFAs yield of 249.14 mg chemical oxygen demand/L was obtained with 120 mg PDS/g suspended solids addition at 6 days of AF, which was 2.2-fold that of the control one. Tightly bound extracellular polymeric substances (EPSs) were transformed into loosely bound EPS and dissolved organic matters, and aromatic proteins and humic-like substances of EPSs were disintegrated, which were caused by the devastating effects of PDS treatments on EPSs disruption. The intracellular constituents of microbial cells in the sludge were released accordingly. As a result, there was release of soluble substrates derived from the disintegration of both EPSs and cells, the amounts of which were proportional to the dose of PDS. Moreover, microbial diversity and richness were both decreased in the presence of PDS, and the relative abundance of phyla Actinobacteria increased with the increase of the PDS dosage. In addition, the stability of sludge flocs was destroyed in the presence of PDS, the distribution of particle size tended to be small and dispersive, and dewaterability of the sludge was deteriorated.

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In this study, the usefulness of the ZVI/S2O82- system in enhancing the dewaterability of waste activated sludge was studied at different initial sludge pH levels to reveal the associated mechanisms. Results showed that conditioning of sludge by the ZVI/S2O82- system at acidic initial sludge pHs enhanced sludge filterability and the dryness of dewatered sludge cake, while only the sludge filterability was improved at neutral initial sludge pH. In particular, the conditioning treatment using 0.353 g/g DS of ZVI and Na2S2O8 with a mole ratio of 1.25:1, at initial sludge pH 2.52, was the optimum condition to improve sludge dewaterability, which reduced the moisture content of dewatered sludge cake to only 69.8% and meanwhile reduced sludge CST and SRF to only 70.9% and 40.7% of that of raw sludge, respectively. During the conditioning treatment, sludge microbial cell lysis resulting from decreasing the initial sludge pH led to the reduction in the moisture content of dewatered sludge cake, while the oxidation of sludge EPS and the coagulation of the disrupted sludge flocs achieved by the ZVI/S2O82- system improved sludge filterability. A kaolin suspension experiment revealed that with a decrease in system pH, the oxidation effect was gradually inhibited and the coagulation effect offset the disruption effect on sludge flocs to improve the filterability of sludge. Therefore, the conditioning of waste activated sludge using the ZVI/Na2S2O8 system at acidic initial sludge pHs is useful to enhance the sludge filterability and the dryness of dewatered sludge cake, both of which are crucial for improving sludge dewatering performance.

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For the first time, the analytical figures of merit in detection capabilities of the very less explored photoinduced chemical oxidation method for Ru(bpy)32+ CL has been investigated in detail using 32 structurally different analytes. It was carried out on-chip using peroxydisulphate and visible light and compared with well-known direct chemical oxidation approaches using Ce(IV). The analytes belong to various chemical classes such as tertiary amine, secondary amine, sulphonamide, betalactam, thiol and benzothiadiazine. Influence of detection environment on CL emission with respect to method of oxidation was evaluated by changing the buffers and pH. The photoinduced chemical oxidation exhibited more universal nature for Ru(bpy)32+ CL in detection towards selected analytes. No additional enhancers, reagents, or modification in instrumental configuration were required. Wide detectability and enhanced emission has been observed for analytes from all the chemical classes when photoinduced chemical oxidation was employed. Some of these analytes are reported for the first time under photoinduced chemical oxidation like compounds from sulphonamide, betalactam, thiol and benzothiadiazine class. On the other hand, many of the selected analytes including tertiary and secondary amines such as cetirizine, azithromycin fexofenadine and proline did not produced any analytically useful CL signal (S/N=3 or above for 1µgmL-1 analyte) under chemical oxidation. The most fascinating observations was in the detection limits; for example ofloxacin was 15 times more intense with a detection limit of 5.81×10-10M compared to most lowest ever reported 6×10-9M. Earlier, penicillamine was detected at 0.1µgmL-1 after derivatization using photoinduced chemical oxidation, but in this study, we improved it to 5.82ngmL-1 without any prior derivatization. The detection limits of many other analytes were also found to be improved by several orders of magnitude under photoinduced chemical oxidation.

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Chemical treatment processes have mostly been considered as an efficient way for biosolid minimization. The improvement of sludge dewatering was more a welcome side-effect of these sequential processes. In this study, heat-activated sodium peroxydisulphate (PDS) and potassium peroxymonosulphate (MPS) were applied in order to disintegrate waste activated sludge (WAS). PDS and MPS treatment of WAS results in the polymer transfer of organic matter from the solid phase to the liquid phase. Our research work was done for chemical disintegration of WAS by PDS and MPS in doses of 0.2%, 0.4%, 0.6%, 0.8% and 1% (169.5, 339.0, 508.5, 678.0 and 847.5 mg [Formula: see text]) activated at temperatures of 60°C and 90°C for 30 min. The application of these methods causes the soluble chemical oxygen demand value to increase in the supernatant. In addition, there was a positive influence on the sludge volume index which decreased for the highest doses of PDS of over 63% and 77% and MPS of over 78% and 82% through heat activation at temperatures of 60°C and 90°C, respectively. Furthermore, MPS was more successful in the floc particle destruction, therefore it caused a higher sludge settlement acceleration (sedimentation/compaction speed) than PDS. The experimental results demonstrated that the application of heat-activated PDS and MPS may become a novel effective way of processing sewage sludge.

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A novel automated precolumn derivatization followed by separation using liquid chromatography for the determination of pseudoephedrine (PSE) by a microfluidic chemiluminescence detector has been developed. An on-line derivatization procedure was utilized by converting PSE into a highly light emitting species in a Ru(bipy)3(2+)-peroxydisulphate chemiluminescence (CL) system by derivatizing it with a 1.0 M formaldehyde solution. The derivatized analyte was directly injected into a microbore high-performance liquid chromatography (HPLC) system coupled to an on-chip chemiluminescence detector. The newly developed highly selective, sensitive and fast HPLC-CL method was validated and successfully applied for the analysis of PSE in pharmaceutical formulations and a human urine sample. The selectivity of the method is not only due to the HPLC separation but is also due to the highly selective detection principle of the Ru(bipy)3(2+)-peroxydisulphate CL system used. There was no interference observed from the common preservatives and excipients used in pharmaceutical preparations, which did not show any significant CL signal. The retention time of PSE was less than 3 min, and the detection limits and quantification limits were found to be 5.7 and 26.0 µg L(-1), respectively.

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