RESUMEN

Aqueous zinc-based energy storage devices possess superior safety, cost-effectiveness, and high energy density; however, dendritic growth and side reactions on the zinc electrode curtail their widespread applications. In this study, these issues are mitigated by introducing a polyimide (PI) nanofabric interfacial layer onto the zinc substrate. Simulations reveal that the PI nanofabric promotes a pre-desolvation process, effectively desolvating hydrated zinc ions from Zn(H2O)6 2+ to Zn(H2O)4 2+ before approaching the zinc surface. The exposed zinc ion in Zn(H2O)4 2+ provides an accelerated charge transfer process and reduces the activation energy for zinc deposition from 40 to 21 kJ mol-1. The PI nanofabric also acts as a protective barrier, reducing side reactions at the electrode. As a result, the PI-Zn symmetric cell exhibits remarkable cycling stability over 1200 h, maintaining a dendrite-free morphology and minimal byproduct formation. Moreover, the cell exhibits high stability and low voltage hysteresis even under high current densities (20 mA cm-2, 10 mAh cm-2) thanks to the 3D porous structure of PI nanofabric. When integrated into full cells, the PI-Zn||AC hybrid zinc-ion capacitor and PI-Zn||MnVOH@SWCNT zinc-ion battery achieve impressive lifespans of 15000 and 600 cycles with outstanding capacitance retention. This approach paves a novel avenue for high-performance zinc metal electrodes.

RESUMEN

Severe stress endangers outdoor workers who are in an exceedingly hot workplace. Although recent studies quantify stress levels on the human skin, they still rely on rigid, bulky sensor modules, causing data loss from motion artifacts and limited field-deployability for continuous health monitoring. Moreover, no prior work shows a wearable device that can endure heat exposure while showing continuous monitoring of a subject's stress under realistic working environments. Herein, a soft, field-deployable, wearable bioelectronic system is introduced for detecting outdoor workers' stress levels with negligible motion artifacts and controllable thermal management. A nanofabric radiative cooler (NFRC) and miniaturized sensors with a nanomembrane soft electronic platform are integrated to measure stable electrodermal activities and temperature in hot outdoor conditions. The NFRC exhibits outstanding cooling performance in sub-ambient air with high solar reflectivity and high thermal emissivity. The integrated wearable device with all embedded electronic components and the NFRC shows a lower temperature (41.1%) in sub-ambient air than the NFRC-less device while capturing improved operation time (18.2%). In vivo human study of the bioelectronics with agricultural activities demonstrates the device's capability for portable, continuous, real-time health monitoring of outdoor workers with field deployability.

Asunto(s)

Dispositivos Electrónicos Vestibles , Humanos , Piel , Electrónica , Temperatura , Frío

RESUMEN

All-weather personal thermal regulation has far been challenged by variable environments especially the regulatory failure caused by highly-dense solar radiation, low environmental radiation and the fluctuated epidermal moisture in different seasons. Herein, from the design of interface selectivity, dual-asymmetrically optical and wetting selective polylactic acid-based (PLA) Janus-type nanofabric is proposed to achieve on-demand radiative cooling and heating as well as sweat transportation. Hollow TiO2 particles are introduced in PLA nanofabric causing high interface scattering (∼99%) and infrared emission (∼91.2%) as well as surface hydrophobicity (CA > 140°). The strictly optical and wetting selectivity help achieve ∼12.8℃ of net cooling effect under > 1500 W/m2 of solar power and ∼5℃ of cooling advantage higher than cotton fabric and sweat resistance simultaneously. Contrarily, the semi-embedded Ag nanowires (AgNWs) with high conductivity (0.245 Ω/sq) endows the nanofabric with visible water permeability and excellent interface reflection for thermal radiation from body (>65%) thus causing ∼7℃ of thermal shielding. Through simple interface flipping, synergistical cooling-sweat reducing and warming-sweat resisting can be achieved to satisfy the thermal regulation in all weather. Compared with conventional fabrics, multi-functional Janus-type passive personal thermal management nanofabrics would be of great significance to achieve the personal health maintenance and energy sustainability.

RESUMEN

An environmentally friendly non-woven nanotextile has been prepared using enantiomeric pairs of poly (lactic acid) PLA by electrospinning technique. Solution blending of synthesized high molecular weight (⁓105 Da) poly (L-lactic acid) PLLA and poly (D-lactic acid), PDLA for prolonged time stirring produce solely stereocrystallites (sc). The high crosslinking effect of sc-PLA has played an important role, with multifunctional behaviour on the addition of anatase-TiO2 (a-TiO2) in three different ways (Case-I-III). The high crystallinity of a-TiO2 (~7.14 nm), has been confirmed from XRD and TEM studies as 98 %. The nanofinish as studied in (Case -III) by dipping and drying has decreased the water contact angle for the electrospun sc-PLA nanotextile from highly hydrophobic (132°) to superhydrophilicity after 8 min. An easy demonstration of high temperature treated nanofabric (at 100 °C) has proven to obtain an anti-shrinkage sc-PLA nanofabric. Even, the presence of a-TiO2 has improved the colour strength ability of sc-PLA as a dark dyed nanofabric. The loading of as-synthesized a-TiO2 nanoparticle has enhanced adsorbent dosages for 5TdipscPLA up to 1.44 mg/g of MB dosage, at contact time (8 h), and 68 % methylene blue (MB) removal efficiency under UV irradiation. Thereby, this a-TiO2 impregnated sc-PLA nanofabric tends to dye removal.

Asunto(s)

Azul de Metileno , Titanio , Colorantes , Ácido Láctico/química , Poliésteres/química , Titanio/química , Agua

RESUMEN

Miniaturization of energy conversion and storage devices has attracted remarkable consideration in the application of wearable electronics. Compared with film-based flexible electronics, fiber-based wearable electronics (e.g., nanogenerators and sensors made from electrospun nanofibers) are more appealing and promising for wearables. However, there are two bottlenecks, a low power output and poor sensing capability, limiting the application of piezoelectric nanofibers. Herein, we integrated zinc oxide nanorods (ZnO NRs) to a less known piezoelectric polymer, polyacrylonitrile (PAN) nanofiber, forming a ZnO/PAN nanofabric, which significantly improved the pressure sensitivity and vibrational energy harvesting ability by about 2.7 times compared with those of the pristine PAN nanofiber, and the maximum output power density of ∼10.8 mW·m-2 is achieved. Noteworthily, the ZnO/PAN nanofabric showed a power output about twice of the one made of ZnO and polyvinylidene fluoride. It was revealed that the integration of ZnO NRs clearly improved the planar zigzag conformation in microstructures of the PAN nanofiber. Further, successful demonstrations of a mechanically robust pressure sensor and wearable power source confirm the potential applications in human activity monitoring and personal thermal management, respectively.

RESUMEN

Nanofabrics made from abundant natural protein that possesses enormous amounts of functional groups may have important applications such as air filtration. However, protein nanofabrics with randomly distributed nanofibers have very low mechanical properties and high airflow resistance, both of which seriously reduce the breathability. Here, a super-breathable zein (corn protein) fabric having a unique "woven-like" nanofibrous structure (w-PNF) via the accumulation effect between the charged nanofibers and the collector during electrospinning is reported. The resulting w-PNF exhibits remarkable tensile strength and modulus, which are 3 and 9 times, respectively, higher than the random protein nanofibrous materials. The filtration tests indicate that w-PNF presents super-breathable performance, including ultralow airflow resistance (1/12 of that of the nonwoven nanofabric) and high filtration efficiency for capturing PM2.5. As compared with the reported nanofabrics, w-PNF maintains the same airflow resistance at up to 4 times higher airflow rate. In addition, w-PNF presents visible-light transparency (80%) and high resolution even in microareas. This work provides a significant strategy for designing and fabricating nanofabrics for boosting the development of biological nanomaterials.

RESUMEN

Development of nonflammable separators with excellent properties is in urgent need by next-generation advanced and safe energy storage devices. However, it has been extremely challenging to simultaneously achieve fire resistance, high mechanical strength, good thermomechanical stability, and low ion-transport resistance for polymeric separators. Herein, to address all these needs, we report an in situ formed silica@silica-imbedded polyimide (in situ SiO2@(PI/SiO2)) nanofabric as a new high-performance inorganic-organic hybrid separator. Different from conventional ceramics-modified separators, this in situ SiO2@(PI/SiO2) hybrid separator is realized for the first time via an inverse in situ hydrolysis process. Benefiting from the in situ formed silica nanoshell, the in situ SiO2@(PI/SiO2) hybrid separator shows the highest tensile strength of 42 MPa among all reported nanofiber-based separators, excellent wettability to the electrolyte, good thermomechanical stability at 300 °C, and fire resistance. The LiFePO4 half-cell assembled with this hybrid separator showed a high capacity of 139 mAh·g-1@5C, which is much higher than that of the battery with the pristine PI separator (126.2 mAh·g-1@5C) and Celgard-2400 separator (95.1 mAh·g-1@5C). More importantly, the battery showed excellent cycling stability with no capacity decay over 100 cycles at the high temperature of 120 °C. This study provides a novel method for the fabrication of high-performance and nonflammable polymeric-inorganic hybrid battery separators.