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Tulathromycin (TUL) is a widely used veterinary antibiotic for treating bovine and porcine respiratory infections. Consuming animal-derived food contaminated with this medication may jeopardize human health. This work adopted the first portable potentiometric platform for direct TUL sensing in pharmaceutical and food products. The sensor employed a plasticized PVC membrane on a glassy carbon electrode doped with calix[6]arene and multi-walled carbon nanotubes (MWCNT) in a single solid contact layer for selective binding and signal stability. Characterization via scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) confirmed the material's integrity. The MWCNT-based sensor produced a stable Nernstian response (1.0 × 10-7 to 1.0 × 10-3 M) and a limit of detection (LOD) of 9.76 × 10-8 M with instantaneous response (8 ± 2 s). IUPAC validation revealed high selectivity for TUL against interfering ions, minimal drift (0.6 mV/h), and functionality over a broad pH range (2.0-7.0), allowing direct application to dosage form, spiked milk, and liver samples. Eco-Scale, AGREE, and Whiteness assessment proved the method's ecological sustainability, economic viability, and practical feasibility, surpassing traditional approaches.

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The presence of metronidazole (MNZ) and acetaminophen (ACE) in aquatic environments has raised growing concerns regarding their potential impact on human health. Incorporating various patterns into a photocatalytic material is considered a critical approach to achieving enhanced photocatalytic efficiency in the photocatalysis process. In this study, WO3 nanoparticles, which were immobilized onto ferromagnetic multi-walled carbon nanotubes that were functionalized using (3-glycidyloxypropyl)trimethoxysilane (FMMWCNTs@GLYMO@WO3), exhibited remarkable efficiency in removing MNZ and ACE (93% and 97%) in only 15 min. In addition, the new visible-light FMMWCNTs@GLYMO@WO3 nanoparticles as a magnetically separable photocatalyst were characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction analysis (XRD), transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), EDS-mapping, vibrating sample magnetometry (VSM), thermogravimetric analysis (TGA), diffuse reflectance spectroscopy (DRS), high-performance liquid chromatography (HPLC), and total organic carbon (TOC) due to detailed studies (morphological, structural, magnetic and optical properties) of the photocatalyst. In-depth spectroscopic and microscopic characterization of the newly developed ferromagnetic FMMWCNTs@GLYMO@WO3 (III) photocatalyst revealed a spherical morphology, with nanoparticle diameters averaging between 23 and 39 nm. Compared to conventional multiwall carbon nanotube and WO3 photocatalysts, FMMWCNTs@GLYMO@WO3 (III) demonstrated superior photocatalytic activity. Remarkably, it exhibited excellent reusability, maintaining its efficiency over a minimum of five cycles in the degradation of metronidazole (MNZ) and acetaminophen (ACE).

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Addressing critical challenges in enhancing the oxidative stability and proton conductivity of high-temperature proton exchange membranes (HT-PEMs) is pivotal for their commercial viability. This study uncovers the significant capacity of multiwalled carbon nanotubes (MWNTs) to absorb a substantial amount of phosphoric acid (PA). The investigation focuses on incorporating long-range ordered hollow MWNTs into self-cross-linked fluorenone-containing polybenzimidazole (FPBI) membranes. The absorbed PA within MWNTs and FPBI forms dense PA networks within the membrane, effectively enhancing the proton conductivity. Moreover, the exceptional inertness of MWNTs plays a vital role in reinforcing the oxidation resistance of the composite membranes. The proton conductivity of the 1.5% CNT-FPBI membrane is measured at 0.0817 S cm-1 at 160 °C. Under anhydrous conditions at the same temperature, the power density of the 1.5% CNT-FPBI membrane reaches 831.3 mW cm-2. Notably, the power density remains stable even after 200 h of oxidation testing and 250 h of operational stability in a single cell. The achieved power density and long-term stability of the 1.5% CNT-FPBI membrane surpass the recently reported results. This study introduces a straightforward approach for the systematic design of high-performance and robust composite HT-PEMs for fuel cells.

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Triethylamine (TEA) poses a significant threat to our health and is extremely difficult to detect at the parts-per-billion (ppb) level at room temperature. Carbon nanotubes (CNTs) are versatile materials used in chemiresistive vapor sensing. However, achieving high sensitivity and selectivity with a low detection limit remains a challenge for pristine CNTs, hindering their widespread commercial application. To address these issues, we propose functionalized multiwalled CNTs (MWCNTs) with carboxylic acid (COOH)-based sensing channels for ultrasensitive TEA detection under ambient conditions. Advanced structural analyses confirmed the necessary modification of MWCNTs after functionalization. The sensor exhibited excellent sensitivity to TEA in air, with a superior noise-free signal (10 ppb), an extremely low limit of detection (LOD ≈ 0.8 ppb), excellent repeatability, and long-term stability under ambient conditions. Moreover, the response values became more stable, demonstrating excellent humidity resistance (40-80% RH). Notably, the functionalized MWCNT sensor exhibited improved response and recovery kinetics (200 and 400 s) to 10 ppm of TEA compared to the pristine MWCNT sensor (400 and 1300 s), and the selectivity coefficient for TEA gas was improved by approximately three times against various interferants, including ammonia, formaldehyde, nitrogen dioxide, and carbon monoxide. The remarkable improvements in TEA detection were mainly associated with the large specific surface area, abundant active sites, adsorbed oxygen, and other defects. The sensing mechanism was thoroughly explained by using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and gas chromatography-mass spectrometry (GC-MS). This study provides a new platform for CNT-based chemiresistive sensors with high selectivity, low detection limits, and enhanced precision with universal potential for applications in food safety and environmental monitoring.

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Polyimide is actively applied in various industrial fields because of its strong mechanical properties, owing to the interactions between the polymer chains. Fully aromatic imide structures exhibit high glass-transition temperatures due to the strong interactions between their chains, which hinder chain mobility. Therefore, preparing a material that exhibits self-healing at a low temperature of ≤100 °C and good mechanical properties is challenging. Thus, we prepared imides with four-component semiaromatic structures by adjusting the contents of 4,4'-(hexafluoroisopropylidene)diphthalic anhydride and 4,4'-(4,4'-isopropylidenediphenoxy)bis(phthalic anhydride) to yield four-component self-healable colorless polyimides (f-SH-CPIs) with novel structures, flexibilities, good mechanical properties, and low healing temperatures. The flexibilities and distances between the polymer chains, as the basis of the trade-off relationship between the mechanical properties and healing efficiency, were controlled. These materials may be used as substrates in wearable devices and multilayer insulation that may protect from space dust, cosmic rays, and satellite fragments.

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In the recent times, one of the most crucial tasks related to water resources is the treatment of polluted water. This study reports the development of a functionalized nanofibrous membrane with enhanced filtration performance, heavy metal removal, and photocatalytic dye degradation for the effective treatment of contaminated water. The nanofibrous mats were developed by the process of electrospinning using a polymeric solution of polyacrylonitrile (PAN) reinforced with curcumin-multiwalled carbon nanotube (C-MWCNT) conjugate. The experimental trials for membrane fabrication were adapted based on the design of experiments (DoE) approach by making use of the Box-Behnken design (BBD) for a three-variable system, a component of response surface methodology (RSM). The three variable parameters selected for optimization of the electrospinning process were the dopant concentration (in weight percentage), the flow rate (in millilitre per hour), and the spinning time (in hours), respectively, and a total of 15 fibrous membranes were fabricated. The SEM analysis of the fabricated membranes revealed alterations in the surface morphology of the fibrous mats with variations in the electrospinning parameters. The infrared spectrum of the fibrous mats, validated the incorporation C-MWCNT conjugate in PAN, thereby confirming the formation of PAN/C-MWNCNT membrane. The mean flow pore size and breaking force of the PAN/C-MWCNT membranes was also obtained using a universal testing machine (UTM) and porometer, respectively. To choose the best membrane for efficient filtration experiments, the performance of each of the prepared membranes was assessed in terms of solute rejection percentage (SR%), permeate flux (PF), and pure water flux (PWF). The statistical analysis of the assessed parameters in accordance with the membranes prepared was done using the MINITAB software, and the three-dimensional (3D) surface plots were constructed using the STATISTICA software to visualize and validate the relation between each of the electrospinning parameters and the corresponding membrane performance characteristics. Similarly, the potential of the electrospun membranes for efficient heavy metal ion removal and photocatalysis were also tested independently and the optimal electrospinning parameters were determined for the same. Based on the results, it was observed that the PAN/C-MWCNT membranes could serve as potential candidates for the treatment of polluted water.

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As a rising branch of advanced oxidation processes, persulfate activation has attracted growing attention. Unlike catalysts that have been widely studied, the selection of persulfate is previously overlooked. In this study, the affecting factors of persulfates were studied. The effect of target pollutant properties on superior persulfate species (the species with a higher degradation efficiency) was investigated by multiwalled carbon nanotube (MWCNT)/persulfate catalytic systems. Innovatively, the EHOMO (or vertical ionization potential (VIP)) value of the target pollutant was proposed to be an index to judge the superior persulfate species, and the threshold is VIP= 6.397-6.674 eV, EHOMO= -8.035∼- 7.810 eV, respectively. To be specific, when the VIP of phenolic compounds is higher (or EHOMO of phenolic compounds is lower) than the threshold, the catalytic performance of peroxymonosulfate would be higher than that of peroxydisulfate. Moreover, the effects of coexisting cations on peroxydisulfate superior species were further investigated. It was illustrated that the hydrated cation radius of coexisting cations would influence the pollutant degradation efficiency under some circumstances. This study provides a new approach to improve the cost of persulfate activation systems and promotes the underlying downstream application of persulfate activation systems.

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Wearable electronic sensors have attracted considerable interest in hand motion monitoring because of their small size, flexibility, and biocompatibility. However, the range of motion and sensitivity of many sensors are inadequate for complex and precise finger motion capture. Here, organic and inorganic materials were incorporated to fabricate a hybrid electronic sensor and optimized and woven into fabric for hand motion detection. The sensor was made from flexible porous polydimethylsiloxane (PDMS) filled with multiwalled carbon nanotubes (MWCNTs). The weight ratios of MWCNTs and geometric characteristics were optimized to improve the hybrid electronic sensor, which showed a high elongation at the breaking point (i.e., more than 100%) and a good sensitivity of 1.44. The strain-related deformation of the PDMS/MWCNT composite network resulted in a variation in the sensor resistance; thus, the strain level that corresponds to different finger motions is be calculated. Finally, the fabricated and optimized electronic sensor in filiform structure with a 6% MWCNT ratio was integrated with smart fabric to create a finger sleeve for real-time motion capture. In conclusion, a novel hybrid E-fiber sensor based on PDMS and MWCNTs was successfully fabricated in the current study with an optimal M/P ratio and structure, and textile techniques were adopted as new packaging approaches for such soft electronic sensors to create smart fabric for wearable and precise detection with highly enhanced sensing performance. The successful results in the current study demonstrate the great potential of such hybrid soft sensors in smart wearable healthcare management, including motion detection.

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In this study, a new non-enzymatic carbon paste biosensor was developed for the determination of Bisphenol-A (BPA) based on Multiwalled Carbon Nanotube (MWCNT) modified Myoglobin (Mb). The measurement principle of the biosensor was developed based on the inhibition effect of BPA on the heme group of myoglobin in the presence of hydrogen peroxide. With the designed biosensor, measurements were taken in the potential range of (-0.15 V & +0.65 V) using the differential pulse voltammetry (DPV) method in the medium containing K4[Fe(CN)6]. The linear range for BPA was determined to be 100-1000 µM. Response time was calculated as 16 s. The limit of detection was set at 89 µM. As a result, it has been proven that MWCNT modified myoglobin based biosensor is an alternative method that can be used for BPA determination, giving very sensitive and fast results.

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Unlike conventional lead ion (Pb2+) detecting methods, electrochemical methods have the attractive advantages of rapid response, good portability and high sensitivity. In this paper, a planar disk electrode modified by multiwalled carbon nanotube (MWCNTs)/chitosan (CS)/lead (Pb2+) ionophore IV nanomaterial and its matched system are proposed. This system presented a good linear relationship between the concentration of Pb2+ ions and the peak current in differential pulse stripping voltammetry (DPSV), under optimized conditions of -0.8 V deposition potential, 5.5 pH value, 240 s deposition time, performed sensitive detection of Pb2+ within sensitivity of 1.811 µA · µg-1 and detection limit of 0.08 µg · L-1. Meanwhile, the results of the system in detecting lead ions in real seawater samples are highly similar to that of inductively coupled plasma emission spectrometer (ICP-MS), which proved a practicability for the system in detection of trace-level Pb2+.

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An alternative biotechnological solid phase bio-extraction (SPE) method was developed. Bacillus subtilis loaded multiwalled carbon nanotube was designed and used as biosorbent for the preconcentrations of Pb(II), Ni(II), and Zn(II). The experimental parameters such as sample flow rate, pH of sample solution, amounts of Bacillus subtilis and multiwalled carbon nanotube, volume of sample solution and reusability of column which affects the analytical characteristics of the SPE method were investigated in details. Surface structures were examined by using FTIR, SEM. The best pH was determined as 5.0 and the percentages recoveries of Zn(II), Ni(II), and Pb(II) were determined as 99.1%, 98.7%, and 96.2%, respectively, at a flow rate of 3 mL/min. In this study, in which the profitable sample volume was determined as 400 mL and the amount of multiwalled carbon nanotube (MWCNT) as 50 mg. It was also observed that the column had a significant potential to preconcentrate Zn(II), Ni(II), and Pb(II) even after 25 reuses. The biosorption capacities for Zn(II), Ni(II) and Pb(II) were calculated as 39.67 mg/g, 45.98 mg/g and 51.34 mg/g respectively. The LOD values were calculated as 0.024 ng/mL for Pb(II), 0.029 ng/mL for Ni(II), and 0.019 ng/mL for Zn(II). The linear range was detected as 0.25-25 ng/mL. The concentrations of Pb(II), Ni(II), and Zn(II) in a variety of real food samples were determined by using developed method after application of certified reference sample.

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For further commercializing proton-exchange membrane fuel cells, it is crucial to attain long-term durability while achieving high performance. In this study, a strategy for modifying commercial Nafion membranes by introducing ultrathin multiwalled carbon nanotubes (MWCNTs)/CeO2 layers on both sides of the membrane was developed to construct a mechanically and chemically reinforced membrane electrode assembly. The dispersion properties of the MWCNTs were greatly improved through chemical modification with acid treatment, and the mixed solution of MWCNTs/CeO2 was uniformly prepared through a high-energy ball-milling process. By employing a spray-coating technique, the ultrathin MWCNTs/CeO2 layers were introduced onto the membrane surfaces without any agglomeration problem because the solvent rapidly evaporated during the layer-by-layer stacking process. These ultrathin and highly dispersed MWCNTs/CeO2 layers effectively reinforced the mechanical properties and chemical durability of the membrane while minimizing the performance drop despite their non-ion-conducting properties. The characteristics of the MWCNTs/CeO2 layers and the reinforced Nafion membrane were investigated using various in situ and ex situ measurement techniques; in addition, electrochemical measurements for fuel cells were conducted.

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The screen-printing process of conductive ink can realize simple and large-scale manufacture of micro/nano patterns for producing wearable electronic products. Herein, chitin nanocrystals (ChNCs) are used as a dispersant for the preparation of multiwalled carbon nanotube (MWCNT) ink with high viscosity and uniformity by ultrasound treatment. ChNCs can interact with MWCNT in noncovalent ways, including π-π and hydrophobic interactions. ChNCs/MWCNT (CCNT) ink does not aggregate even after standing for 3 months with a maximum MWCNT concentration of 33 mg mL-1 and dispersion efficiency of 91.1%. Using CCNT ink, a paper-based thermoelectric generator (TEG) is manufactured by screen-printing technology. With good thermoelectric and strain sensing properties, CCNT coated paper can stably collect human energy at room temperature to realize self-powering. The CCNT coated paper-based TEG can convert thermal voltage signals into musical notes, monitor the changes in human behavior and respiratory rate, and monitor joint movements. Moreover, CCNT coated paper has no cytotoxicity by CCK-8 and live/dead staining. This work puts forward a strategy of green preparation of MWCNT-based ink by adding renewable chitin, which opens up a new way to apply MWCNT-based ink in self-powering wearable multifunctional sensors.

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Continuous detection of toxic and hazardous gases like nitric oxide (NO) and ammonia (NH3) is needed for environmental management and noninvasive diagnosis of various diseases. However, to the best of our knowledge, dual detection of these two gases has not been previously reported. To address the challenge, we demonstrate the design and fabrication of low-cost NH3 and NO dual gas sensors using tungsten disulfide/multiwall carbon nanotube (WS2/MWCNT) nanocomposites as sensing channels which maintained their performance in a humid environment. The composite-based device has shown successful dual detection at temperatures down to 18 °C and relative humidity of 90%. For 0.1 ppm ammonia, it exhibited a p-type conduction with response and recovery times of 102 and 261 s, respectively; on the other hand, with NO (10 ppb, n-type), these times were 285 and 198 s, respectively. The device with 5 mg MWCNTs possesses a superior selectivity along with a relative response of ≈7% (5 ppb) and ≈5% (0.1 ppm) for NO and NH3, respectively, at 18 °C. The response is less affected by relative humidity, and this is attributed to the presence of MWCNTs that are hydrophobic in nature. Upon simultaneous exposure to NO (5-10 ppb) and NH3 (0.1-5 ppm), the response was dominated by NO, implying clear discrimination to the simultaneous presence of these two gases. We propose a sensing mechanism based on adsorption/desportion and accompanied charge transfer between the adsorbed gas molecules and sensing surface. The results suggest that an optimized weight ratio of WS2 and MWCNTs could govern favorable sensing conditions for a particular gas molecule.

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Carbon−polymer composite-based pressure sensors have many attractive features, including low cost, easy integration, and facile fabrication. Previous studies on carbon−polymer composite sensors focused on very high sensitivities for low pressure ranges (10 s of kPa), which saturate quickly at higher pressures and thus are ill-suited to measure the high pressure ranges found in various applications, including those in underwater (>1 atm, 101 kPa) and industrial environments. Current sensors designed for high pressure environments are often difficult to fabricate, expensive, and, similarly to their low-pressure counterparts, have a narrow sensing range. To address these issues, this work reports the design, synthesis, characterization, and analysis of high-pressure TPU-MWCNT based composite sensors, which detect pressures from 0.5 MPa (4.9 atm) to over 10 MPa (98.7 atm). In this study, the typical approach to improve sensitivity by increasing conductive additive concentration was found to decrease sensor performance at elevated pressures. It is shown that a better approach to elevated pressure sensitivity is to increase sensor response range by decreasing the MWCNT weight percentage, which improves sensing range and resolution. Such sensors can be useful for measuring high pressures in many industrial (e.g., manipulator feedback), automotive (e.g., damping elements, bushings), and underwater (e.g., depth sensors) applications.

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The macromorphic properties of carbon nanotubes perform poorly because of their size limitations: nanosize in diameters and microsize in length. In this work, to realize these dual purposes, we first used an electrochemical method to tear the surface of multiwalled carbon nanotubes (MWCNTs) to anchor photonic Eu3+-complexes there. Through the polar reactive groups endowed by the tearing, the Eu3+-complexes coordinate at the defected structures, obtaining the Eu3+-complex-anchored, unzipped, multiwalled carbon nanotubes (E-uMWCNTs). The controllable surface-breaking retains the MWCNTs' original, excellent mechanical properties. Then, to obtain the macromorphic structure with infinitely long fibers, a wet-spinning process was applied via the binding of a small quantity of polyvinyl alcohol (PVA). Thus, the wet-spun fibers with high contents of E-uMWCNTs (E-uMWCNT-Fs) were produced, in which the E-uMWCNTs took 33.3 wt%, a high ratio in E-uMWCNT-Fs. On the other hand, due to the reinforcing effect of E-uMWCNTs, the highest tensile strength can reach 228.2 MPa for E-uMWCNT-Fs. Meanwhile, the E-uMWCNT-Fs show high-efficiency photoluminescence and excellent media resistance performance due to the embedding effect of PVA on the E-uMWCNTs. Therefore, E-uMWCNT-Fs can exhibit excellent luminescence properties in aqueous solutions at pH 4~12 and in some high-concentration metal-ion solutions. Those distinguished performances promise outstanding innovations of this work.

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The pandemic of the coronavirus disease 2019 (COVID-19) has made biotextiles, including face masks and protective clothing, quite familiar in our daily lives. Biotextiles are one broad category of textile products that are beyond our imagination. Currently, biotextiles have been routinely utilized in various biomedical fields, like daily protection, wound healing, tissue regeneration, drug delivery, and sensing, to improve the health and medical conditions of individuals. However, these biotextiles are commonly manufactured with fibers with diameters on the micrometer scale (> 10 µm). Recently, nanofibrous materials have aroused extensive attention in the fields of fiber science and textile engineering because the fibers with nanoscale diameters exhibited obviously superior performances, such as size and surface/interface effects as well as optical, electrical, mechanical, and biological properties, compared to microfibers. A combination of innovative electrospinning techniques and traditional textile-forming strategies opens a new window for the generation of nanofibrous biotextiles to renew and update traditional microfibrous biotextiles. In the last two decades, the conventional electrospinning device has been widely modified to generate nanofiber yarns (NYs) with the fiber diameters less than 1000 nm. The electrospun NYs can be further employed as the primary processing unit for manufacturing a new generation of nano-textiles using various textile-forming strategies. In this review, starting from the basic information of conventional electrospinning techniques, we summarize the innovative electrospinning strategies for NY fabrication and critically discuss their advantages and limitations. This review further covers the progress in the construction of electrospun NY-based nanotextiles and their recent applications in biomedical fields, mainly including surgical sutures, various scaffolds and implants for tissue engineering, smart wearable bioelectronics, and their current and potential applications in the COVID-19 pandemic. At the end, this review highlights and identifies the future needs and opportunities of electrospun NYs and NY-based nanotextiles for clinical use.

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The synergistic effect of applying hybrid nanoparticles in improving the fatigue property of fiber reinforced polymer composites has rarely been explored before. Hence the monotonic and fatigue flexure properties of the carbon fiber reinforced epoxy laminates with matrix modified by multiwalled carbon nanotubes and graphene nanoplatelets were experimentally studied herein. The nanofiller ratio applied in the matrix modification was considered as a variable in the experimental program to investigate the effect of nanofiller ratio on the studied mechanical properties. A synergistic index has been employed to evaluate the synergistic effect of hybrid nanoparticles on the studied properties successfully. Experimental results show that the laminates with matrix modified under a nanofiller ratio (multiwalled carbon nanotube: graphene nanoplatelet) of 9:1 have the higher monotonic and fatigue strengths than those modified under other nanofiller ratios. The monotonic flexural strength and fatigue limit of the specimens modified under a nanofiller ratio of 9:1 are higher than the neat laminate specimens by 9.3 and 11.0%, respectively. The fatigue limits of the studied nano-modified laminates increase with the static strengths. Adding hybrid nanoparticles under proper nanofiller ratios in the matrix can suppress the degradation of the stiffness, further increase the resistance to fatigue damage. Examining the fracture surfaces of fatigued specimens reveals that the pullout/bridging effects of carbon nanotubes and the crack deflection effect of graphene nanoplatelets are the main reinforcement mechanisms in enhancing the fatigue strength of the composites.

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It is of great significance to develop a new gravity-driven filter to remove water pollutants, but it is still challenging. Here, a novel and simple strategy is demonstrated to manufacture fly ash (FA) ceramic foams showing a three-dimensional interconnected porous structure, with multiwalled carbon nanotubes (MWCNTs) implanted by combining carbamate grafting and polydimethylsiloxane coating. The polydimethylsiloxane formed a physical coating on the carbamate group, generating an effective thermal insulating layer on the outer side of the entire MWCNT. The FA foam, which shows a sufficient adsorption capacity for Pb(II) (51.67 ± 1.17 mg g-1) and Cd(II) (30.12 ± 0.37 mg g-1) at pH = 5, T = 25 °C, has a 96.33%, 95.12%, 89.50% removal efficiency for Cd(II), Pb(II), and particulate pollutants, and exhibits excellent recycling performance. This paper provides new opportunities to fabricate gravity-driven filters with low energy consumption for wastewater treatment.

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The monotonic and cyclic properties of carbon fiber-reinforced epoxy (CFEP) laminate specimens with matrices modified by multiwalled carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) were experimentally studied. The laminate specimens were fabricated by the hand lay-up procedure and six MWCNT:GNP weight ratios, i.e., 0:0, 10:0, 0:10, 5:5, 9:1, and 1:9, were considered to prepare the nanoparticle-modified epoxy resin by using an ultrasonic homogenizer and a planetary centrifugal mixer. Then, these laminate specimens with their matrices modified under various nanofiller ratios were employed to investigate the influence of the number of nanofiller types and hybrid nanofiller ratios on the quasi-static strength, fatigue strength, and mode I fracture toughness. The experimental results show that adding individual types of nanoparticles has a slight influence on the quasi-static and fatigue strengths of the CFEP laminates. However, the remarkable synergistic effect of MWCNTs and GNPs on the studied mechanical properties of the CFEP laminates with matrices reinforced by hybrid nanoparticles has been observed. Examining the evolution of stiffness-based degradation indicates that adding hybrid nanoparticles to the matrix can reduce the degradation effectively. The high experimental data of the mode I fracture toughness of hybrid nano-CFEP laminates demonstrate that embedding hybrid nanoparticles in the matrix is beneficial to the interlaminar properties, further improving the fatigue strength. The pushout mechanism of the MWCNTs and the crack deflection effect of the GNPs suppress the growth and linkage of microcracks in the matrix. Furthermore, the bridging effect of the nanoparticles at the fiber/matrix interface retards the interfacial debonding, further improving the resistance to delamination propagation.