RESUMEN
A major challenge in the pursuit of higher-energy-density lithium batteries for carbon-neutral-mobility is electrolyte compatibility with a lithium metal electrode. This study demonstrates the robust and stable nature of a closo-borate based gel polymer electrolyte (GPE), which enables outstanding electrochemical stability and capacity retention upon extensive cycling. The GPE developed herein has an ionic conductivity of 7.3 × 10-4 S cm-2 at room temperature and stability over a wide temperature range from -35 to 80 °C with a high lithium transference number ( tLi+$t_{{\rm{Li}}}^ + $ = 0.51). Multinuclear nuclear magnetic resonance and Fourier transform infrared are used to understand the solvation environment and interaction between the GPE components. Density functional theory calculations are leveraged to gain additional insight into the coordination environment and support spectroscopic interpretations. The GPE is also established to be a suitable electrolyte for extended cycling with four different active electrode materials when paired with a lithium metal electrode. The GPE can also be incorporated into a flexible battery that is capable of being cut and still functional. The incorporation of a closo-borate into a gel polymer matrix represents a new direction for enhancing the electrochemical and physical properties of this class of materials.
Asunto(s)
Boratos , Litio , Electrólitos , Litio/química , Polímeros , TemperaturaRESUMEN
A self-powered electrochromic device (ECD) powered by a self-rechargeable battery is easily fabricated to achieve electrochromic window design, quantitative reactive oxygen species (ROS) sensing, and energy storage. The special design of the battery was composed of Prussian blue (PB) and magnesium metal as the cathode and anode, respectively, which exhibits fast self-charging and high power-density output for continuous and stable energy supply. Benefitting from the fast electrochromic response of PB, it was not only used for structuring self-rechargeable batteries but also used as an electrochromic display for highly sensitive self-powered ROS sensing and visual analysis. We believe that this work provides a solution to self-powered ECDs limited to a single application and could combine the applications in smart windows, ROS sensing, and other fields together, and in the meantime provide a solution for energy supply problems.
RESUMEN
A solution-processed self-powered polymer electrochromic/photovoltaic (EC/PV) device is realized by vertically integrating two transparent PV cells with an ECD. The EC/PV cell is a net energy positive dual functional device, which can be reversibly switched between transparent and colored states by PV cells for regulating incoming sunlight through windows. The two PV cells can individually, or in pairs, generate electricity.