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Developing countries primarily rely on fossil-based energy sources to meet their energy demands. The use of fossil fuels has several adverse environmental repercussions that damage the biosphere both directly and indirectly. Among fossil fuels, coal brings about the heaviest environmental externalities, yet its abundance makes its use widespread, particular in countries having significant power generation deficits, such as Pakistan. This study presents an environmental, technological, and economic analysis of a supercritical coal-based power unit located in Pakistan and used for electricity generation. For environmental assessment, the CML-1A baseline method in OpenLCA software was used, and eight midpoint impact indicators were selected. The functional unit chosen was 1 MWh of generated electricity. The results indicated that the category of ozone layer depletion has the least impact, whereas global warming potential has the highest impact score. Except for photochemical oxidation and human toxicity, the plant operational stage dominated most of the selected impact categories. The current paper also reveals that the removal efficiency of CO2 and other pollutants is higher in supercritical compared to subcritical plants. Moreover, the economic feasibility of supercritical plant is compared with chemical looping combustion (CLC)-based supercritical coal-fired power plant, and results shows that CLC-based coal-fired power plant is a more competitive and environmentally friendly option. The utilization of a scientific cleaner energy-management system in real-time, as exemplified in this study, may facilitate the development of a optimal policy framework that encourages for the adoption of cleaner coal power generation in developing countries, ultimately resulting in improved energy sustainability. Furthermore, this paper also presents some policy implications which could be helpful for policymakers, researchers, and industrialists to improve the sustainability of energy in emerging economies.

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Microalgal tolerance to emerging contaminants (ECs) such as 1,4 dioxane (DXN) and its impact on phycoremediation performance, algal growth, biomolecules generated, and recycling the produced biomass for biochar production has been rarely reported. Hence, Chlorella vulgaris was cultivated in DXN-free wastewater (WW1) and 100 mg L-1 DXN-laden wastewater (WW2) in 1-liter photobioreactors with an operating volume of 800 ml under controlled conditions: temperature (25 ± 1 °C), light intensity (351 µmol m-2s-1), and photoperiod (12 h light:12 h dark). Interestingly, this microalgal-based system achieved up to 32.79% removal efficiency of DXN in WW2. In addition, there was no significant difference in the removal of COD (90.6% and 86.8%) and NH4-N (74.5% and 76.8%) between WW1 and WW2, respectively. Moreover, the variation in C. vulgaris growth, pigments, lipid, and carbohydrate contents between the two applied wastewaters was negligible. However, there was a significant increase in the protein yield upon exposure to DXN, suggesting the ability of C. vulgaris to secrete various antioxidant and degrading enzymes to detoxify the contaminant. These results were validated by FTIR, SEM, and EDX analysis of C. vulgaris biomass with and without DXN exposure. The harvested biomass was thermally treated at 350 °C for 60 min in an oxygen-free environment. The biochars generated from both algal systems were characterized by comparable morphologies and elemental profiles with sufficient C and N contents, indicating their applicability to enhance the soil properties. The economic evaluation of the combined phycoremediation/pyrolysis system demonstrated a net profit of 596 USD⋅y-1 with a payback period of 6.2 years and fulfilled the objectives of several sustainable development goals (SDGs). This is the first study to point to C. vulgaris as a robust microalgal strain in remediating DXN-laden wastewater accompanied by the potential recyclability of the biomass produced for biochar production.

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The rampant exploitation of fossil fuels has led to the significant energy scarcity and environmental disruption, affecting the sound momentum of development and progress of human civilization. To build a closed-loop anthropogenic carbon cycle, development of biofuels employing sustainable biomass feedstocks stands at the forefront of advancing carbon neutrality, yet its widespread adoption is mainly hampered by the high production costs. Montmorillonite, however, has garnered considerable attention serving as an efficient heterogeneous catalyst of ideal economic feasibility for biofuel production, primarily due to its affordability, accessibility, stability, and excellent plasticity. Up to now, nevertheless, it has merely received finite concerns and interests in production of various biofuels using montmorillonite-based catalysts. There is no timely and comprehensive review that addresses this latest relevant progress. This review fills the gap by providing a systematically review and summary in controllable synthesis, performance enhancement, and applications related to different kinds of biofuels including biodiesel, biohydrogenated diesel, levulinate, γ-valerolactone, 5-ethoxymethylfurfural, gaseous biofuels (CO, H2), and cycloalkane, by using montmorillonite catalysts and its modified forms. Particularly, this review critically depicts the design strategies for montmorillonite, illustrates the relevant reaction mechanisms, and assesses their economic viability, realizing sustainable biofuels production via efficient biomass valorization.

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With a growing export and local market, sheep farming is critical to the economy of smallholder farmers; however, indigenous sheep breeds usually exhibit low carcass output and live weight due to nutritional constraints. The study aimed to investigate the impact of supplementing local sheep with dawri-damaa leaf meal (DDLM) on their performance, carcass characteristics, and profitability when fed native grass hay. The research used a randomized complete block design (RCBD) to administer four feeding treatments (T1, T2, T3, and T4 at 0%, 30%, 50%, and 70% DDLM, respectively) to 20 local uncastrated male lambs having an average 23.72 ± 0.73 kg body weight and average age of 11.72 ± 0.74 months. Greater doses of DDLM in the diet resulted in greater average daily gain (ADG) of 51.4-83.8 g/day and feed conversion efficiency (FCE) of 0.066-0.089 in lambs, compared to 15.0 g/day ADG and 0.025 FCE in lambs under control diet (T1). Additionally, the lambs had increased slaughter body weight (SBW), empty body weight (EBW), and hot carcass weight (HCW) in T4 and T3 compared to other treatments (p < .05). There were no significant differences in dressing percentages (DPs) across any treatment group. The study also discussed the economic viability of supplementing with DDLM, suggesting that feeding 70% daily dry matter of DDLM at 2.5% live weight might be beneficial depending on availability, access, and cost factors. In conclusion, feeding DDLM up to 70% has improved the performance of sheep and is economically feasible. Further research might be required to discover whether such levels of inclusion are harmful and apply different processing methods for feeding animals.

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Microwave (MW) remediation of organics-contaminated soil technology offers the advantages of high efficiency and minimal damage, representing a new approach of soil thermal remediation. However, soil, being a weak MW-absorbing medium, struggles to convert MW energy into thermal energy, thus failing to attain the necessary temperature for thermal remediation. This paper prepared two new bluecoke (BC)-based modifiers (KHCO3@BC and KHCO3/MnO2@BC) to address temperature problem of MW remediation, as well as enhance soil quality. Their composition, structure and electromagnetic properties were analyzed to investigate their role in assisting with the MW remediation of an artificially crude oil-contaminated soil were investigated. Additionally, the industrial feasibility of MW remediation was addressed for the first time. The results showed that the KHCO3 and MnO2 particles in the two modifiers were covered on the BC surface and exhibited local agglomeration. Their carbon crystalline grain size increased, and the electromagnetic properties were weaker than those of the BC. Following 10 min of MW remediation assisted by KBC or KMnBC, the remediation temperatures exceeded 300 °C, with the removal rates of PHs reaching 76.16% and 88.31%, respectively. The organic matter content, soil potassium and mechanical fraction of the remediated soil were improved, but soil acidification still needed to be further addressed. The industrial application analysis indicated that the technical process and techno-economics of MW remediation of crude oil-contaminated soil were feasible, suggesting significant potential for the large-scale industrial application.

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BACKGROUND: Urban agriculture significantly contributes to food security. The two primary components of urban agriculture are livestock production and horticulture. The goat, Capra hircus, is one of the commonly raised food animals. Goats can be used to generate income, produce milk, meat, skins, furs (hairs) and manure and provide various sociocultural and ecological services. OBJECTIVES: This study evaluates the significance of urban goat production and recommends ways to lessen the adverse impacts of urban goat production. METHODS: This report involved an in-depth interview with seven key informants in Adama and Addis Ababa cities. RESULTS: Goats can thrive in limited urban open spaces, scavenge leftovers from homes and open markets and browse on open public land. Goats can be incorporated into urban agriculture, in so doing contributing to a circular economy. Goats can thrive on a limited supply of water and feed and require less care and space. Goat farming is used to mitigate the adverse impact of climate change. Goats are naturally active, which makes them better at avoiding traffic accidents. Goats can be used to control bush encroachment. Goat farming in cities improves land use efficiency and food security. Being friendly animals, goats can be utilized to play with kids, and they can be a basic piece of metropolitan ecotourism. However, goats can harm urban green spaces; therefore, to avoid issues of this kind, goat production must be zoned. CONCLUSIONS: Urban goat farming could add a new dimension to urban food security. Extensive pieces of empirical evidence need to be generated to enhance the adoption of urban goat farming.

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Climate change-induced saline intrusion into both surface and groundwater, extreme weather events, and unregulated water usage are serious threats to the drinking water supply in coastal areas worldwide, especially in least-developed countries. This research developed a data-driven decision-making methodology to evaluate the performance of rainwater harvesting (RWH) systems in the saline-prone southwestern coastal region of Bangladesh. Twenty-five community managed RWH systems, recently piloted in two major coastal districts, were considered the case study to develop and validate this evaluation tool. The evaluation methodology integrates daily water models, lifetime cost analysis, Geographic Information System (GIS)-based parameters supported by the Analytical Hierarchy Process (AHP), and field observation. While the meteorological parameters as well as the hydrological and economic performance were found to be highly suitable, 36 % of the systems showed moderate performance, as challenges remain in ensuring proper operation and maintenance practices at the community level. However, 40 % of the systems showed high performance, with two systems showing very high suitability, which suggests community managed RWH systems as a sustainable adaptation for coastal water supply.

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This study focused on the economic feasibility of two potential industrial-scale bioleaching technologies for metal recovery from specific metallurgical by-products, mainly basic oxygen steelmaking dust (BOS-D) and goethite. The investigation compared two bioleaching scaling technology configurations, including an aerated bioreactor and an aerated and stirred bioreactor across different scenarios. Results indicated that bioleaching using Acidithiobacillus ferrooxidans proved financially viable for copper extraction from goethite, particularly when 5% and 10% pulp densities were used in the aerated bioreactor, and when 10% pulp density was used in the aerated and stirred bioreactor. Notably, a net present value (NPV) of $1,275,499k and an internal rate of return (IRR) of 65% for Cu recovery from goethite were achieved over 20-years after project started using the aerated and stirred bioreactor plant with a capital expenditure (CAPEX) of $119,816,550 and an operational expenditure (OPEX) of $5,896,580/year. It is expected that plant will start to make profit after one year of operation. Aerated and stirred bioreactor plant appeared more reliable alternative compared to the aerated bioreactor plant as the plant consists of 12 reactors which can allow better management and operation in small volume with multiple reactors. Despite the limitations, this techno-economic assessment emphasized the significance of selective metal recovery and plant design, and underscored the major expenses associated with the process.

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The broader adoption of urine-diverting technologies (UDTs) and related products has been proposed as a strategy for moving towards a more circular economy. While some studies have explored the performance of UDTs, the interconnected factors involving supply, demand, and economic feasibility of UDTs remain under-researched. Our systematic review addresses this gap. Our search identified only 64 relevant, peer-reviewed studies, 71 % of which addressed the supply side (primarily the technical aspect of UDTs) and 58 % of which addressed the demand side (focusing on consumers' perceptions). Approximately one-third (18) of these studies delved into the economic feasibility of UDTs, with only 9 employing a cost benefit analysis (CBA) framework. However, none of these studies have analysed the economic performance of UDTs that have been fully deployed, indicating a significant knowledge gap. Our review suggests that overcoming challenges in scaling up UDTs can be achieved by engaging those stakeholders driving the uptake, developing business cases that offer an overall understanding of both market and non-market benefits of UDTs, addressing technological constraints by optimising urine treatment options for efficiency and economic viability, and enhancing stakeholders' acceptance of UDTs.

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With advancements in research and the necessity of improving the performance of bioelectrochemical system (BES), coupling anaerobic digestion (AD) with BES is crucial for energy gain from wastewater and bioremediation. Hybridization of BES-AD concept opens new avenues for pollutant degradation, carbon capture and nutrient-resource recovery from wastewater. The strength of merging BES-AD lies in synergy, and this approach was employed to differentiate fads from strategies with the potential for full-scale implementation and making it an energy-positive system. The integration of BES and AD system increases the overall performance and complexity of combined system and the cost of operation. From a technical standpoint, the primary determinants of BES-AD feasibility for field applications are the scalability and economic viability. High potential market for such integrated system attract industrial partners for more industrial trials and investment before commercialization. However, BES-AD with high energy efficacy and negative economics demands performance boost.

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Phosphorous (P) removal in wastewater treatment is essential to prevent eutrophication in water bodies. Side-stream enhanced biological phosphorous removal (S2EBPR) is utilized to improve biological P removal by recirculating internal streams within a side-stream reactor to generate biodegradable carbon (C) for polyphosphate accumulating organisms (PAOs). In this study, a full-scale S2EBPR system in a water resource recovery facility (WRRF) was evaluated for 5 months. Batch experiments revealed a strong positive correlation (r = 0.91) between temperature and C consumption rate (3.56-8.18 mg-COD/g-VSS/h) in the system, with temperature ranging from 14°C to 18°C. The anaerobic P-release to COD-uptake ratio decreased from 0.93 to 0.25 mg-P/mg-COD as the temperature increased, suggesting competition between PAOs and other C-consumers, such as heterotrophic microorganisms, to uptake bioavailable C. Microbial community analysis did not show a strong relationship between abundance and activity of PAO in the tested WRRF. An assessment of the economic feasibility was performed to compare the costs and benefits of a full scale WRRF with and without implementation of the S2EBPR technology. The results showed the higher capital costs required for S2EBPR were estimated to be compensated after 5 and 11 years of operation, respectively, compared to chemical precipitation and conventional EBPR. The results from this study can assist in the decision-making process for upgrading a conventional EBPR or chemical P removal process to S2EBPR. PRACTITIONER POINTS: Implementation of S2EBPR presents adaptable configurations, exhibiting advantages over conventional setups in addressing prevalent challenges associated with phosphorous removal. A full-scale S2EBPR WRRF was monitored over 5 months, and activity tests were used to measure the kinetic parameters. The seasonal changes impact the kinetic parameters of PAOs in the S2EBPR process, with elevated temperatures raising the carbon demand. PAOs abundance showed no strong correlation with their activity in the full-scale S2EBPR process in the tested WRRF. Feasibility assessment shows that the benefits from S2EBPR operation can offset upgrading costs from conventional BPR or chemical precipitation.

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The purpose of this study is to design and investigate two coupling processes for acid-catalyzed hydrolysis of corncob, achieving the simultaneous preparation of biomass-based furfural and levulinic acid (LA). Meanwhile, high concentration and yield of LA were obtained through a situ feeding strategy of pretreated furfural residue with high solids loading (20%, w/v). In Scenario A, 2-methyltetrahydrofuran was selected as the solvent for the LA extraction process compared with the neutralization process in Scenario B. Techno-economic assessment results show that Scenario A is technically feasible and cost-competitive, with an internal rate of return of 21.92%, a net present value of 121 million US dollars, a carbon efficiency of 72%, an environmental factor of 4.38, and a process mass intensity of 32.19. This study will provide new insights for fully utilizing lignocellulosic biomass to prepare renewable energy resources, comprehensively evaluating the economic feasibility, and promoting green and low-carbon development.

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The pulp-paper industry is one of the main industrial sectors that produce massive amounts of residual sludge, constituting an enormous environmental burden for the industries. Traditional sludge management practices, such as landfilling and incineration, are restricted due to mounting environmental pressures, complex regulatory frameworks, land availability, high costs, and public opinion. Valorization of pulp-paper industry sludge (PPS) to produce high-value products is a promising substitute for traditional sludge management practices, promoting their reuse and recycling. Valorization of PPIS for biorefinery beneficiation includes biomethane, biohydrogen, bioethanol, biobutanol, and biodiesel production for renewable energy generation. Additionally, the various thermo-chemical technologies can be utilized to synthesize bio-oil, hydrochar, biochar, adsorbent, and activated carbon, signifying potential for value-added generation. Moreover, PPIS can be recycled as a byproduct by incorporating it into nanocomposites, cardboard, and construction materials development. This paper aims to deliver a comprehensive overview of PPIS management approaches and thermo-chemical technologies utilized for the development of platform chemicals in industry. Substitute uses of PPIS, such as making building materials, developing supercapacitors, and making cardboard, are also discussed. In addition, this article deeply discusses recent developments in biotechnologies for valorizing PPIS to yield an array of valuable products, such as biofuels, lactic acids, cellulose, nanocellulose, and so on. This review serves as a roadmap for future research endeavors in the effective handling of PPIS.

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The worldwide use of clean and environmentally friendly renewable energy sources, has been increasing to prevent global warming and climate change. In this study, a hybrid renewable energy system (HRES) including biomass and solar as the source, has been investigated for Mehmet Akif Ersoy University Istiklal Campus in Burdur, Türkiye. The campus has an animal farm consisting of 300 cattle and 200 sheep. Therefore, manure of the animals will be used as the resource for biomass generation. HOMER software is used to simulate the system and to find the size and the quantity of the equipment according to the meteorological and biomass capacity of the campus. The optimum system is determined by means of net present cost (NPC) and the cost of energy (COE). In the simulation, wind energy is also investigated but since the wind speed is not sufficient to produce energy in the region, it is not considered in the optimum system. The optimum system is determined to be grid connected biomass-solar system with 5000 kW PV panels and a 1500 kW biomass generator assisted by the grid of 3000 kW. Also, the NPC of the system is estimated to be USD 18.800.000 and the COE for the system is calculated as 0,107 USD/kWh. The system also reduces the emissions causing the global warming.

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Biomass-derived sustainable aviation fuel holds significant potential for decarbonizing the aviation sector. Its long-term viability depends on crop choice, longevity of soil organic carbon (SOC) sequestration, and the biomass-to-biojet fuel conversion efficiency. We explored the impact of fuel price and SOC value on viable biojet fuel production scale by integrating an agroecosystem model with a field-to-biojet fuel production process model for 1,4-dimethylcyclooctane (DMCO), a representative high-performance biojet fuel molecule, from Miscanthus, sorghum, and switchgrass. Assigning monetary value to SOC sequestration results in substantially different outcomes than an increased fuel selling price. If SOC accumulation is valued at $185/ton CO2, planting Miscanthus for conversion to DMCO would be economically cost-competitive across 66% of croplands across the continental United States (US) by 2050 if conventional jet fuel remains at $0.74/L (in 2020 US dollars). Cutting the SOC sequestration value in half reduces the viable area to 54% of cropland, and eliminating any payment for SOC shrinks the viable area to 16%. If future biojet fuel prices increase to $1.24/L-Jet A-equivalent, 48 to 58% of the total cultivated land in the United States could support a more diverse set of feedstocks including Miscanthus, sorghum, or switchgrass. Among these options, only 8-14% of the area would be suitable exclusively for Miscanthus cultivation. These findings highlight the intersection of natural solutions for carbon removal and the use of deep-rooted feedstocks for biofuels and biomanufacturing. The results underscore the need to establish clear and consistent values for SOC sequestration to enable the future bioeconomy.

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In adsorptive water treatment applications, the exploration of waste-derived activated carbon (AC) has gained substantial attention in scientific research. The use of waste materials as precursors for AC has gained attention due to its economic viability and potential to reduce the consumption of non-renewable resources. However, there is a lack of comprehensive literature regarding the costs and environmental impacts associated with the waste-based AC production and application. As sustainability practices gain importance, there has been an increase in research dedicated to estimating costs and conducting life cycle assessment (LCA) of AC production from waste sources. However, there is a need for thorough literature reviews that cover various methodologies and conclusions. The primary objective of this study is to provide a comprehensive overview and analysis of the economic and environmental factors related to the use of waste-derived AC in water treatment. LCA studies indicate that utilizing waste materials for AC production can lead to significant resource and energy savings compared to conventional methods relying on fossil resources. The cost of AC is influenced by factors such as precursor material cost, energy requirements during production (optimizable on an industrial scale), and properties of the resulting material. Additionally, the review emphasizes the significance of waste-based AC regeneration for sustainable viability. Evaluating the environmental and economic costs is crucial to support sustainability claims and avoid unsupported assertions. Overall, this study contributes to understanding the potential of waste-derived AC in water treatment and highlights the need for further research in this area.

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Constructed wetlands (CWs) represent the most viable artificial wastewater treatment system that works on the principles of natural wetlands. Filter media are integrally linked to CWs and have substantial impacts on their performance for pollutant removal. Carbon-derived substrates have been in the spotlight for decades due to their abundance, sustainability, reusability, and potential to treat complex contaminants. However, the efficiency and feasibility of carbon substrates have not been fully explored, and there are only a few studies that have rigorously analyzed their performance for wastewater treatment. This critical synthesis of the literature review offers comprehensive insights into the utilization of carbon-derived substrates in the context of pollutant removal, intending to enhance the efficiency and sustainability of CWs. It also compares several carbon-based substrates with non-carbon substrates with respect to physiochemical properties, pollutant removal efficiency, and cost-benefit analysis. Furthermore, it addresses the concerns and possible remedies about carbon filtration materials such as configuration, clogging minimization, modification, and reusability to improve the efficacy of substrates and CWs. Recommendations made to address these challenges include pretreatment of wastewater, use of a substrate with smaller pore size, incorporation of multiple filter media, the introduction of earthworms, and cultivation of plants. A current scientific scenario has been presented for identifying the research gaps to investigate the functional mechanisms of modified carbon substrates and their interaction with other CW components.

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Carcass characteristics, product quality, and the conversion of feed into meat with higher performance and feasibility are important determinants of the profitability and sustainability of any poultry enterprise. The objective of this study was to investigate the potential effect of Rumex nervosus leaf powder (RNLP) on carcass composition, small intestine dimensions, breast color quality, and economic feasibility of Ross broiler chickens. A total of 122 broilers were randomly distributed evenly among 4 treatments (0, 1, 3, and 5 g RNLP/ kg diet, n = 5 replicates per treatment, with 6 broilers per replicate: 3 ♀ and 3 ♂). Performance and economic data were collected in each replicate during the experiment. One male bird from each replication was examined for other criteria on d 34. Results showed that broilers fed 3 g of RNLP had a higher eviscerated carcass weight and dressing percentage (P < 0.05) than the control. The RNLP-fed broilers had higher weights and thicknesses in the duodenum and jejunum of up to 5 g and in the ileum and overall small intestine of up to 3 g. Broilers fed the lowest levels of RNLP had the highest revenue and net gain and the lowest cost-benefit ratio compared with those fed the highest levels of RNLP. The results indicate that the addition of RNLP has a positive effect on carcass processing, the intestinal measurements, and profitability ratios of the broilers. The 1 g RNLP/kg feed is the recommended dose to increase productivity and economic profitability ratios per kilogram of meat.

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The non-scientific disposal of antibiotics has resulted in massive contamination of the bioactive molecules in the aquatic ecosystem. The presence of antibiotics in the effluents limits the biodegradation of micropollutants by affecting the micro-ecological balance. Hence this study aims to remove doxycycline antibiotics from wastewater using biochar. Elemental analysis of the biochar revealed C, Si and N as most abundant content while BET analysis confirmed the mesoporous nature of the adsorbent. The XRD and Raman spectra confirmed amorphic sp2 carbon dominant structure in the biochar. The adsorption mechanism was predicted, correlating the charge distribution and FTIR analysis. The effects of different process parameters were studied using CCD, ANOVA, and RSM. Moreover, the different kinetic models revealed that the pseudo-second-order kinetics model was the best fit and film layer diffusion was the dominant contributor. The isotherm study indicated the high adsorption capacity of the biochar and its non-ionic nature. Thermodynamics study established the spontaneity and exothermic nature. The results suggested no significant change in antibiotic removal efficiency across different system (pond water (97.13%), river water (98.11%), seawater (96.84%), tap water (99.13%), and distilled water (99.74%)). For the desorption of the antibiotic from the biochar surface, 90% ethanol was the most efficient (98.9%), and upon recrystallization by solvent evaporation, 98.7% of the antibiotic of the initial load was recovered. Hence, the implementation of this described process would enable resource recovery along with water treatment, which is not possible with existing approaches. The cost analysis of the whole process revealed that biochar preparation was the bulk expense and the process would be self-sustainable even if the price of the recovered antibiotic would be set at less than half ($41/kg) of the current market price ($94/kg) of the API. Thus, the process endorses a successful circular economy approach toward societal and economic sustainability.

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