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1.
ACS Nano ; 18(24): 15769-15778, 2024 Jun 18.
Artículo en Inglés | MEDLINE | ID: mdl-38829376

RESUMEN

A polarized light source covering a wide wavelength range is required in applications across diverse fields, including optical communication, photonics, spectroscopy, and imaging. For practical applications, high degrees of polarization and thermal performance are needed to ensure the stability of the radiation intensity and low energy consumption. Here, we achieved efficient emission of highly polarized and broadband thermal radiation from a suspended aligned carbon nanotube film. The anisotropic nature of the film, combined with the suspension, led to a high degree of linear polarization (∼0.9) and great thermal performance. Furthermore, we performed time-resolved measurements of thermal emission from the film, revealing a fast time response of approximately a few microseconds. We also obtained visible light emission from the device and analyzed the film's mechanical breakdown behavior to improve the emission intensity. Finally, we demonstrated that suspended devices with a constriction geometry can enhance the heating performance. These results show that carbon nanotube film-based devices, as electrically driven thermal emitters of polarized radiation, can play an important role for future development in optoelectronics and spectroscopy.

2.
Entropy (Basel) ; 26(6)2024 Jun 09.
Artículo en Inglés | MEDLINE | ID: mdl-38920513

RESUMEN

The modern textbook analysis of the thermal state of photons inside a three-dimensional reflective cavity is based on the three quantum numbers that characterize photon's energy eigenvalues coming out when the boundary conditions are imposed. The crucial passage from the quantum numbers to the continuous frequency is operated by introducing a three-dimensional continuous version of the three discrete quantum numbers, which leads to the energy spectral density and to the entropy spectral density. This standard analysis obscures the role of the multiplicity of energy eigenvalues associated to the same eigenfrequency. In this paper we review the past derivations of Bose's entropy spectral density and present a new analysis of energy spectral density and entropy spectral density based on the multiplicity of energy eigenvalues. Our analysis explicitly defines the eigenfrequency distribution of energy and entropy and uses it as a starting point for the passage from the discrete eigenfrequencies to the continuous frequency.

3.
Sensors (Basel) ; 24(7)2024 Mar 22.
Artículo en Inglés | MEDLINE | ID: mdl-38610237

RESUMEN

Multispectral thermometry is based on the law of blackbody radiation and is widely used in engineering practice today. Temperature values can be inferred from radiation intensity and multiple sets of wavelengths. Multispectral thermometry eliminates the requirements for single-spectral and spectral similarity, which are associated with two-colour thermometry. In the process of multispectral temperature inversion, the solution of spectral emissivity and multispectral data processing can be seen as the keys to accurate thermometry. At present, spectral emissivity is most commonly estimated using assumption models. When an assumption model closely matches an actual situation, the inversion of the temperature and the accuracy of spectral emissivity are both very high; however, when the two are not closely matched, the inversion result is very different from the actual situation. Assumption models of spectral emissivity exhibit drawbacks when used for thermometry of a complex material, or any material whose properties dynamically change during a combustion process. To address the above problems, in the present study, we developed a multispectral thermometry method based on optimisation ideas. This method involves analysing connections between measured temperatures of each channel in a multispectral temperature inversion process; it also makes use of correlations between multispectral signals at different temperatures. In short, we established a multivariate temperature difference correlation function based on the principles of multispectral radiometric thermometry, using information correlations between data for each channel in a temperature inversion process. We then established a high-precision thermometry model by optimising the correlation function and correcting any measurement errors. This method simplifies the modelling process so that it becomes an optimisation problem of the temperature difference function. This also removes the need to assume the relationships between spectral emissivity and other physical quantities, simplifying the process of multispectral thermometry. Finally, this involves correction of the spectral data so that any impact of measurement error on the thermometry is reduced. In order to verify the feasibility and reliability of the method, a simple eight-channel multispectral thermometry device was used for experimental validation, in which the temperature emitted from a blackbody furnace was identified as the standard value. In addition, spectral data from the 468-603 nm band were calibrated within a temperature range of 1923.15-2273.15 K, resulting in multispectral thermometry based on optimisation principles with an error rate of around 0.3% and a temperature calculation time of less than 3 s. The achieved level of inversion accuracy was better than that obtained using either a secondary measurement method (SMM) or a neural network method, and the calculation speed achieved was considerably faster than that obtained using the SMM method.

4.
Sensors (Basel) ; 24(5)2024 Mar 06.
Artículo en Inglés | MEDLINE | ID: mdl-38475243

RESUMEN

High-precision temperature control of large-area blackbodies has a pivotal role in temperature calibration and thermal imaging correction. Meanwhile, it is necessary to correct the temperature difference between the radiating (surface of use) and back surfaces (where the temperature sensor is installed) of the blackbody during the testing phase. Moreover, large-area blackbodies are usually composed of multiple temperature control channels, and manual correction in this scenario is error-prone and inefficient. At present, there is no method that can achieve temperature-automated calibration for a large-area blackbody radiation source. Therefore, this article is dedicated to achieving temperature-automated calibration for a large-area blackbody radiation source. First, utilizing two calibrated infrared thermometers, the optimal temperature measurement location was determined using a focusing algorithm. Then, a three-axis movement system was used to obtain the true temperature at the same measurement location on a large-area blackbody surface from different channels. This temperature was subtracted from the blackbody's back surface. The temperature difference was calculated employing a weighted algorithm to derive the parameters for calibration. Finally, regarding experimental verification, the consistency error of the temperature measurement point was reduced by 85.4%, the temperature uniformity of the surface source was improved by 40.4%, and the average temperature measurement deviation decreased by 43.8%. In addition, this system demonstrated the characteristics of strong environmental adaptability that was able to perform temperature calibration under the working conditions of a blackbody surface temperature from 100 K to 573 K, which decreased the calibration time by 9.82 times.

5.
Sensors (Basel) ; 22(21)2022 Oct 29.
Artículo en Inglés | MEDLINE | ID: mdl-36365999

RESUMEN

In this paper, using automated optical inspection equipment and a thermal imager, the position and the temperature of the heat source or measured object can effectively be grasped. The high-resolution depth camera is with the stereo vision distance measurement and the low-resolution thermal imager is with the long-wave infrared measurement. Based on Planck's black body radiation law and Stefan-Boltzmann law, the binocular stereo calibration of the two cameras was calculated. In order to improve the measured temperature error at different distances, equipped with Intel Real Sense Depth Camera D435, a compensator is proposed to ensure that the measured temperature of the heat source is correct and accurate. From the results, it can be clearly seen that the actual measured temperature at each distance is proportional to the temperature of the thermal image vanadium oxide, while the actual measured temperature is inversely proportional to the distance of the test object. By the proposed compensation function, the compensation temperature at varying vanadium oxide temperatures can be obtained. The errors between the average temperature at each distance and the constant temperature of the test object at 39 °C are all less than 0.1%.

6.
Sensors (Basel) ; 22(15)2022 Jul 30.
Artículo en Inglés | MEDLINE | ID: mdl-35957279

RESUMEN

High-temperature measurements above 1000 °C are critical in harsh environments such as aerospace, metallurgy, fossil fuel, and power production. Fiber-optic high-temperature sensors are gradually replacing traditional electronic sensors due to their small size, resistance to electromagnetic interference, remote detection, multiplexing, and distributed measurement advantages. This paper reviews the sensing principle, structural design, and temperature measurement performance of fiber-optic high-temperature sensors, as well as recent significant progress in the transition of sensing solutions from glass to crystal fiber. Finally, future prospects and challenges in developing fiber-optic high-temperature sensors are also discussed.

7.
Ultrason Sonochem ; 78: 105727, 2021 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-34509955

RESUMEN

Sonoluminescence (SL) is an interesting physical effect which can convert acoustic energy into light pulses. Up to now, the microscopic mechanism of the SL has not yet been fully clear. It is known that hydroxyl radicals play the important role for SL from water. In this work, we take advantage of carbon nano-dots (CNDs) as free radical captors to modulate the hydroxyl radicals (OH) in SL effect. Through studying the single bubble SL (SBSL) from CND aqueous solution (CNDAS) with trace amount of CNDs, we find that the color of SBSL is tuned dramatically from blue in water to green in CNDAS. Two different SL mechanisms can be identified from emission spectrum. One comes from blackbody-like radiation and another is attributed from the characteristic emission with identified peaks. The decrease in the yield of H2O2 in the presence of CNDs suggests the modulation effect on SL via OH interacting with CNDs. By comparison of the CNDs before and after sonication, it is found that hydroxyl radicals generated during SL can take part in the chain-like oxidation of the chemical groups attached to the CNDs to form larger amount of carboxyl groups. The blackbody temperature of blackbody-like radiation decreases from 15,600 K in water to 11,300 K in CNDAS. Moreover, the emission from hydroxyl radicals and two new luminescent centers related to carboxyl groups are introduced in SL from CNDAS. These important and interesting findings indicate that by adding trace amount of CNDs in water, the effect of SBSL can be significantly modulated, which can provide a macroscopic phenomenon for gaining an insight into the microscopic mechanism of the SL effect.

8.
J Am Soc Mass Spectrom ; 32(6): 1380-1387, 2021 Jun 02.
Artículo en Inglés | MEDLINE | ID: mdl-33956438

RESUMEN

Transmembrane α-helical domains of membrane proteins tend to remain structured in the gas phase, presenting a challenge for efficient electron capture/transfer dissociation during top-down dissociation mass spectrometry (MS) experiments. In this study, we compare results from different dissociation modes on a modern Orbitrap platform applied to a model integral membrane protein containing two transmembrane helices, the c-subunit of the Fo domain of the chloroplast ATP synthase. Using commercially available options, we compare collisionally activated dissociation (CAD) with the related variant higher-energy collisional dissociation (HCD) and with electron transfer dissociation (ETD). HCD performed better than CAD and ETD. A combined method utilizing both ETD and HCD (EThcD) demonstrates significant synergy over HCD or ETD alone, representing a robust option analogous to activated ion electron capture dissociation, whereby an infrared laser was used to heat the protein ion alongside electron bombardment. Ultraviolet photodissociation at 213 nm displays at least three backbone dissociation mechanisms and covered nearly 100% of backbone bonds, suggesting significant potential for this technique.


Asunto(s)
ATPasas de Translocación de Protón de Cloroplastos/química , Espectrometría de Masas/métodos , Proteínas de la Membrana/química , ATPasas de Translocación de Protón de Cloroplastos/aislamiento & purificación , Transporte de Electrón , Espectrometría de Masas/instrumentación , Proteínas de la Membrana/aislamiento & purificación , Procesos Fotoquímicos , Conformación Proteica en Hélice alfa , Rayos Ultravioleta
9.
Nano Lett ; 20(12): 8912-8918, 2020 12 09.
Artículo en Inglés | MEDLINE | ID: mdl-33206534

RESUMEN

Light emission from tunnel junctions are a potential photon source for nanophotonic applications. Surprisingly, the photons emitted can have energies exceeding the energy supplied to the electrons by the bias. Three mechanisms for generating these so-called overbias photons have been proposed, but the relationship between these mechanisms has not been clarified. In this work, we argue that multielectron processes provide the best framework for understanding overbias light emission in tunnel junctions. Experimentally, we demonstrate for the first time that the superlinear dependence of emission on conductance predicted by this theory is robust to the temperature of the tunnel junction, indicating that tunnel junctions are a promising candidate for electrically driven broadband photon sources.

10.
Anal Chim Acta ; 1058: 39-47, 2019 Jun 13.
Artículo en Inglés | MEDLINE | ID: mdl-30851852

RESUMEN

The self-absorption effect due to optically thick property greatly influences the measured line intensities as well as the performance of quantification for laser-induced breakdown spectroscopy (LIBS) especially for calibration-free LIBS which requires proper correction. In this paper, a new self-absorption correction method for Calibration-Free LIBS (CF-LIBS), called blackbody radiation referenced self-absorption correction (BRR-SAC) is proposed. An iterative algorithm was designed to calculate the plasma temperature and normally hard-to-obtain collection efficiency of the optical collection system by directly comparing the measured spectrum with the corresponding theoretical blackbody radiation for self-absorption correction. Compared with generally applied self-absorption correction methods based on the principle of curve of growth, the proposed method has obvious advantages of simpler programming, higher computation efficiency, and its independency of the availability or accuracy of line broadening coefficients. Experiments were conducted on titanium alloy samples. The experimental results showed that the self-absorption was corrected with increased linearity of the Boltzmann plots and the measurement accuracy of the elemental concentration was significantly improved through BRR-SAC. Compared with the traditional CF-LIBS with self-absorption correction, the proposed method also showed better performance. In addition, BRR-SAC provides a simple way to obtain the collection efficiency of the experimental setup, which benefits the plasma diagnostics and quantitative analysis.

11.
Angew Chem Int Ed Engl ; 54(4): 1357-60, 2015 Jan 19.
Artículo en Inglés | MEDLINE | ID: mdl-25475369

RESUMEN

We report the observation of chemical reactions in gas-phase Rh(n)(N2O)m(+) complexes driven by absorption of blackbody radiation. The experiments are performed under collision-free conditions in a Fourier transform ion cyclotron resonance mass spectrometer. Mid-infrared absorption by the molecularly adsorbed N2O moieties promotes a small fraction of the cluster distribution sufficiently to drive the N2O decomposition reaction, leading to the production of cluster oxides and the release of molecular nitrogen. N2O decomposition competes with molecular desorption and the branching ratios for the two processes show marked size effects, reflecting variations in the relative barriers. The rate of decay is shown to scale approximately linearly with the number of infrared chromophores. The experimental findings are interpreted in terms of calculated infrared absorption rates assuming a sudden-death limit.

12.
Adv Mater ; 25(35): 4868-74, 2013 Sep 20.
Artículo en Inglés | MEDLINE | ID: mdl-23696297

RESUMEN

A single nanoplatform integrating laser-induced heat generation by gold nanoparticles and temperature sensing up to 2000 K via (Gd,Yb,Er)2 O3 nanorods is demonstrated, which presents considerable potential for nanoscale photonics and biomedicine. Blackbody emission is ascertained from the temperature increment with AuNP concentration, emission color coordinates as a function of the laser pump power, and Planck's law of blackbody radiation.


Asunto(s)
Erbio/química , Oro/química , Nanopartículas/química , Nanotubos/química , Termómetros , Rayos Láser , Óptica y Fotónica/instrumentación
13.
Photonics Lasers Med ; 4: 255-266, 2012 Nov 01.
Artículo en Inglés | MEDLINE | ID: mdl-23833705

RESUMEN

Far infrared (FIR) radiation (λ = 3-100 µm) is a subdivision of the electromagnetic spectrum that has been investigated for biological effects. The goal of this review is to cover the use of a further sub-division (3- 12 µm) of this waveband, that has been observed in both in vitro and in vivo studies, to stimulate cells and tissue, and is considered a promising treatment modality for certain medical conditions. Technological advances have provided new techniques for delivering FIR radiation to the human body. Specialty lamps and saunas, delivering pure FIR radiation (eliminating completely the near and mid infrared bands), have became safe, effective, and widely used sources to generate therapeutic effects. Fibers impregnated with FIR emitting ceramic nanoparticles and woven into fabrics, are being used as garments and wraps to generate FIR radiation, and attain health benefits from its effects.

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