RESUMEN
We examined the distribution characteristics of atmospheric microplastics in typical desert agricultural regions, with a focus on the agricultural areas surrounding the Taklamakan Desert, Xinjiang, China. We collected samples of total suspended particulate matter (TSP), atmospheric deposition, and atmospheric dust using both active and passive collection methods. The chemical composition, particle size, shape, and color of atmospheric microplastics were examined using a stereomicroscope and a Fourier-transform infrared spectrometer to analyze their characteristics. The results showed that the primary chemical compositions of microplastics included polypropylene (PP), polyethylene, polyethylene terephthalate, polymethylmethacrylate, and cellophane. Particle sizes were mainly within the range of 0 to 1000 µm. Fibrous microplastics constituted the majority of the TSP and atmospheric deposition, whereas film-like microplastics constituted the largest proportion of atmospheric dustfall. The deposition flux of atmospheric microplastics in the first quarter was measured at 103.21 ± 22.12 particles/m2/day, which was lower than that observed in conventional agricultural areas. The abundance of microplastics in atmospheric dustfall was found to be 1.36 particles/g. The proportion of PP microplastics in atmospheric dustfall can be as high as 35%. Through a comparison of microplastic content in TSP during dust storms and under normal weather conditions, it was found that dust storms can lead to an increase in the abundance of microplastics within the atmospheric TSP. The present study provides a scientific basis for understanding the distribution of atmospheric microplastics in typical desert agricultural regions. Environ Toxicol Chem 2024;43:1982-1995. © 2024 SETAC.
Asunto(s)
Agricultura , Contaminantes Atmosféricos , Clima Desértico , Monitoreo del Ambiente , Microplásticos , Microplásticos/análisis , China , Contaminantes Atmosféricos/análisis , Atmósfera/química , Tamaño de la Partícula , Polvo/análisis , Material Particulado/análisisRESUMEN
The main objective of this study was to determine the presence of Fusarium metabolites in maize samples collected from different regions of Northern Serbia (Backa, Banat and Srem) during a period of two years (2016-2017). A total of 458 maize samples were analysed by liquid chromatography-tandem mass spectrometry. A total of 40 metabolites were detected, where 94% of the samples contained at least 5 metabolites. Fumonisins (including B1, B2, B3 and B4), moniliformin and bikaverin were the most frequent (80-98%) Fusarium metabolites in both years. Furthermore, in samples from 2016, fumonisin A1 and A2, deoxynivalenol, deoxynivalenol-3-glucoside, zearalenone, culmorin, 15-hydroxyculmorin, fusapyron, fusaproliferin and aurofusarin were detected with frequencies of 58-80%. Levels of certain Fusarium metabolites in 2016 were higher on average due to increased humidity when compared to 2017, which was characterised by warm and dry conditions.
Asunto(s)
Fumonisinas , Fusarium , Micotoxinas , Contaminación de Alimentos/análisis , Micotoxinas/análisis , Serbia , Zea maysRESUMEN
The aim of the current study was to track the composition, spatial and temporal distribution charactistics of triazine herbicides in arable soils and corns in typical agricultural regions of Liaoning Province, China. All samples were analyzed using high performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS). Twelve kinds of triazine herbicides were found including atrazine, simazine, prometryn, propazine, ametryn, metribuzin, simetryn, aziprotryne, cyanizine, atrazine-desethyl, atrazine-desisopropyl and atrazine-desethyl-desisopropyl in the soil samples, of which atrazine, simazine, prometryn, atrazine-desethyl and atrazine-desethyl-desisopropyl were proved to be the predominant species with a high incidence though relatively low contamination level. The maximum concentration of atrazine in the soils was 73.80 µg·kg-1. Five kinds of triazine herbicides were found in corns in the region including atrazine, simazine, prometryn, atrazine-desethyl and atrazine-desethyl-desisopropyl with the detection rate 96.4%, 17.8%, 14.3%, 60.7% and 46.4%, respectively. The maximum contaminant level of atrazine in corns was 12.52 µg·kg-1, which is lower than that regulated in the National Standard of the People's Republic of China (GB2763-2012).
Asunto(s)
Herbicidas/análisis , Triazinas/análisis , Atrazina/análisis , China , Cromatografía Líquida de Alta Presión/métodos , Simazina , Suelo , Espectrometría de Masas en Tándem/métodosRESUMEN
The presence of mycotoxins in cereal grain is a very important food safety issue with the occurrence of masked mycotoxins extensively investigated in recent years. This study investigated the variation of different Fusarium metabolites (including the related regulated, masked, and emerging mycotoxin) in maize from various agriculture regions of South Africa. The relationship between the maize producing regions, the maize type, as well as the mycotoxins was established. A total of 123 maize samples was analyzed by a LC-MS/MS multi-mycotoxin method. The results revealed that all maize types exhibited a mixture of free, masked, and emerging mycotoxins contamination across the regions with an average of 5 and up to 24 out of 42 investigated Fusarium mycotoxins, including 1 to 3 masked forms at the same time. Data obtained show that fumonisin B1, B2, B3, B4, and A1 were the most prevalent mycotoxins and had maximum contamination levels of 8908, 3383, 990, 1014, and 51.5 µg/kg, respectively. Deoxynivalenol occurred in 50% of the samples with a mean concentration of 152 µg/kg (max 1380 µg/kg). Thirty-three percent of the samples were contaminated with zearalenone at a mean concentration of 13.6 µg/kg (max 146 µg/kg). Of the masked mycotoxins, DON-3-glucoside occurred at a high incidence level of 53%. Among emerging toxins, moniliformin, fusarinolic acid, and beauvericin showed high occurrences at 98%, 98%, and 83%, and had maximum contamination levels of 1130, 3422, and 142 µg/kg, respectively. Significant differences in the contamination pattern were observed between the agricultural regions and maize types.
Asunto(s)
Fusarium , Micotoxinas/análisis , Zea mays/química , Agricultura , Monitoreo del Ambiente , Fusarium/metabolismo , SudáfricaRESUMEN
Soil heavy metal pollution has been becoming serious and widespread in China. To date, there are few studies assessing the nationwide soil heavy metal pollution induced by industrial and agricultural activities in China. This review obtained heavy metal concentrations in soils of 402 industrial sites and 1041 agricultural sites in China throughout the document retrieval. Based on the database, this review assessed soil heavy metal concentration and estimated the ecological and health risks on a national scale. The results revealed that heavy metal pollution and associated risks posed by cadmium (Cd), lead (Pb) and arsenic (As) are more serious. Besides, heavy metal pollution and associated risks in industrial regions are severer than those in agricultural regions, meanwhile, those in southeast China are severer than those in northwest China. It is worth noting that children are more likely to be affected by heavy metal pollution than adults. Based on the assessment results, Cd, Pb and As are determined as the priority control heavy metals; mining areas are the priority control areas compared to other areas in industrial regions; food crop plantations are the priority control areas in agricultural regions; and children are determined as the priority protection population group. This paper provides a comprehensive ecological and health risk assessment on the heavy metals in soils in Chinese industrial and agricultural regions and thus provides insights for the policymakers regarding exposure reduction and management.