RESUMEN

In 2013, California revised its upholstered furniture flammability standard TB 117-2013 to improve fire safety without the need for flame retardant (FR) chemicals. Subsequent legislation (SB 1019) required disclosure of FR content. In 2020 California expanded restriction on FR chemicals to include juvenile products and upholstered furniture (AB 2998). To monitor trends in FR use, and assess the effectiveness of the new regulations, we analyzed 346 samples from upholstered furniture (n = 270) and children's consumer products (n = 76), collected pre- and post-regulatory intervention for added FR chemicals (i.e., ∑FR > 1000 mg/kg). Upholstered furniture samples, collected from products before enactment of the new regulations, had a median FR concentration of 41,600 mg/kg (range: 1360-92,900 mg/kg), with 100% of the foam samples and 13.7% of the textile samples containing ∑FR > 1000 mg/kg. Firemaster formulations (FM 550 and FM 600), a mixture of triphenyl phosphate (TPHP), 2-ethylhexyl-2,3,4,5-tetrabromobenzoate (EH-TBB), bis(2-ethylhexyl)-3,4,5,6-tetrabromophthalate (BEH-TEBP) and a mixture of isopropyl- or tert-butyl-triphenyl phosphates (ITPs or TBPPs), were the most frequently detected FR (34%), followed by tris(1,3-dichloroisopropyl) phosphate (TDCIPP; 25%), TPHP with a mixture of polybrominated diphenyl ethers (BDE-47, 99, 100, 153 and 154; 20%) and tris(2-chloroethyl) phosphate (TCEP; 11%). Upholstered furniture components collected after enactment of the new legislation had a median FR concentration of 2600 mg/kg (range: 1160-49,800 mg/kg, outlier sample 282,200 mg/kg), with 11.9% of the foam samples and no textile samples containing ∑FR > 1000 mg/kg. Of these samples, tris(1-chloro-2-propyl) phosphate (TCIPP) was the most frequently detected FR (55%), followed by TDCIPP (30%) and Firemaster (FM 550, 15%). No PBDEs were detected in the post-regulatory intervention products. Our initial work on children's products showed 15% of the samples contained ∑FR > 1000 mg/kg. In our post- AB 2998 work, no regulated children's product components failed compliance (i.e., ∑FR > 1000 mg/kg). The data confirm successful adoption of the new regulations with most samples in compliance, demonstrating the efficacy of regulatory intervention. Given these results, environmental FR exposure is expected to decrease as older FR treated consumer products are replaced with FR free products.

Asunto(s)

Retardadores de Llama , Niño , Humanos , Retardadores de Llama/análisis , Diseño Interior y Mobiliario , Polvo/análisis , Organofosfatos/análisis , Fosfatos/análisis , Éteres Difenilos Halogenados/análisis , California , Monitoreo del Ambiente/métodos

RESUMEN

There exists a variety of specialized fire dynamics routines, zone fire models, and field fire models. Many of these heuristics and correlations rely on experimental data from fires fueled by gas burners or liquid pool fires and have had minimal, if any, validation against data from fires with solid, more complex fuels, such as upholstered furniture. One hundred and twenty fire experiments were conducted inside a compartment that contained a single ventilation opening in the form of a doorway that was either open or closed for the entirety of each experiment. The fires were fueled by natural gas burners and upholstered furniture items. The compartment was instrumented throughout with thermocouples, oxygen sampling probes, heat flux gauges (total and radiative), pressure transducers, and bi-directional probes. Additionally, heat release rate data were collected during open door experiments with fires larger than 100 kW. This experimental series was designed to better quantify the repeatability of and differences between natural gas burner and upholstered furniture fuels and to provide new validation cases for the fire modeling community.

RESUMEN

This paper presents an approach to the design of an upholstered furniture frame using the finite element method and empirical studies. Three-dimensional discrete models of upholstered furniture frames were developed taking into account orthotropic properties of solid pine wood (Pinus sylvestris L.) without and with details strengthening their structure in the form of glue joints and upholstery staples. Using the CAE Autodesk Inventor Nastran finite element method, linear static analyses were performed by simulating normative loading. The finite element method was performed considering the experimentally determined stiffness coefficients of the PCAC adhesive and staple joints. As a result, stress, displacement, and equivalent strain distributions were obtained for upholstered furniture frame models with stapled corner joints. The deformation and strength behavior of the upholstered furniture frames was improved by reinforcing with a wood strip. A new approach to the design of upholstered furniture frame frames using the FEM method with stapled component connections was developed and tested. The results of the study can be applied in the optimization of upholstered furniture construction.

RESUMEN

Upholstered furniture is often manufactured with polyurethane foam (PUF) containing flame retardants (FRs) to prevent the risk of a fire and/or to meet flammability regulations, however, exposure to certain FRs and other chemicals have been linked to adverse health effects. This study developed a new methodology for evaluating volatile organic compound (VOC) and FR exposures to users of upholstered furniture by simulating use of a chair in a controlled exposure chamber and assessing the health significance of measured chemical exposure. Chairs with different fire-resistant technologies were evaluated for VOC and FR exposures via inhalation, ingestion, and dermal contact exposure routes. Data show that VOC exposure levels are lower than threshold levels defined by the US and global indoor air criteria. Brominated FRs were not detected from the studied chairs. The organophosphate FRs added to PUF were released into the surrounding air (0.4 ng/m3 ) and as dust (16 ng/m2 ). Exposure modeling showed that adults are exposed to FRs released from upholstered furniture mostly by dermal contact and children are exposed via dermal and ingestion exposure. Children are most susceptible to FR exposure/dose (2 times higher average daily dose than adults) due to their frequent hand to mouth contact.

Asunto(s)

Exposición a Riesgos Ambientales/estadística & datos numéricos , Retardadores de Llama , Diseño Interior y Mobiliario , Contaminación del Aire Interior , Polvo , Monitoreo del Ambiente , Éteres Difenilos Halogenados , Halogenación , Vivienda , Humanos , Organofosfatos , Compuestos Organofosforados , Poliuretanos

RESUMEN

The effectiveness and the failure mechanism of fire barriers in residential upholstered furniture were investigated by full-scale flaming tests on upholstered chair mock-ups. Six commercial fire barriers were tested in this study. Fire barriers were screened for (1) the presence of elements that are typically used in fire retardants and, (2) the presence of targeted fire retardants. For each fire barrier, triplicate flammability tests were run on chair mock-ups where polyurethane foam and polyester fiber fill were used as the padding materials, and each chair component was fully wrapped with the fire barrier of choice and a polypropylene cover fabric. The ignition source was an 18 kW square propane burner, impinging on the top surface of the seat cushion for 80 s. Results showed all six fire barriers reduced the peak heat release rate (as much as ≈ 64 %) and delayed its occurrence (up to ≈ 19 min) as compared to the control chair mock-ups. The heat release rate remained at a relatively low plateau level until liquid products (generated by either melting or pyrolysis of the padding material) percolated through the fire barrier at the bottom of the seat cushion and ignited, while the fire barrier was presumably intact. The flaming liquid products dripped and quickly formed a pool fire under the chair and the peak heat release rate occurred shortly thereafter. Ultimately, the ignition of the percolating liquid products at the bottom of the seat cushion was identified as the mechanism triggering the failure of the fire barrier.

RESUMEN

Flame retardants (FRs) are widely incorporated in polyurethane foams to decrease their fire reaction. Currently, the risks associated with the use of FRs in domestic upholstered furniture (UF) are evaluated according to FRs volatility and potency to be emitted into the atmosphere. However, exposure via contact and dermal penetration, mediated by sweat, has not been considered so far. Our study provides an identification of the latest-generation of FRs most commonly used in UF, and an evaluation of their potency to migrate into artificial sweat. First of all, an extensive literature search, along with surveys with professionals, led to the identification of twenty-two FRs and synergists commonly used in France and Europe. Then, migration into artificial sweat of various FRs embedded into synthetic or commercially available polymer matrix was studied and evidenced. These results were analysed in the light of their potential effects on human health and the environment. Based on the migration's data, it is not possible to clearly rule out potential effects of FRs on human and environment health. Therefore, the authors consider that the use of FRs in domestic upholstery does not seem to be justified due to potential risks and a lack of clear benefits.

RESUMEN

The purpose of this paper was to highlight potential exposure in indoor air to phosphorus flame retardants (PFRs) due to their use in upholstered furniture. For that, an analytical method of PFRs by headspace coupled to solid-phase micro-extraction (HS-SPME) was developed on cushioning foams in order to determine the PFRs' volatile fraction in the material. Tests on model foams proved the feasibility of the method. The average repeatability (RSD) is 6.3 % and the limits of detection range from 0.33 to 1.29 µg g(-1) of foam, depending on the PFRs. Results showed that some PFRs can actually be emitted in air, leading to a potential risk of exposure by inhalation. The volatile fraction can be high (up to 98 % of the total PFRs amount) and depends on the physicochemical properties of flame retardants, on the textural characteristics of the materials and on the temperature. The methodology developed for cushioning foams could be further applied to other types of materials and can be used to rate them according to their potential releases of phosphorus flame retardants.

Asunto(s)

Contaminantes Atmosféricos/análisis , Retardadores de Llama/análisis , Diseño Interior y Mobiliario , Compuestos Organofosforados/análisis , Monitoreo del Ambiente , Sistema Respiratorio , Microextracción en Fase Sólida , Volatilización

RESUMEN

The main objective of the work reported here is to assess factors that could affect the outcome of a proposed open flame test for barrier fabrics (BF-open flame test). The BF-open flame test characterizes barrier effectiveness by monitoring the ignition of a flexible polyurethane foam (FPUF) layer placed in contact with the upper side of the barrier fabric, exposed to a burner flame from below. Particular attention is given to the factors that influence the ignitibility of the FPUF, including thermal resistance, permeability, and structural integrity of the barrier fabrics (BFs). A number of barrier fabrics, displaying a wide range of the properties, are tested with the BF-open flame test. Visual observations of the FPUF burning behavior and BF char patterns, in addition to heat flux measurements on the unexposed side of the barrier fabrics, are used to assess the protective performance of the BF specimen under the open flame test conditions. The temperature and heat transfer measurements on the unexposed side of the BF and subsequent ranking of BFs for their thermal protective performance suggest that the BF-open flame test does not differentiate barrier fabrics based on their heat transfer properties. A similar conclusion is reached with regard to BF permeability characterized at room temperature. However, the outcome of this BF-open flame test is found to be heavily influenced by the structural integrity of thermally degraded BF. The BF-open flame test, in its current form, only ignited FPUF when structural failure of the barrier was observed.

RESUMEN

The effect of a mandated consumer product safety standard on the net public benefit is expressed in terms of the difference between two well characterized market states (pre- and post-standard), each of which is assumed to be in static equilibrium. The analysis is facilitated by treating the post-standard state as one which can be "derived" from the pre-standard state by 1) expanding the production cost and demand functions around their initial market values and 2) introducing modifications in the production cost function required for compliance with the standard. A gain in net benefit would imply that promulgation of the standard is favorable; however, a variety of uncertainties are encountered in estimating the incremental changes in production, demand, compliance, and regulatory costs. These are discussed, some of the simpler situations which may prevail are disclosed, and the sources of expertise required to effect the analysis are identified. The detailed portion of the analysis undertaken in this paper is one which attempts to derive a market factor such that when it is multiplied by the basic increment in manufacturing cost necessary to comply with the standard yields the loss in net benefit due to the market system. The results are then applied to a case involving the manufacturing and retailing of upholstered furniture, which industries may be subject to a certain fire prevention standard.