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The rapid growth in the use of two dimensional liquid chromatography (2D-LC) applied to the analysis of moderately to highly complex mixtures, has been fueled by continuous improvements in performance and robustness of the instrument components, as well as the ease-of-use of software necessary for controlling the 2D-LC instrument hardware, and analysis of the large data files that result from this type of work. This work has focused on the evaluation of the performance of an online full comprehensive mode (LC×LC), when an active modulation is implemented using a flow splitter pump placed after the 1D effluent. Two different types of splitting pumps were evaluated: a binary ultra-high pressure liquid chromatography (UHPLC) pump and a high precision syringe pump. We analyzed the performance (reproducibility in peak area and retention times and the 2D peak dispersion) as a function of the location of the active pump Before or After the modulation valve, and the influence of connecting tubes (based on internal diameter and length) necessary between the interface, waste, and the splitting pump. The effect on the flow direction on the filling and flushing of the injection loops at the modulation valve was also analyzed for each pump. In this study, we demonstrate that flow-splitting LCxLC assembly can be performed using either a UHPLC binary pump or a simple syringe pump. Flow splitting after the first dimension is a straightforward strategy to: (i) independently select the 1D column and flow rates with respect to the second dimension; (ii) consciously dilute the eluate according to the solvent characteristics of the second dimension, thereby avoiding 2D peak distortions; and (iii) adapt the injected amount to the second column according to the relative concentration of the components in a complex sample. However, careful consideration of the system setup is necessary. It is demonstrated how experimental results can be significantly affected in terms of peak broadening and reproducibility if optimization of the interface is not taken into account. In addition, under the optimized conditions, the reproducibility in peak area and dispersion in the 2D dimension were evaluated as a function of the amount of sample transferred in terms of percentage of filled loop.

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For the polarization multiplexing requirements in all-optical networks, this work presents a compact all-fiber polarization beam splitter (PBS) based on dual-core photonic crystal fiber (PCF) and an elliptical gold layer. Numerical analysis using the finite element method (FEM) demonstrates that the mode modulation effect of the central gold layer effectively reduces the dimensions of the proposed PBS. By determining reasonable structural parameters of the proposed PCF, the coupling length ratio (CLR) between X- and Y-polarized super-modes can approach 2, achieving a minimal device length of 0.122 mm. The PBS exhibits a maximum extinction ratio (ER) of - 65 dB at 1.55 µm, with an operating bandwidth spanning 100 nm (1.5-1.6 µm) and a stable insertion loss (IL) of ~ 1.5 dB at 1.55 µm. Furthermore, the manufacture feasibility and performance verification scheme are also investigated. It is widely anticipated that the designed PBS will play a crucial role in the ongoing development process of miniaturization and integration of photonic devices.

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Visible light communication (VLC) is becoming more relevant due to the accelerated advancement of optical fibers. Polymer optical fiber (POF) technology appears to be a solution to the growing demand for improved transmission efficiency and high-speed data rates in the visible light range. However, the VLC system requires efficient splitters with low power losses to expand the optical energy capability and boost system performance. To solve this issue, we propose an effective 1 × 8 optical splitter based on multicore polycarbonate (PC) POF technology suitable for functioning in the green-light spectrum at a 530 nm wavelength. The new design is based on replacing 23 air-hole layers with PC layers over the fiber length, while each PC layer length is suitable for the light coupling of the operating wavelength, which allows us to set the right size of each PC layer between the closer PC cores. To achieve the best result, the key geometrical parameters were optimized through RSoft Photonics CAD suite software that utilized the beam propagation method (BPM) and analysis using MATLAB script codes for finding the tolerance ranges that can support device fabrication. The results show that after a light propagation of 2 mm, an equally green light at a 530 nm wavelength is divided into eight channels with very low power losses of 0.18 dB. Additionally, the splitter demonstrates a large bandwidth of 25 nm and stability with a tolerance range of ±8 nm around the operated wavelength, ensuring robust performance even under laser drift conditions. Furthermore, the splitter can function with 80% and above of the input signal power around the operated wavelength, indicating high efficiency. Therefore, the proposed device has a great potential to boost sensing detection applications, such as Raman spectroscopic and bioengineering applications, using the green light.

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As we know, valley-Hall kink states or pseudospin helical edge states are excited by polarized-momentum-locking [left-handed circular polarization (LCP) and right-handed circular polarization (RCP)] because the valley-Hall kink modes or pseudospin polarized modes have intrinsic and local chirality, which is difficult for these states to achieve phase modulation. Here we theoretically design and study a compatible topological photonic system with coexistence of photonic quantum Hall phase and pseudospin Hall phase, which is composed of gyromagnetic photonic crystals with a deformed honeycomb lattice containing six cylinders. A typical kind of hybrid topological waveguide states with pseudospin-characteristic, magnetic field-dependent, and strong robustness against backscattering and perfect electric conductor (PEC) is realized in the present system. Furthermore, we re-design a structure with intersection-liked, achieve splitting for one-way pseudospin quantum Hall edge states by using phase modulation. Robustness of the one-way pseudospin-quantum Hall edge states in splitting has been demonstrated as well. Additionally, PEC inserted in transport channel brings optical path difference in waveguide transmission, which would influence splitting for hybrid topological waveguide states in phase difference modulation. This work not only provides a new way for manipulation (i.e., phase modulation) of hybrid topological waveguide states in compatible topological photonic system from distinct topological classes but also has potential in various applications, such as sensing, signal processing, and on-chip communications.

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An optical-chemical sensor based on two modified plastic optical fibers (POFs) and a molecularly imprinted polymer (MIP) is realized and tested for the detection of 2-furaldehyde (2-FAL). The 2-FAL measurement is a scientific topic of great interest in different application fields, such as human health and life status monitoring in power transformers. The proposed sensor is realized by using two POFs as segmented waveguides (SW) coupled through a micro-trench milled between the fibers and then filled with a specific MIP for the 2-FAL detection. The experimental results show that the developed intensity-based sensor system is highly selective and sensitive to 2-FAL detection in aqueous solutions, with a limit of detection of about 0.04 mg L-1. The proposed sensing approach is simple and low-cost, and it shows performance comparable to that of plasmonic MIP-based sensors present in the literature for 2-FAL detection.

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We present a new high-efficiency splitter waveguide design based on photonic topological insulators. The system's robust edge states allow electromagnetic waves to propagate in the 2D waveguide without backscattering, resulting in almost 100% transmission in the outputs. We also study resonating modes in the structure and show that introducing specific defects can create such modes. We consider four domains with rods of varying magneto-optical properties to provide edge modes in the system. By eliminating rows and columns of rods, we calculate the transmission at the outputs, revealing resonating modes in the middle of the structure with spatial symmetry. Our calculations indicate that the most promising resonating mode occurs when two rods and two columns are eliminated, with a quality factor Q = 1.02 × 106 at frequency f = 8.23 GHz and almost zero transmission at this frequency to the outputs. We further confirm our results using the transmission line resonator model as a semi-analytical model, which agrees well with our findings.

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Experience replay is a powerful mechanism to learn efficiently from limited experience. Despite several decades of compelling experimental results, the factors that determine which experiences are selected for replay remain unclear. A particular challenge for current theories is that on tasks that feature unbalanced experience, rats paradoxically replay the less-experienced trajectory. To understand why, we simulated a feedforward neural network with two regimes: rich learning (structured representations tailored to task demands) and lazy learning (unstructured, task-agnostic representations). Rich, but not lazy, representations degraded following unbalanced experience, an effect that could be reversed with paradoxical replay. To test if this computational principle can account for the experimental data, we examined the relationship between paradoxical replay and learned task representations in the rat hippocampus. Strikingly, we found a strong association between the richness of learned task representations and the paradoxicality of replay. Taken together, these results suggest that paradoxical replay specifically serves to protect rich representations from the destructive effects of unbalanced experience, and more generally demonstrate a novel interaction between the nature of task representations and the function of replay in artificial and biological systems.

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Integration of functional materials and structures on the tips of optical fibers has enabled various applications in micro-optics, such as sensing, imaging, and optical trapping. Direct laser writing is a 3D printing technology that holds promise for fabricating advanced micro-optical structures on fiber tips. To date, material selection has been limited to organic polymer-based photoresists because existing methods for 3D direct laser writing of inorganic materials involve high-temperature processing that is not compatible with optical fibers. However, organic polymers do not feature stability and transparency comparable to those of inorganic glasses. Herein, we demonstrate 3D direct laser writing of inorganic glass with a subwavelength resolution on optical fiber tips. We show two distinct printing modes that enable the printing of solid silica glass structures ("Uniform Mode") and self-organized subwavelength gratings ("Nanograting Mode"), respectively. We illustrate the utility of our approach by printing two functional devices: (1) a refractive index sensor that can measure the indices of binary mixtures of acetone and methanol at near-infrared wavelengths and (2) a compact polarization beam splitter for polarization control and beam steering in an all-in-fiber system. By combining the superior material properties of glass with the plug-and-play nature of optical fibers, this approach enables promising applications in fields such as fiber sensing, optical microelectromechanical systems (MEMS), and quantum photonics.

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Hippocampal principal neurons display both spatial tuning properties and memory features. Whether this distinction corresponds to separate neuron types or a context-dependent continuum has been debated. We report here that the task-context ("splitter") feature is highly variable along both trial and spatial position axes. Neurons acquire or lose splitter features across trials even when place field features remain unaltered. Multiple place fields of the same neuron can individually encode both past or future run trajectories, implying that splitter fields are under the control of assembly activity. Place fields can be differentiated into subfields by the behavioral choice of the animal, and splitting within subfields evolves across trials. Interneurons also differentiate choices by integrating inputs from pyramidal cells. Finally, bilateral optogenetic inactivation of the medial entorhinal cortex reversibly decreases the fraction of splitter fields. Our findings suggest that place or splitter features are different manifestations of the same hippocampal computation.

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Methane gas concentration detection faces the challenges of increasing accuracy and sensitivity, as well as high reliability in harsh environments. The special design of the optical path structure of the sensitive element provides an opportunity to improve methane gas concentration detection. In this study, the optical path structure of the sensitive element was newly designed based on the Pyramidal beam splitter matrix. The infrared light source was modulated by multi-frequency point-signal superimposed modulation technology. At the same time, concentration detection results and confidence levels were calculated using the four-channel methane gas concentration detection algorithm based on spectral refinement. Through the experiment, it was found that the sensor enables the full-range measurement of CH4; at the lower explosive limit (LEL, CH4 LEL of 5%), the reliability level is 0.01 parts-per-million (PPM), and the limit of detection is 0.5 ppm. The sensor is still capable of achieving PPM-level detections under extreme conditions in which the sensor's optical window is covered by two-thirds and humidity is 85% or dust concentration is 100 mg/m3. Those improve the sensitivity, robustness, reliability, and accuracy of the sensor.

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With the high number of microplastic-like particles captured by net hauls including manta or neuston nets, it is often required to subsample in order to decrease sample volume for microplastic enumeration and analysis. Plankton splitter is commonly used to divide microplastic samples. However, current devices such as Folsom plankton splitter and Motoda box splitter have accuracy issues in separating highly buoyant microplastics, namely expanded polystyrene (EPS) as they tend to adhere to the inner walls. Inspired by an apple cutter, we have developed a simple radial splitter made of stainless steel that efficiently divides EPS microplastic samples into precise aliquots. With this simple device, we uniformly divided EPS microplastic samples from marine environments into eight aliquots with no significant differences. The device is a versatile tool to partition all buoyant microplastics including polypropylene and polyethylene microplastics.•The method developed facilitates the precise division of buoyant microplastics into equal aliquots.•The method is specifically effective in splitting expanded polystyrene particles with high buoyancy.

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We report a novel 2 × 2 broadband 3 dB coupler based on fast adiabatic mode evolution with a compact footprint and large bandwidth. The working principle of the coupler is based on the rapid adiabatic evolution of local eigenmodes of fishbone-like grating waveguides. Different from a traditional adiabatic coupling method realized by the slow change of the cross-section size of a strip waveguide, a fishbone waveguide allows faster adiabatic transition with proper structure and segment designs. The presented 3 dB coupler achieves a bandwidth range of 168 nm with an imbalance of no greater than ±0.1 dB only for a 9 µm coupling region which significantly improves existing adiabatic broadband couplers.

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The on-chip nano-integration of large-scale optical phased arrays (OPAs) is a development trend. However, the current scale of integrated OPAs is not large because of the limitations imposed by the lateral dimensions of beam-splitting structures. Here, we propose an ultra-compact and broadband OPA beam-splitting scheme with a nano-inverse design. We employed a staged design to obtain a T-branch with a wavelength bandwidth of 500 nm (1300-1800 nm) and an insertion loss of -0.2 dB. Owing to the high scalability and width-preserving characteristics, the cascaded T-branch configuration can significantly reduce the lateral dimensions of an OPA, offering a potential solution for the on-chip integration of a large-scale OPA. Based on three-dimensional finite-difference time-domain (3D FDTD) simulations, we demonstrated a 1 × 16 OPA beam-splitter structure composed entirely of inverse-designed elements with a lateral dimension of only 27.3 µm. Additionally, based on the constructed grating couplers, we simulated the range of the diffraction angle θ for the OPA, which varied by 0.6°-41.6° within the wavelength range of 1370-1600 nm.

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Metasurfaces, composed of micro-nano-structured planar materials, offer highly tunable control over incident light and find significant applications in imaging, navigation, and sensing. However, highly efficient polarization devices are scarce for the extended shortwave infrared (ESWIR) range (1.7~2.5 µm). This paper proposes and demonstrates a highly efficient all-dielectric diatomic metasurface composed of single-crystalline Si nanocylinders and nanocubes on SiO2. This metasurface can serve as a nanoscale linear polarizer for generating polarization-angle-controllable linearly polarized light. At the wavelength of 2172 nm, the maximum transmission efficiency, extinction ratio, and linear polarization degree can reach 93.43%, 45.06 dB, and 0.9973, respectively. Moreover, a nonpolarizing beam splitter (NPBS) was designed and deduced theoretically based on this polarizer, which can achieve a splitting angle of ±13.18° and a phase difference of π. This beam splitter can be equivalently represented as an integration of a linear polarizer with controllable polarization angles and an NPBS with one-bit phase modulation. It is envisaged that through further design optimization, the phase tuning range of the metasurface can be expanded, allowing for the extension of the operational wavelength into the mid-wave infrared range, and the splitting angle is adjustable. Moreover, it can be utilized for integrated polarization detectors and be a potential application for optical digital encoding metasurfaces.

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We put forward and demonstrate a silicon photonics (SiPh)-based mode division multiplexed (MDM) optical power splitter that supports transverse-electric (TE) single-mode, dual-mode, and triple-mode (i.e., TE0, TE1, and TE2). An optical power splitter is needed for optical signal distribution and routing in optical interconnects. However, a traditional optical splitter only divides the power of the input optical signal. This means the same data information is received at all the output ports of the optical splitter. The powers at different output ports may change depending on the splitting ratio of the optical splitter. The main contributions of our proposed optical splitter are: (i) Different data information is received at different output ports of the optical splitter via the utilization of NOMA. By adjusting the power ratios of different channels in the digital domain (i.e., via software control) at the Tx, different channel data information can be received at different output ports of the splitter. It can increase the flexibility of optical signal distribution and routing. (ii) Besides, the proposed optical splitter can support the fundamental TE0 mode and the higher modes TE1, TE2, etc. Supporting mode-division multiplexing and multi-mode operation are important for future optical interconnects since the number of port counts is limited by the chip size. This can significantly increase the capacity besides wavelength division multiplexing (WDM) and spatial division multiplexing (SDM). The integrated SiPh MDM optical power splitter consists of a mode up-conversion section implemented by asymmetric directional couplers (ADCs) and a Y-branch structure for MDM power distribution. Here, we also propose and discuss the use of the Genetic algorithm (GA) for the MDM optical power splitter parameter optimization. Finally, to provide adjustable data rates at different output ports after the MDM optical power splitter, non-orthogonal multiple access-orthogonal frequency division multiplexing (NOMA-OFDM) is also employed. Experimental results validate that, in three modes (TE0, TE1, and TE2), user-1 and user-2 achieve data rates of (user-1: greater than 22 Gbit/s; user-2: greater than 12 Gbit/s) and (user-1: greater than 12 Gbit/s; user-2: 24 Gbit/s), respectively, at power-ratio (PR) = 2.0 or 3.0. Each channel meets the hard-decision forward-error-correction (HD-FEC, i.e., BER = 3.8 × 10-3) threshold. The proposed method allows flexible data rate allocation for multiple users for optical interconnects and system-on-chip networks.

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This paper presents a new design for a 1 × 4 optical power splitter using multimode interference (MMI) coupler in silicon nitride (Si3N4) strip waveguide structures. The main functionality of the proposed design is to use Si3N4 for dealing with the back reflection (BR) effect that usually happens in silicon (Si) MMI devices due to the self-imaging effect and the higher index contrast between Si and silicon dioxide (SiO2). The optimal device parameters were determined through numerical optimizations using the beam propagation method (BPM) and finite difference time domain (FDTD). Results demonstrate that the power splitter with a length of 34.6 µm can reach equal distribution power in each output port up to 24.3% of the total power across the O-band spectrum with 0.13 dB insertion loss and good tolerance MMI coupler parameters with a shift of ±250 nm. Additionally, the back reflection range over the O-band was found to be 40.25-42.44 dB. This demonstrates the effectiveness of the incorporation using Si3N4 MMI and adiabatic input and output tapers in mitigating unwanted BR to ensure that a good signal is received from the laser. This design showcases the significant potential for data-center networks, offering a promising solution for efficient signal distribution and facilitating high-performance and reliable optical signal routing within the O-band range. By leveraging the advantages of Si3N4 and the MMI coupler, this design opens possibilities for advanced optical network architectures and enables efficient transmission of optical signals in the O-band range.

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The utilization of nanofluids and concentrating techniques in solar photovoltaic/thermal (PV/T) systems, to enhance the overall system performance, have been analysed explicitly in the last few years. More recently, nanofluid-based optical filters were integrated with photovoltaic (PV) systems for the effective utilization of solar spectrum, i.e. below and beyond the band-gap of PV cells. Therefore, to quantify the recent progress of spectral beam splitting-based hybrid PV/T systems (BSPV/T), a systematic review has been presented therein. The study highlights the technological and scientific advancement in BSPV/T in last two decades. Linear Fresnel mirror-based BSPV/T showed significant enhancement in the overall performance of hybrid PV/T system. Recently developed nanoparticle-laden BSPV/T system shows significant improvement in overall thermal efficiency of BSPV/T system, thanks to decoupling of thermal system and PV cell. Further, economic analysis, carbon footprint, and environmental assessment of BSPV/T are also discussed briefly. At the last, the authors have made an effort to identify the challenges, limitations, and prospective paths for future research in BSPV/T systems.

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A two-dimensional numerical simulation is performed to investigate the drag reduction and vortex shedding suppression behind three square cylinders with attached splitter plates in the downstream region at a low Reynolds number (Re = 150). Numerical calculations are carried out using the lattice Boltzmann method. The study is carried out for various values of gap spacing between the cylinders and different splitter plate lengths. The vortices are completely chaotic at very small spacing, as observed. The splitter plates are critical in suppressing shedding and reducing drag on the objects. The splitter plates with lengths greater than two fully control the jet interaction at low spacing values. There is maximum percentage reduction in CDmean for small spacing and the selected largest splitter plate length. Furthermore, systematic investigation reveals that splitter plates significantly suppress the fluctuating lift in addition to drastically reducing the drag.

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In this study, a hardness tester was modified by attaching a metal blade to its testing area to obtain the minimum forces required to subdivide tablets along their diameters (F'). Moreover, the tensile strengths of subdividing tablets (TS') were calculated. Tablets of microcrystalline cellulose (MCC) weighing 0.5 g were produced at applied compression pressures of 21, 31, 41, 50, and 60 MPa. In addition, tablets of Ludipress®, and a 5:2 mixture of paracetamol to MCC weighing 0.7 g were produced at applied compression pressures of 77, 116, 154, 193, and 232 MPa. It was found that F' increased as the applied compression pressure used to produce the tablets increased until a maximum value was reached. This maximum value was at around 100 N for MCC and Ludipress® tablets and at around 76 N for paracetamol/MCC tablets. Moreover, a maximum value of TS' was reached at a porosity of 0.37 for MCC, 0.15 for Ludipress®, and 0.11 for paracetamol/MCC tablets. The maximum TS' values were at around 1.5 MPa for MCC and Ludipress® tablets and at around 0.9 MPa for paracetamol/MCC tablets. Therefore, both inter particulate bonding (tablet strength) and porosity (packing) affected the magnitudes of F' and TS'.

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A multi-functional sensing system based on surface plasmon resonance (SPR) phenomenon using a square glass rod with two gold-deposited adjacent faces was developed in this work. This sensor system consists of a unpolarized light-emitting diode, a gold-deposited square glass rod, a polarizing beam splitter, and two photodiodes. The SPR responses of two adjacent faces are independently and simultaneously measured with a polarizing beam splitter and two PDs. The response property of the gold-deposited face was confirmed using methanol solutions of ethylene glycol. The response curve of the sensor of the 45 nm gold-deposited face was compared with the theoretical curve calculated using multi-layer Fresnel equations. It was confirmed that the experimental curve is similar to the theoretical one. An evaluation was carried out on the square glass rod, which has an unmodified face and Teflon AF2400 coated gold-deposited face as multi-functional sensor. It was confirmed that this sensor can simultaneously measure the ethanol concentration in the glucose mix solution and refractive index of the sample from the calibration curve. Since this sensor can measure multiple components simultaneously, expected applications to various fields include medical diagnosis, food analysis, and environmental monitoring.