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Gold (Au) nanoclusters chemically synthesized on the cell surface of living Lactobacillus rhamnosus rendered them photoluminescent. Importantly, the bacteria were viable and the clusters were passed down the generations with the loss of luminescence in the first subculture onward. The clusters were agglomerated into spherical structures of 100-200 nm, without being converted to plasmonic Au nanoparticles, on the cell surfaces of the bacteria of all six subcultures studied. The results indicated the role of cell wall remodeling in transforming the Au nanoclusters into larger aggregates down the generations. This may hold important implications for using nanoparticle-studded bacteria in theranostics.

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A new type of functional lignin-based spherical particles (L-CTAB) prepared with the use of hexadecyltrimethylammonium bromide (CTAB) was applied as an effective biosorbent for removing vanadium(V) ions. The porous structure, characteristic functional groups, electrokinetic stability, morphology and size of the L-CTAB particles were examined. The conditions of removal were also investigated, including pH (2-12), sorbent mass (0.1-0.5 g), concentration (10-100 mg/dm3), phase contact time (1-240 min) and temperature (293-333 K). At pH 5.0 the maximum sorption percentage (%S) of V(V) was 45%, while at pH 2.0 it was 32%. The maximum sorption capacity of V(V) for L-CTAB was found to be 10.79 mg/g. The kinetic data indicate that the sorption followed the pseudo-second-order and film diffusion models. Sorption equilibrium for V(V) ions removal by L-CTAB was reached after 60 min at the initial concentrations 10 and 50 mg/dm3. It has been shown that the adsorption of V(V) ions on the surface of L-CTAB is a heterogeneous, endothermic and spontaneous reaction, as evidenced by the calculated values of thermodynamic parameters - free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) - for the tested systems at different temperatures. HCl solutions, used as an L-CTAB regeneration agent, quantitatively eluted V(V) ions.

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Nanostructured hematite materials for advanced applications are conventionally prepared with the presence of additives, tainting its purity with remnants of copolymer surfactants, active chelating molecules, stabilizing agents, or co-precipitating salts. Thus, preparing nanostructured hematite via additive-free and green synthesis methods remains a huge hurdle. This study presents an environmentally friendly and facile synthesis of spherical nanostructured hematite (Sp-HNP) using rice starch-assisted synthesis. The physicochemical properties of the Sp-HNP were investigated by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), field emission scanning electron microscopy (FESEM), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DR UV-Vis), and nitrogen adsorption⁻desorption analysis. The Sp-HNP showed a well-crystallized structure of pure rhombohedral phase, having a spherical-shaped morphology from 24 to 48 nm, and a surface area of 20.04 m²/g. Moreover, the Sp-HNP exhibited enhanced photocatalytic degradation of methylene blue dye, owing to the large surface-to-volume ratio. The current work has provided a sustainable synthesis route to produce spherical nanostructured hematite without the use of any hazardous agents or toxic additives, in agreement with the principles of green chemistry for the degradation of dye contaminant.

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The optical properties of alternating ultrathin Ti0.91O2 nanosheets and CdS nanoparticle hybrid spherical structures designed by the layer-by-layer (LBL) assembly technique are investigated. From the photoluminescence (PL) spectral measurements on the hybrid spherical structures, a spectrum-shifted fluorescence emission occurs in this novel hybrid material. The time-resolved PL measurements exhibit a remarkably increased PL lifetime of 3.75 ns compared with only Ti0.91O2 spheres or CdS nanoparticles. The novel results were attributed to the enhanced electron-hole separation due to the new type II indirect optical transition mechanism between Ti0.91O2 and CdS in a charge-separated configuration.

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Considerable research effort has focused on the discovery of mitigators that block the toxicity of the ß-amyloid peptide (Aß) by targeting a specific step involved in Aß fibrillogenesis and subsequent aggregation. Given that aggregation intermediates are hypothesized to be responsible for Aß toxicity, such compounds could likely prevent or mitigate aggregation, or alternatively cause further association of toxic oligomers into larger nontoxic aggregates. Herein we investigate the effect of modifications of the KLVFF hydrophobic core of Aß by replacing N- and C-terminal groups with various polar moieties. Several of these terminal modifications were found to disrupt the formation of amyloid fibrils and in some cases induced the disassembly of preformed fibrils. Significantly, mitigators that incorporate MiniPEG polar groups were found to be effective against Aß(1-40) fibrilligonesis. Previously, we have shown that mitigators incorporating alpha,alpha-disubstituted amino acids (ααAAs) were effective in disrupting fibril formation as well as inducing fibril disassembly. In this work, we further disclose that the number of polar residues (six) and ααAAs (three) in the original mitigator can be reduced without dramatically changing the ability to disrupt Aß(1-40) fibrillization in vitro.

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