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In this study, non-thermal plasma (NTP) was employed to modify the Cu/TiO2 adsorbent to efficiently purify H2S in low-temperature and micro-oxygen environments. The effects of Cu loading amounts and atmospheres of NTP treatment on the adsorption-oxidation performance of the adsorbents were investigated. The NTP modification successfully boosted the H2S removal capacity to varying degrees, and the optimized adsorbent treated by air plasma (Cu/TiO2-Air) attained the best H2S breakthrough capacity of 113.29 mg H2S/gadsorbent, which was almost 5 times higher than that of the adsorbent without NTP modification. Further studies demonstrated that the superior performance of Cu/TiO2-Air was attributed to increased mesoporous volume, more exposure of active sites (CuO) and functional groups (amino groups and hydroxyl groups), enhanced Ti-O-Cu interaction, and the favorable ratio of active oxygen species. Additionally, the X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) results indicated the main reason for the deactivation was the consumption of the active components (CuO) and the agglomeration of reaction products (CuS and SO42-) occupying the active sites on the surface and the inner pores of the adsorbents.

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This study aimed to evaluate effective treatment strategies for laboratory waste with an initial pH of 1.0, containing Cr6+, Mn2+, Co2+, Fe3+, Ni2+, Cu2+, Zn2+, Sr2+, Hg2+, and Pb2+ ions, focusing on flocculation, precipitation, and adsorption techniques. The study utilized microparticles derived from Moringa oleifera seed husks (MS), cryogels of carboxymethyl cellulose (CMC), and hybrid cryogels combining CMC and MS (CMC-MS25 and CMC-MS50) as adsorbents. The optimal strategy involved raising the pH to 7 using NH4OH, leading to the partial precipitation of metal ions. The remaining supernatant was then passed through columns packed with the aforementioned adsorbents. Utilizing CMC-MS25 and CMC-MS50 adsorbents resulted in the simultaneous removal of over 90% of the targeted metal ions. The adsorption of Cu2+ ions onto the adsorbents was facilitated by electrostatic interactions between Cu2+ ions and carboxylate groups, as well as Cu-OH chelation, as confirmed by X-ray photoelectron spectroscopy. Under optimized conditions, the fixed-bed column adsorption capacity was determined as 88.2 mg g-1. The CMC-MS25 adsorbents proved reusable at least 5 times, with the recovered Cu2+ ions potentially suitable for other processes. The scalability and feasibility of producing these novel adsorbents suggest a promising, cost-effective solution for treating complex matrices and recovering high-value metals, as copper.

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Returning carbon materials from biomass to soil is a potential technology to retard organic contaminants or dissolved organic matter (DOM) in soil by adsorption, as well as to store carbon in soil for carbon sequestration. However, DOM was widely reported to inhibit adsorption of organic contaminants on carbon materials by competition and by enhancing contaminants' solubility. In this study, a KOH activated carbon material (KAC), pyrolyzed from bamboo chips, with high surface area (3108 m2/g), micropores volumes (0.964 cm3/g), mesopores volumes (1.284 cm3/g), was observed that it can adsorb fulvic acid (FA) and organic contaminants (e.g., nitrobenzene, phenols, and anilines) simultaneously with weak competition and high adsorption capacity. With 50 mg TOC/L FA, for example, the average competition suppressing rate (ΔKf/Kf-m) of organic contaminants on KAC was lower than 5%, the adsorption for organic contaminants and FA were higher than 1100 mg/g and 90 mg TOC/g, respectively. The weak competition on KAC could be attributed to the low micropore blockage (<35%) and the weak adsorption sites competition on mesopores of KAC, as well as the minimal solubility enhancement of organic contaminants by FA because most FA is adsorbed on KAC but is not dissolved in the solution. In addition, adsorption of organic contaminants with high hydrogen-bonding donor ability (αm) and adsorption affinity was less suppressed by FA because of the heterogeneous nature of hydrophilic sites on KAC's surface. Therefore, KAC could be a potential carbon material to be produced to implement to soil for carbon storage and simultaneous retarding organic contaminants and DOM.

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This research aimed to synthesise an effective hydrochar adsorbent from vineyard pruning wastes to remove emerging contaminants as a potential valorisation product. The adsorption capacity of the hydrochar was optimised using the Taguchi method. Four synthesis variables were evaluated: hydrothermal reaction temperature, use of H3PO4 as a catalyst, number of acetone washes, and type of chemical cold activation. The simultaneous adsorption of five model pesticides (clothianidin (CTD), acetamiprid (ACE), 2,4-D, metalaxyl (MET), and atrazine (ATZ)) at an initial pH of 7 was studied. At optimum conditions, the hydrochar presented a total adsorption capacity of 22.7 µmol/g, representing a 2.7-fold improvement with respect to pristine hydrochar performance. High percentage removals were achieved for all pollutants (85 % CTD, 94 % ACE, 86 % MET, and 95 % ATZ) except for 2,4-D (4 %). This research provides a valuable reference for developing hydrochar adsorbents for pollution control and the valorisation of biomass wastes.

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Casting method was used to synthesize a novel sodium alginate nanohybrid functionalized with aminated ZnO/SiO2 Schiff base for adsorption of nickel (Ni2+) and copper (Cu2+) divalent cations in single and binary water systems. The cast Schiff base nanohybrids were investigated using FESEM, XRD, BET, FTIR, TGA, and XPS analyses. The influence of unfunctionalized binary ZnO/SiO2 nano oxides and aminated Schiff base ligands formed by the reaction between salicylaldehyde and O-phenylenediamine on the adsorption of Ni2+ and Cu2+ cations was evaluated. The results confirmed that the aminated Schiff base ligands led to a higher adsorption ability of the cast nanohybrids containing interaction of divalent cations with nitrogen and oxygen atoms, as well as carboxyl and hydroxyl groups. The adsorption kinetics and isotherm for both cations followed a double-exponential model and the Redlich-Peterson model, respectively. The maximum monolayer capacity was found to be 249.8 mg/g for Cu2+ cation and 96.4 mg/g for Ni2+ cation. Thermodynamic analysis revealed an endothermic and spontaneous adsorption process with an increase in entropy. Furthermore, the synthesized Schiff base adsorbent could be easily reused over five times. The simultaneous adsorption in binary system exhibited a higher adsorption selectivity of the cast Schiff base nanohybrid for Cu2+ cation compared to Ni2+ cation. It was found that the removal percentages of Cu2+ and Ni2+ from industrial electroplating wastewater were 91.3 and 64.5%, respectively. Lastly, cost analysis of the synthesized nanohybrid was investigated.

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With increasing demand for adsorbents highly effective in pollutant removal, carbon-based porous materials are becoming more and more popular. In this work, a new approach to the synthesis of such solids using an environmentally friendly, two-step preparation method is presented. A series of hybrid porous silica-containing carbon composites was synthesized, namely: metal free (C/SiO2), enriched with manganese (C/Mn/SiO2), as well as iron (C/Fe/SiO2). The effect of additives on the structure and morphology of the composites was evaluated using X-ray photoelectron spectroscopy (XPS), nitrogen adsorption/desorption and scanning electron microscope (SEM). The as-synthesized carbons were used as effective adsorbents for the simultaneous removal of heavy metals, including lead (Pb(II)) and zinc (Zn(II)) ions. In particular, it was determined that C/Mn/SiO2 sample demonstrated the highest adsorption capacity towards Pb(II) and Zn(II) ions. It was equal to 211.60 mg/g for Pb(II) and 74.95 mg/g for Zn(II). Zeta potential and surface charge density of the solids, with and without metals, were investigated to determine electrical double layer structure, whereas stability studies and aggregate size measurements were performed to estimate solid aggregation under selected conditions. It was established that solids with adsorbed metals formed suspensions with lower stability than those without ions. This, in turn, facilitates their separation from aqueous solutions.

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Textile and pharmaceutical effluents contain significant amounts of dyes and antibiotics, which pose a serious threat to the ecosystem when discharged directly. Therefore, they should be treated by facile treatment techniques using low-cost materials. Layered double hydroxide (LDH) and its hybrids have emerged as robust and economic adsorbents for water treatment. Herein, magnesium/aluminum LDH and its starch-based composite were synthesized by a co-precipitation technique. The physicochemical features of the developed adsorbents were thoroughly characterized using various analytical tools. The developed materials were tested for the eradication of methylene blue (MB) and amoxicillin (AMX) in batch mode adsorption by varying operating conditions. Adsorption performance depends on the solution's pH. Under optimum adsorption conditions of pH 11, adsorbent dosage of 50 mg/L, and treatment time of 120 min, starch-impregnated MgAl-LDH exhibited maximum MB and AMX adsorption capacities of 114.94 and 48.08 mg/g, respectively. The adsorption mechanism states that hydrogen bonds and weak van der Waals forces are responsible for the removal of pollutants by the developed materials. Moreover, equilibrium and kinetic studies revealed that the removal of dye and antibiotic followed the Freundlich and Langmuir models with the pseudo-second-order reaction kinetics, respectively. The spent adsorbents were regenerated using 0.1 M HCl (for MB) and methanol (for AMX) eluent, and reusability studies ensured that the developed adsorbents retained their performance for up to four consecutive adsorption/desorption cycles. MgAl-LDH and its starch-based hybrid could thus be used to effectively remove organic contaminants from wastewater streams on a commercial scale.

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The development of bifunctional hybrid materials based on natural clays and layered double hydroxide (LDH) and their application on the simultaneous adsorption of Cd(II) and As(V) was investigated in this work. Two different synthesis routes, in situ and assembly, were employed to obtain the hybrid materials. Three types of natural clays, namely bentonite (B), halloysite (H), and sepiolite (S), were used in the study. These clays are characterized by a laminar, tubular, and fibrous structural arrangement, respectively. The physicochemical characterization results indicate that the hybrid materials were formed through interactions between the Al-OH and Si-OH groups present in the natural clays, and the Mg-OH and Al-OH groups present in the LDH for both synthesis routes. However, the "in situ" route yields a more homogenous material because the LDH formation is performed on the natural clay surface. The hybrid materials showed an anion and cation exchange capacity up to 200.7 meq/100 g and an isoelectric point near 7. The arrangement of natural clay has no impact on the properties of hybrid material but influences the adsorption capacity. The adsorption of Cd(II) onto hybrid materials was enhanced in comparison with natural clays, obtaining adsorption capacities of 80, 74, 65, and 30 mg/g for 15:1 (LDH:H)INSITU, 1:1 (LDH:S)INSITU, 1:1 (LDH:B)INSITU, and 1:1 (LDH:H)INSITU, respectively. The adsorption capacities of hybrid materials to adsorb As(V) were between 20 and 60 µg/g. The 15:1 (LDH:H)INSITU sample showed the best adsorption capacity being ten folds greater than halloysite and LDH. In all cases, the hybrid materials showed a synergistic effect for Cd(II) and As(V) adsorption. The adsorption study of Cd(II) onto hybrid materials showed that the primary adsorption mechanism is cation exchange between the interlayer cations in natural clay and Cd(II) in the aqueous solution. The adsorption of As(V) showed that the adsorption mechanism is attributed to anion exchange between CO23- in the interlayer space of LDH and H2ASO4- in the solution. The simultaneous adsorption of As (V) and Cd (II) shows that, during the As(V) adsorption, there is no competition by the adsorption sites. Still, the adsorption capacity towards Cd(II) was enhanced 1.2-folds. This study ultimately revealed that the arrangement of clay has a significant influence on the adsorption capacity of the hybrid material. This can be attributed to the similar morphology between the hybrid material and natural clays, as well as the important diffusion effects observed in the system.

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The treatment of combined antibiotics and heavy metals pollution is a critical challenge. Herein, iron and nitrogen co-doped biochar (Fe/N-BC) was synthesized using rape straw as precursor, and applied for the adsorption of ciprofloxacin (CIP) and Cu2+ in single and binary systems. The qmax for CIP and Cu2+ were 46.45 mg g-1 and 30.77 mg g-1, respectively. Adsorption decreased in a binary matrix, indicating that there was a competitive effect between CIP and Cu2+, which might be due to CIP and Cu2+ sharing similar active adsorption sites on Fe/N-BC. Interestingly, CIP and Cu2+ co-adsorption was a pH-dependent process. Fe/N-BC has potential to highly selectively separate CIP/Cu2+ from mixed solutions through adjusting pH values. Furthermore, adsorption mechanisms were systematically investigated in this research. This research could help to provide a deeper understanding of the synchronously removing specific antibiotics and heavy metals by biochar adsorbents.

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The coexistence of pharmaceuticals and heavy metals is regarded as a serious threat to aquatic environments. Adsorbents have been widely applied to the simultaneous removal of pharmaceuticals and metals from aqueous phase. Through a comprehensive review, behaviors that promote, inhibit, or have no effect on simultaneous adsorption of pharmaceuticals and heavy metals were found to depend on the system of contaminants and adsorbents and their environmental conditions, such as: characteristics of adsorbent and pollutant, temperature, pH, inorganic ions, and natural organic matter. Bridging and competition effects are the main reasons for promoting and inhibiting adsorption in coexisting systems, respectively. The promotion is more significant in neutral or alkaline conditions. After simultaneous adsorption, a solvent elution approach was most commonly used for regeneration of saturated adsorbents. To conclude, this work could help to sort out the theoretical knowledge in this field, and may provide new insights into the prevention and control of pharmaceuticals and heavy metals coexisting in wastewater.

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Industrial wastewater typically contains both cationic and anionic heavy metals; therefore, their simultaneous removal must be considered to ensure environmental sustainability. Herein, nitrogen heteroatom (N) doped hydrochar derived from corncob was prepared via facile NH4Cl-aided hydrothermal carbonization and used for the simultaneous adsorption of divalent copper (Cu(II)) and hexavalent chromium (Cr(VI)) in aqueous solutions. During hydrothermal carbonization, NH4Cl played a vital role as the porogen and N dopant, which contributed to the efficient adsorption affinity toward coexisting Cu(II) and Cr(VI). The theoretical maximum adsorption capacities of the N-doped hydrochar were determined to be 1.223 mmol/g for Cu(II) and 1.995 mmol/g for Cr(VI), which were much better than those of the pristine hydrochar. Furthermore, in the binary-component system, the synergistic effect between Cu(II) and Cr(VI) significantly promoted the adsorption affinity of N-doped hydrochar, resulting in adsorption capacities for Cu(II) and Cr(VI) 9.48 and 1.92 times higher than those of the single-component system, respectively. A series of adsorption experiments and spectroscopic analyses demonstrated that multiple mechanisms, including electrostatic shielding, cation bridging, and redox reactions, mutually contributed to the synergistic effect in the adsorption of coexisting Cu(II) and Cr(VI). Overall, the N-doped hydrochar proved to be effective in simultaneously removing both cationic and anionic heavy metal pollutants.

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Multiple potentially toxic elements (PTEs) often coexist in practical wastewater environment, which poses serious risks to the ecological environment and human health. However, few of the reported adsorbents are capable of simultaneously and effectively removing multiple PTEs from wastewater due to the unique properties of each element. In this work, a multifunctional adsorbent FMHs was developed by optimizing Fe2+/Fe3+/Mn2+/HA ratio, and applied to remove Cd(II), Pb(II), Cu(II), Zn(II), As(III), Sb(III), As(V) and Sb(V) from aqueous solution. Results revealed that the adsorption data obeyed the Elovich, Sips and Redlich-Peterson models in the mono-component system, and the maximum adsorption capacity of FMHs was superior to most adsorbents reported in the literatures. In addition, FMHs retained considerable removal capacity after four cycles, and maintained excellent adsorption performance under the interference of different environmental factors (including pH, ionic strength, co-existing ions and humic acid). In the multi-component system, FMHs also presented high adsorption capacity for all the selected PTEs, especially for Sb(III/V) and Pb(II). Characterization results confirmed that various removal mechanisms, such as precipitation, surface complexation, ion exchange, electrostatic attraction and redox, were responsible for the capture of PTEs by FMHs.

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Lead and cadmium are toxic to human, animal, and plant health; they enhance oxidative stress indirectly while simultaneously acting through other toxicodynamic mechanisms. In this study, pristine vermiculite (VER) was functionalized with butylamine (BUT) and a novel organoclay (BUT-VER) adsorbent material was produced for simultaneous removal of Pb(II) and Cd(II) in aquatic medium. The adsorbents were characterized by spectroscopic, microscopic, spectrometric, and potentiometric techniques. The adsorption affecting parameters, including pH, time, initial concentration, temperature, and co-existing cations were investigated and optimized. The kinetic data results were in better agreement with pseudo-second-order (PSO) model (R2 > 0.992). Multiple isotherm models were used to study the adsorption system and results showed that adsorption was monolayer. The BUT-VER showed an improvement in adsorption capacity in a single system (Pb(II): from 134.2 to 160.6 mg g-1) and (Cd(II): from 51.1 to 58.9 mg g-1) while in binary system (Pb(II): from 107.3 to 114.5 mg g-1) and (Cd(II): from 33.7 to 39.7 mg g-1), respectively. Furthermore, BUT-VER was tested in real river water and removed efficiency of >99% was achieved in just 1 h. The dominant mechanisms were electrostatic attraction and complexation. BUT-VER was regenerated for five consecutive cycles and showed >90% removal efficiency. These findings suggest that the proposed inexpensive adsorbent has the potential for practical applications of toxic metals removal from water.

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The simultaneous removal and selective separation of U(VI) and Th(IV) via adsorption remain challenging due to their strong mobility, reactivity, and similar chemical properties. Thus, a surface-functioned lignin nanoparticle (AL-PEI) was synthesized to adsorb U(VI)/Th(IV) in a unitary system via a pH-dependent process. In alkaline solution, AL-PEI exhibited excellent adsorption performance, and the maximum adsorption capacities for U(VI) and Th(IV) reached 392 and 396 mg/g, respectively. Discrepantly in acidic solution, the adsorption performance of AL-PEI for U(VI) could still reach a high capacity (332 mg/g), whereas highly limited adsorption capacity (less than 40 mg/g) for Th(IV) was obtained, and the separation factor of U(VI) from U(VI)-Th(IV) matrix significantly reached 6662 in 3 M of the HNO3 medium. The simultaneously efficient adsorption in alkaline solution and highly selective separation performance in acidic solution of AL-PEI also showed excellent anti-ions interference capacities, high reusability, and strong stability. This study is the first to apply lignin fabricating radiation-resistant adsorbent material, and the adsorbent displays good performance for U(VI)/Th(IV) removal and selective separation via a novel pH-dependent process, which is important to the green and sustainable development of nuclear energy and environmental protection.

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Non-thermal plasma (NTP) surface modification technology is a new method to control the surface properties of materials, which has been widely used in the field of environmental protection because of its short action time, simple process and no pollution. In this study, Cu/ACF (activated carbon fiber loaded with copper) adsorbent was modified with NTP to remove H2S and PH3 simultaneously under low temperature and micro-oxygen condition. Meanwhile, the effects of different modified atmosphere (air, N2 and NH3), specific energy input (0-13 J/mL) and modification time (0-30 min) on the removal of H2S and PH3 were investigated. Performance test results indicated that under the same reaction conditions, the adsorbent modified by NH3 plasma with 5 J/mL for 10 min had the best removal effect on H2S and PH3. CO2 temperature-programmed desorption and X-ray photoelectron spectroscopy (XPS) analyzes showed that NH3 plasma modification could introduce amino functional groups on the surface of the adsorbent, and increase the types and number of alkaline sites on the surface. Brunauer-Emmett-Teller and scanning electron microscopy showed that NH3 plasma modification did not significantly change the pore size structure of the adsorbent, but more active components were evenly exposed to the surface, thus improving the adsorption performance. In addition, X-ray diffraction and XPS analysis indicated that the consumption of active components (Cu and Cu2O) and the accumulation of sulfate and phosphate on the surface and inner pores of the adsorbent are the main reasons for the deactivation of the adsorbent.

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The highly efficient, pollution-free and degradable biomass-based adsorbents used for the purification of wastewater are currently being highlighted in the research. Bamboo is an excellent raw material for pulp production due to its characteristics of fast growth, wide distribution and high cellulose content. In this study, a tannin/chitosan/bamboo pulp aerogel (TCPA), an environmentally friendly, renewable and low-density adsorbent, was synthesized using a simple freeze-drying method and analyzed by FTIR, XPS, SEM, TEM, TGA and surface area and porosity methods. TCPA has a large specific surface area (137.33 m2/g) and 3D porous structure, and its surface has multiple functional groups including amino, carboxyl and hydroxyl groups, which lead to a simultaneous absorption effect with Me2+ (Cu2+ and Cd2+). The maximum adsorption capacity for Cu2+ and Cd2+ of the TCPA was 72.73 mg/g and 52.52 mg/g, respectively. The adsorption processes of Me2+ by TCPA follow the pseudo-second-order model and Langmuir isotherm mode, and the adsorption processes are spontaneous and endothermic. The study provides a promising candidate for the treatment of wastewater containing heavy metal mixtures.

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Currently, simultaneous removal of anionic and cationic pollutants from combined pollution wastewater is a challenging subject. Here, a novel composite adsorbent which can simultaneously adsorb anionic azo dye and heavy metal cations was developed by flocculation inspired assembly of Mg2Al layered double hydroxides (LDH) and fulvic acid (FA). The results show that the negatively charged macromolecule FA is firmly intertwined with the positively charged LDH through electrostatic attraction and adsorption bridging. This composite adsorbent (Mg2Al LDH-FA) can effectively capture anionic Orange II by anion exchange adsorption derived from LDH component with the maximum adsorption capacity of 604 mg/g. Mg2Al LDH-FA also exhibits good adsorption performance for heavy metals due to the complexation with FA and surface precipitation on LDH. The adsorption isotherms of heavy metals coincided with Langmuir model or Freundlich model, and the adsorption capacities for Pb2+, Cu2+, Ni2+, Cd2+ could reach up to 661.5 mg/g, 116.3 mg/g, 117.3 mg/g, 235.2 mg/g respectively. Particularly, Mg2Al LDH-FA can simultaneously uptake Orange II and heavy metals from the stimulated combined pollution wastewater, moreover it shows higher adsorption capacity for each pollutant than that in the single pollutant case as the result of the synergistic adsorption effect between LDH and FA.

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Upcycling of waste plastics as functional materials is a new approach for synthesizing low-cost and durable adsorbents with zwitterionic property. Herein, a facile process for recycling blending waste plastics to fabricate zwitterionic plastic-g-hydrogel (ZPH) for simultaneous adsorbing cationic and anionic heavy metals was developed. ZPH possessed high affinities for cations and anions in both acid and alkaline conditions owing to its zwitterionic property, and the maximum adsorption capacities of Pb2+, Cd2+, Ba2+, and Cr(VI) (Cr2O72-) were 132.13, 85.58, 69.92 and 85.15 mg/g, respectively. Mechanism study indicated the incompatibility of blending plastics was skillfully overcome through the crosslinking between sodium alginate (SA)/chitosan (CTS) and plastics. Cations were adsorbed onto ZPH via electrostatic interaction, cation exchange and coordination interactions with Cl/N/O-containing groups. Furthermore, the reduction of Cr(VI) to Cr(III) was another important path for ZPH to capture anionic Cr2O72-, and subsequently Cr(III) was adsorbed via coordination interaction and cation exchange. Moreover, the regeneration experiment showed ZPH possessed excellent reusability and stable structure. Accordingly, this research provides a profitable approach for recycling blending plastics, and ZPH has potentials for industrial application in wastewater treatment or contaminated site remediation with complex heavy metals pollution.

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Trivalent arsenic (As(III)) and divalent cadmium (Cd(II)) contamination in water environment is an urgent issue because of their most toxic physicochemical properties. Herein, the simultaneous purification of As(III) and Cd(II) from aqueous solution was achieved by use of a pre-magnetic Fe modified bamboo biochar that cross-linked CaMgAl layered double-hydroxide composite (Fe-BC@LDH). In a binary system, adsorption equilibrium of As(III) and Cd(II) onto specific sorbent Fe-BC@LDH was reached within 100 and 10 min of contact time under anaerobic conditions, respectively, and the maximum adsorption capacities of As(III) and Cd(II) by Fe-BC@LDH were respectively calculated to be ⁓265.3 and ⁓320.7 mg/g at pH 4.5 and 5- and 14-times than that of unmodified biochar. Moreover, adsorption in a competitive or single system, the sorbent displayed a greater preference for Cd(II). Importantly, the removal of As(III) and Cd(II) onto the composite was more favorable in a binary system due to formation of ternary FeOCdAs bonding configuration as well as the redox transformation of As(III) to As(V), inner-sphere complexation of MOAs/Cd (MFe, Ca, Mg, Al), electrostatic attraction, and co-precipitation of scorodite and hydroxy­iron­cadmium. Furthermore, the nanocomposite was still highly efficient after 5 adsorption cycles. This study demonstrated that the synthesized cost-effective Fe-BC@LDH is a promising candidate for the simultaneous separation of As(III) and Cd(II) from wastewater.

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Heavy metals and organic dyes are the major source of water pollution. Herein, a trifunctional ß-cyclodextrin-ethylenediaminetetraacetic acid-chitosan (ß-CD-EDTA-CS) polymer was synthesized using an easy and simple chemical route by the reaction of activated ß-CD with CS through EDTA as a cross-linker (amidation reaction) for the removal of inorganic and organic pollutants from aqueous solution under different parameters such as pH, time effect, initial concentration, reusability, etc. The synthesized adsorbent was characterized using powder X-ray diffraction, Fourier transform infrared spectroscopy, field scanning electron microscopy, energy dispersive spectroscopy, Brunauer-Emmett-Teller (BET), thermogravimetric analyzer techniques to investigate their structural, functional, morphological, elemental compositions, surface area and thermal properties, respectively. Two types of heavy metals, i.e., mercury (Hg2+) and cadmium (Cd2+), and three organic dyes, i.e., methylene blue (MB), crystal violet (CV) and safranin O (SO) were chosen as inorganic and organic pollutants, respectively, to study the adsorption capacity of ß-CD-EDTA-CS in aqueous solution. The ß-CD-EDTA-CS shows monolayer adsorption capacity 346.30 ± 14.0 and 202.90 ± 13.90 mg g-1 for Hg2+ and Cd2+, respectively, and a heterogeneous adsorption capacity 107.20 ± 5.70, 77.40 ± 5.30 and 55.30 ± 3.60 mg g-1 for MB, CV and SO, respectively. Kinetics results followed pseudo-second order (PSO) kinetics behavior for both metal ions and dyes, and higher rate constants values (0.00161-0.00368 g mg-1 min-1) for dyes confirmed the cavitation of organic dyes (physisorption). In addition, we have also demonstrated the performance of ß-CD-EDTA-CS for the of four heavy metals Hg2+, Cd2+, Ni2+, and Cu2+ and three dyes MB, CV, and SO in secondary treated wastewater. Findings of this study indicate that ß-CD-EDTA-CS simple and essay to synthesize and can be use in wastewater treatment.

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