RESUMEN

The present study investigated the adsorption of diclofenac sodium (DCF) and carbamazepine (CBZ) on carbon-silica composites (CSC), activated carbon (RH-AC) and biogenic silica (RH-BS) based on rice husks from aqueous solutions. The materials were characterised using scanning electron microscopy, infrared spectroscopy, inductively coupled plasma optical emission spectroscopy, nitrogen sorption and elemental analysis. These methods provided essential information on the morphology, chemical composition, textural properties and surface characteristics of porous materials. The results of the adsorption studies demonstrate that the investigated materials exhibit varying adsorption capacities for DCF and CBZ. The maximum adsorption capacity was achieved by CSCs, with 1111 mg g-1 for DCF and 455 mg g-1 for CBZ and indicates additive effects on the adsorption capacity of CSCs compared to RH-AC and RH-BS. In addition to the hydrogen bonds and the π-π electron donor-acceptor interactions of the carbon component, further hydrogen bonds are formed by the silanol groups of the silica component. The CSCs derived from rice husks represent an innovative approach to the more efficient removal of pharmaceutical residues from wastewater. This is accomplished by utilizing a single starting material for both components, thereby yielding a unique structural combination.

RESUMEN

The high silicon content in rice plant waste, specifically rice husks, makes this waste by-product attractive for the extraction and valorization of silicon oxide, which is widely used as an inert support in catalysis, drug delivery and molecular sieving. The procedures currently used for the treatment of plant biomass make extensive use of mineral acids (HCl, H2SO4, HNO3), which, besides them being potential environmental pollutants, reduce the yield and worsen the chemical-physical properties of the product. In this study, an evaluation of the easy treatment of rice husks by benchmarking different, more eco-friendly carboxylic acids in order to obtain a mesoporous SiO2 with an alveolar structure and a relatively high surface area and pore volume (300-420 m2/g, 0.37-0.46 cm3/g) is presented. The obtained mesoporous silicas are characterized by worm-like pores with a narrow size distribution and a maximum in the range of 3.4-3.5 nm. The mesoporous structure of the obtained materials was also confirmed by TEM. The complete removal of the organic part of the rice husks in the final materials was evidenced by thermogravimetric analysis. The high purity of the obtained mesoporous silica was detected using ICP analysis (98.8 wt. %). The structure peculiarities of the obtained mesoporous silicas were also characterized by solid-state NMR and ATR-FTIR spectroscopies. The morphology of the mesoporous silica was investigated by SEM.

Asunto(s)

RESUMEN

Lab-made biosilica (SiO2) nanoparticles were obtained from waste biomass (rice husks) and used as eco-friendly fillers in the production of nickel matrix composite films via the co-electrodeposition technique. The produced biosilica nanoparticles were characterized using XRD, FTIR, and FE-SEM/EDS. Amorphous nano-sized biosilica particles with a high SiO2 content were obtained. Various current regimes of electrodeposition, such as direct current (DC), pulsating current (PC), and reversing current (RC) regimes, were applied for the fabrication of Ni and Ni/SiO2 films from a sulfamate electrolyte. Ni films electrodeposited with or without 1.0 wt.% biosilica nanoparticles in the electrolyte were characterized using FE-SEM/EDS (morphology/elemental analyses, roundness), AFM (roughness), Vickers microindentation (microhardness), and sheet resistance. Due to the incorporation of SiO2 nanoparticles, the Ni/SiO2 films were coarser than those obtained from the pure sulfamate electrolyte. The addition of SiO2 to the sulfamate electrolyte also caused an increase in the roughness and electrical conductivity of the Ni films. The surface roughness values of the Ni/SiO2 films were approximately 44.0%, 48.8%, and 68.3% larger than those obtained for the pure Ni films produced using the DC, PC, and RC regimes, respectively. The microhardness of the Ni and Ni/SiO2 films was assessed using the Chen-Gao (C-G) composite hardness model, and it was shown that the obtained Ni/SiO2 films had a higher hardness than the pure Ni films. Depending on the applied electrodeposition regime, the hardness of the Ni films increased from 29.1% for the Ni/SiO2 films obtained using the PC regime to 95.5% for those obtained using the RC regime, reaching the maximal value of 6.880 GPa for the Ni/SiO2 films produced using the RC regime.

RESUMEN

Rice husks are a low value byproduct, even though it possesses molecules with great potential, such as arabinoxylans, proteins, and silica. These molecules can be used to improve mechanical and physicochemical properties of materials for food packaging. In this work, hydrothermal treatment was used for a sustainable extraction of the valuable molecules present in rice husks. Various extraction temperatures (180, 200, and 220 °C) were performed targeting to extract fractions with distinct compositions. The water extract obtained at 220 °C demonstrated the highest extraction yield, 3 times superior to conventional hot water extraction. These extracts exhibited high content of proteins, phenolic compounds, and carbohydrates, particularly arabinoxylans. This extract was incorporated in chitosan-based films in different ratios, 1:0.1, 1:0.3, and 1:0.5 (chitosan:extract, w:v). The film with the lowest extract ratio presented the highest flexibility (higher elongation and lower Young's modulus) when compared to the pristine chitosan film. The antioxidant capacity was also increased, achieving an antioxidant capacity of >10-fold in comparison to control film. The results revealed that hydrothermal extraction emerges as an environmentally friendly and sustainable methodology for extracting valuable compounds from rice industry byproducts. This method exhibits significant potential to impart flexible and antioxidant properties to biobased materials.

Asunto(s)

RESUMEN

Rice husks are rich in xylan, which can be hydrolyzed by xylanase to form xylooligosaccharides (XOS). XOS are a functional oligosaccharide such as improving gut microbiota and antioxidant properties. In this study, the structure and functional characteristics of XOS were studied. The optimal xylanase hydrolysis conditions through response surface methodology (RSM) were: xylanase dosage of 3000 U/g, hydrolysis time of 3 h, hydrolysis temperature of 50 °C. Under this condition, the yield of XOS was 150.9 mg/g. The TG-DTG curve showed that XOS began to decompose at around 200 °C. When the concentration of XOS reached 1.0 g/L, the clearance rate of DPPH reached 65.76 %, and the scavenging rate of OH reached 62.10 %, while the clearance rate of ABTS free radicals reached 97.70 %, which was equivalent to the clearance rate of VC. XOS had a proliferative effect on four probiotics: Lactobacillus plantarum, Lactobacillus brucelli, Lactobacillus acidophilus, and Lactobacillus rhamnosus. However, the further experiments are needed to explore the improvement effect of XOS on human gut microbiota, laying a foundation for the effective utilization of XOS. XOS have a wide range of sources, low price, and broad development prospects. The reasonable utilization of XOS can bring greater economic benefits.

Asunto(s)

RESUMEN

BACKGROUND: Rice, a pivotal global food staple, annually accumulates vast amounts of rice husks, resulting in substantial environmental impact. Exploiting the high silica content in rice husk, our research aimed to recycle this agricultural byproduct to synthesize mesoporous silica nanoparticles (rMSNs). These nanoparticles were further modified to evaluate their potential as effective carriers for cancer drug delivery. RESULTS: rMSNs showed high biocompatibility, large surface area and porous structure as MSNs, making them excellent drug carriers. Further modifications were applied to rMSNs, such as the incorporation of the lanthanides europium and gadolinium into rMSNs, making them fluorescent and magnetic for detection and tracking using confocal fluorescence microscopy and magnetic resonance imaging. Additionally, folic acid and aptamer AS1411 were conjugated with rMSNs to enhance the targeting of cancer cells. HeLa cells exhibited higher uptake of camptothecin (CPT)-loaded rMSNs compared to normal fibroblast cells (L929). The linkage of disulfide bonds to rMSNs also allowed CPT to be carried by rMSNs and released intracellularly in the presence of the abundant reducing agent glutathione. The validation of rMSNs in vitro and in vivo proved their practical feasibility. CONCLUSION: Our findings indicate that low-cost rMSNs, derived from recycled agricultural waste, can replace highly valuable MSNs. Functionalized rMSNs exhibit promising capabilities in transporting clinical drugs to specific aberrant tissues and offering dual-targeting and dual-imaging functionalities for enhanced cancer therapy. © 2023 Society of Chemical Industry.

Asunto(s)

RESUMEN

Rice husk is an abundant agricultural waste generated from rice production, but its application is limited. Considering its complex components, the rice husk was hydrolyzed by different enzymes to enhance its saccharification. In this study, saccharification of the rice husk by cellulase, xylosidase, and xylanase was first investigated. The synergistic effect of LPMO on the above hydrolases and different enzyme combinations in the saccharification process was then explored. Thereafter, the formulation of the enzyme cocktail and the degradation conditions were optimized to obtain the highest saccharification efficiency. The results showed that the optimum enzyme cocktail consists of Celluclast 1.5 L (83.3 mg/g substrate), the key enzymes in the saccharification process, worked with BpXyl (20 mg/g substrate), BpXyn11 (24 mg/g substrate), and R17L/N25G (4 mg/g substrate). The highest reducing sugar concentration (1.19 mg/mL) was obtained at pH 6.0 and 60 â„ƒ for 24 h. Fourier transform infrared spectroscopy and scanning electron microscopy were employed to characterize the structural changes in the rice husk after degradation. The results showed that the key chemical bonds in cellulose and hemicellulose were broken. This study illuminated the concept of saccharifying lignocellulose from rice husk using LPMO synergistically assisted combined-hydrolase including cellulase, xylosidase, and xylanase, and provided a theoretical basis for lignocellulose biodegradation.

Asunto(s)

RESUMEN

The brightly colored synthetic dyes used in the textile industry are discharged at high concentrations-for example, various azo dyes including Methylene Blue (MB) and Methyl Orange (MO)-which is a matter of global concern, as such dyes are harmful to humans and the environment. Microbial degradation is considered an efficient alternative for overcoming the disadvantages of conventional physical and chemical dye removal methods. In this study, we investigated the potential of multiple types of the enzyme-producing extremophilic bacteria Bacillus FW2, isolated from food waste leachate, for the decolorization and bioremediation of artificial synthetic dyes. The screening of enzyme production and assaying of bacterial strain enzymes are essential for enhancing the breakdown of azo bonds in textile azo dyes. The degradation efficiencies of the water-soluble dyes MB and MO were determined at different concentrations using rice husk, which is an efficient substrate. Using the rice husks, the MO was removed completely within 20 h, and an estimated 99.8% of MB was degraded after 24 h by employing shaking at 120 rpm at 40 °C-whereas a removal efficiency of 98.9% was achieved for the combination of MB + MO. These results indicate the possibility of applying an extremophilic bacterial strain, Bacillus sp., for large-scale dye degradation in the future.

RESUMEN

In this study, the sound absorption coefficients of rice and buckwheat husks were estimated. Computed tomography (CT) images were processed to determine the circumference and surface area of voids in the granular material, and the normal incident sound absorption coefficients were derived. In addition, the tortuosity, which expresses the complexity of the sound wave propagation through the structure, was measured for each material. The theoretical sound absorption coefficients were then compared to the measured sound absorption coefficients with and without consideration of the tortuosity. A correction factor was used to bring the surface area of the granular material closer to the actual surface area and observed that the tortuosity obtained theoretical values that matched the trend of the measured values. These results indicate that using CT images to estimate the sound absorption coefficient is a viable approach.

RESUMEN

In this study, conventional and Graphene Oxide-engineered biochars were produced and thoroughly characterized, in order to investigate their potential as adsorptive materials. Two types of biomass, Rice Husks (RH) and Sewage Sludge (SS), two Graphene Oxide (GO) doses, 0.1% and 1%, and two pyrolysis temperatures, 400 °C and 600 °C were investigated. The produced biochars were characterized in physicochemical terms and the effect of biomass, GO functionalization and pyrolysis temperature on biochar properties was studied. The produced samples were then applied as adsorbents for the removal of six organic micro-pollutants from water and treated secondary wastewater. Results showed that the main factors affecting biochar structure was biomass type and pyrolysis temperature, while GO functionalization caused significant changes on biochar surface by increasing the available C- and O- based functional groups. Biochars produced at 600 °C showed higher C content and Specific Surface Area, presenting more stable graphitic structure, compared to biochars produced at 400 °C. Micro-pollutant adsorption rates were in the range of 39.9%-98.3% and 9.4%-97.5% in table water and 28.3%-97.5% and 0.0%-97.5% in treated municipal wastewater, for the Rice Husk and Sewage Sludge biochars respectively. The best biochars, in terms of structural properties and adsorption efficiency were the GO-functionalized biochars, produced from Rice Husks at 600 °C, while the most difficult pollutant to remove was 2.4-Dichlorophenol.

Asunto(s)

RESUMEN

The effect of different commercially available bedding materials on the growth performance and carcass characteristics of ducks for 42 days was investigated. 336 one-day-old White-Pekin ducklings (60.48 ± 0.16 g) were randomly allocated into 24-floor pens with one of the three beddings namely i) coco peat, ii) rice husks, or iii) sawdust. 14 ducklings per pen and 8 replicate pens per bedding material were used. Birds were fed a starter diet from days 1-21 and a grower diet from days 22-42. Weekly growth performance evaluation was conducted for the average body weight, weight gains, daily feed intake, and feed conversion efficiency. One bird per pen was sacrificed on day 42 for the evaluation of carcass characteristics including the carcass, breast, and leg muscle percentages. Breast and leg muscle samples were then collected and analyzed for their proximate and pH values. Higher body weights (p < 0.05) were noticed with rice husks on day 42 only. Improved daily gains (p < 0.05) were also noticed for birds raised with rice husks over the entire period (days 1-42). Concerning feed intake, higher values (p < 0.05) were similarly noted with rice husks for the grower phase (days 22-42), and the entire experimental period (days 1-42). Marginally improved feed intake values were also noted with the use of rice husks as the bedding materials on day 42 (p = 0.092). Improved feed efficiency (p < 0.05) was noticed with rice husks on day 35, the grower period, and the entire 42-day period. However, no significant differences were noticed for most of the carcass characteristics that were evaluated. Nevertheless, higher (p < 0.05) pH values for the breast muscle were noticed with the use of coco peat and sawdust as the bedding. Conclusively, the bedding type could have a significant impact on the growth performance of ducks without adverse effects on carcass characteristics. The use of rice husks as bedding might be advantageous and is therefore recommended.

RESUMEN

The alteration of agricultural wastes into novel adsorbents can stimulate their scalability in realistic application, showing great economic and environmental advantages. Here, we proposed a strategy to engineer rice husk (RH) with microporous melamine-formaldehyde networks (MFNs) resins and the utilization for dynamic removal of organic micropollutants rapidly and efficiently. was pre-treated to acquire attractive surface and unique hierarchical porosity, endowing with surface functionalization and essential filtering properties. MFNs can be uniformly generated in-situ on the fully exposed cellulose backbones of the pre-treated RH. MFNs granules functionalized RH (RH@MFNs) exhibited high removal efficiencies over 90% within 30 min for the adsorption of hazardous organic compounds (e.g., phenolic and antibiotic micropollutants) in static tests. Experiment results and density functional theory (DFT) simulation revealed that the synergy of hydrogen bonding, π-πinteraction, and micropore preservation dominates the adsorption. Further dynamic adsorption experiments showed that the removal efficiency and equilibrium removal capacity towards bisphenol A by RH@MFNs packed bed up-flow column were 2.6 and 67 times higher than that of raw RH, respectively. The column adsorption fits well with the Thomas model and bed depth service time (BDST) kinetic model. The inherent macropores inside RH and the roughness caused by the spiky structures and mesopores outside RH, as well as the accumulated MFNs granules, can lead to local turbulence of water flow around RH@MFNs, enabling fast and efficient adsorption. This sustainable and cost-effective preparation of RH-based adsorbents sheds light on the rational design of biomass waste adsorbents for realistic wastewater.

Asunto(s)

RESUMEN

Removing emulsified water from a water-in-crude oil (W/O) emulsion is critically required prior to downstream processing in the petroleum industry. In this work, environmentally friendly and amphipathic rice husk carbon (RHC) demulsifier was prepared by a simple carbonization process in a muffle furnace using rice husks as starting materials. RHC was characterized by field-emission scanning electron microscope, energy dispersive spectrometer, Fourier transform infrared spectrometer, ultraviolet-visible spectrometer, powder X-ray diffraction, zeta potential and synchronal thermal analyzer. The factors such as dosage, temperature, settling time, pH value and salinity were systematically investigated. The results indicated that the dehydration efficiency (DE) reached as high as 96.99% with 600 mg/L of RHC for 80 min at 70 °C. RHC exhibited an optimal DE under neutral condition, but it was also effective under acidic and alkaline conditions. Also, it had an excellent salt tolerance. The possible demulsification mechanism was explored by interfacial properties, different treatment methods for RHC and microexamination. The demulsification of RHC is attributed to its high interfacial activity, oxygen-containing groups and content of silica. It indicates that RHC is an effective demulsifier for the treatment of the W/O emulsion.

Asunto(s)

RESUMEN

Silicon sub-oxides (SiOx) are increasingly becoming a prospective anode material for lithium-ion batteries (LIBs). Nevertheless, inferior electrical conductivity and drastic volume fluctuation upon cycling significantly hamper the electrochemical performance of SiOx. In this work, rice husks (RHs)-derived pitaya-like SiOx/nitrogen-doped carbon (SNC) superstructures have been prepared by a simple electrospray-carbonization approach. SiOx nanoparticles (NPs) are well-dispersed in a spherical nitrogen-doped carbon (NC) matrix. The carbon frameworks discourage the aggregation of SiOx NPs, facilitating the kinetics for ion diffusion and charge transfer, and maintaining structural stability upon cycling, thus bringing about improved electrochemical performance. When the optimized SNC superstructures with SiOx content of 64.3% are utilized as LIBs anodes, a stable specific capacity of 622.8 mA h g-1 after 100 cycles at 0.1 A g-1, and an excellent long cycle performance of 190.1 mA h g-1 after 5000 cycles at 5 A g-1 are obtained. This effective and universal synthetic strategy for fabricating controllable superstructures offers insights into the development of high-performance LIBs.

Asunto(s)

RESUMEN

A N-enriched porous carbon/SiO2 (SiO2 /NC) composite from rice husks was prepared by ball milling and tested as a stable anode for lithium ion batteries (LIBs), in which the homogeneous dispersion of SiO2 nanoparticles and carbon matrix, and high level of N-doping can be realized simultaneously. The influence of N-doping on a series of SiO2 /NCs was systematically studied; this proved that the porosity, N-doping content, and electronic conductivity of SiO2 /NC can be controlled by adjusting common nitrogen sources (urea and melamine) and doping routes, including dry and wet milling, to reach a desirable balance of high capacity, long-term cyclability, and rate property. The optimized SiO2 /NC composite delivers a stably reversible capacity of 581 mA h g-1 at the high current load of 1.0 A g-1 at the 1000th cycle. The novel Li-storage mechanism of active silica in a composite was first proposed after observation of the N-doping effect that the redox reaction between SiO2 and Li+ is accelerated to transform into an alloying reaction of generated Si and Li+ , thus enhancing the reversible capacity. Moreover, kinetics analysis confirms that there is a combined Li-storage mechanism of battery-capacitive pattern in composite that contributes to fast charge transfer and ion diffusion during cycle.

Asunto(s)

RESUMEN

The sustainable future of contemporary society has been compromised due to environmental pollution from industrial systems and the generation of solid waste. Consequentially, the managed exploitation of natural resources to a sustainable level within the Earth's capacity remains a present and future challenge. Furthermore, the pursuit of materials free from toxic substances made from renewable sources is a tendency towards effective cleaner production and waste management. To address these problems, this article reports the results of exploratory and experimental research that developed a novel eco-efficient product - a pyramidal absorber of electromagnetic radiation - from rice husks and MDF (Medium Density Fibreboard) residues through design from waste principles. Key findings indicated that the technical performance of the absorber is better in the frequency of 2.45 GHz, resulting in a difference of -18.71 dB concerning the reflective metal plate used in the tests. This result is above the expected limit of -10 dB found in similar commercial products. This study is an innovation in improving the design from waste of pyramidal microwave absorbers used in radio frequency anechoic chambers. The product represents a new and sustainable alternative to similar products in the market that are produced from toxic materials extracted from non-renewable raw materials. The limitations and technical characteristics of usage for which the pyramidal absorbers of electromagnetic radiation are applicable should be considered.

Asunto(s)

RESUMEN

Organic waste from greens of tomato plants, gardening substrate, rice husks and shrimp-derived chitin were pyrolyzed at 400 °C and 500 °C for 3 h, with the aim to elucidate the feasibility of using such products as replacement of peat in soilless gardening substrates. Characterization of the carbonized organic matter (COM) and the gardening substrate indicated that neither the peat nor the COMs provided the recommended levels of nutrients for the cultivation of tomato plants, although improvements could be obtained using COM/substrate mixtures. The toxicity thresholds for Zn were exceeded significantly by the COMs of the tomato greens and high boron levels were found for all the COMs except for those derived from chitin. In a 40-days pot experiment, germination and development of tomato seeds and plants (Solanum lycopersicum L.) were tested on COM/peat mixtures at 30%, 60% and 100% COM substitution rate. The lack of seed germination on the mixtures with COM from tomato greens is best explained with the high salinity of the COM. Best plant growth was obtained with COM from chitin at 60%, most likely because its high N content satisfied best the N-needs of the growing tomato plants without increasing the pH of the growing media. Moreover, an increase of water retention was evidenced for COM/substrate mixtures. Although the use of COM from chitin and rice husks showed promising results, the proposed recycling of organic waste from agriculture or fishery as soilless gardening substrate requires the development of formulations of COM/peat/and added nutrients with ready-to-use characteristics to increase its feasibility.

Asunto(s)

RESUMEN

Efforts to reduce pressure on use of wood in particleboard formulation have included the use of non-wood materials such as crop residues. Physical and mechanical properties are determined by the number of the hydroxyl (-OH) groups. Hydroxyl (-OH) groups attracts water molecules through hydrogen bonding affecting water absorption (WA) and thickness swelling (TS). WA and TS affect curing process of adhesive. Curing process of adhesives affects the mechanical characteristics of formulated particleboards. These challenges have been acted upon continuously through research. This review paper presents crop residues used as alternative lignocellulose material source in particleboard formulation and the various advances that have been made to improve on the properties of the resultant particleboards. Improvement over time of the non-wood material in composite materials focusses on increasing water resistance and compatibility between lignocellulose and binder. Crop residues-based are used in making medium and low density particleboards. These boards have shown good mechanical characteristics which include modulus of rupture (MOR), modulus of elasticity (MOE) and internal bonding (IB). MOR, MOE and IB have over time been improved by enhancing chemical compatibility of lignocellulose material and the binders. Water absorption and thickness swelling remain challenge. This review paper further explored various methods of improving water absorption and thickness swelling of crop-residue based particleboards.

RESUMEN

Conventional binders in the particleboards formulation involve use of formaldehyde resins. Epidemiologic studies show that formaldehyde is carcinogenic. Efforts to reduce formaldehyde emissions by use of scavengers has not been proven to reduce the emission. Molecular bonding of biobased adhesive molecules with lignocellulose materials provides an alternative way of producing composite material. In this study, maize stalk (MS), rice husks (RH) and sugarcane bagasse (SB) were used as sources of lignocellulose materials for particleboard formulation. SB, MS and RH were collected from their respective sites, sorted and dried. MS and RH were ground. Lignin content determination was done by drying lignocellulose material at 105 °C. Lignocellulose materials were prepared by hydrolysis of dried lignocellulose material with sodium hydroxide. Oxidized starch was prepared by oxidation of cassava peel starch using alkaline hydrogen peroxide. Particleboards were formulated through starch-lignocellulose polymerization at 60 °C compressed with 6.5 Nmm-2 pressure. Characterization of raw materials and formulated particleboards was done using XRD for mineralogical analysis, FTIR and NMR for elucidation of functional groups transformation. The results showed that esterification is the main process of chemical bonding in the particleboard formulation due to reaction between -COOH from starch and and OH- from lignocellulose. Etherification between hydroxyl groups from starch with hydroxyl groups from lignocellulose material. RH combined more through silication process with cassava peels starch than RH and SB showing materials containing high cellulose and hemicellulose content are more compatible. Composite materials formulated were used to produce medium density particleboards that can be used for making furniture and room partitioning.

RESUMEN

A one-step and template-free synthesis of a SiC nanowires/C (SiC-NW/C) composite from rice husks (RHs) is realized via a molten-salt-assisted electrochemical method. The process integrates simultaneously carbonization, electrodeoxidation, nanostructuring, and self-purification for converting RHs to a SiC-NW/C hybrid that is assembled from SiC NWs embedded in porous N-doped graphitic carbon with strong coupling. The SiC-NW/C nanostructure enables efficient CO2 adsorption and fast separation and transfer of charge carriers. Benefiting from the structural and compositional merits, the SiC-NW/C composite shows superior activity for photoreduction of CO2 to CO, in the absence of any additional cocatalysts or sacrificial agents. The process proposed herein might help to bridge a closed-loop carbon cycle in the whole production-utilization of biomass.

Asunto(s)