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1.
Nano Lett ; 23(22): 10305-10310, 2023 Nov 22.
Artículo en Inglés | MEDLINE | ID: mdl-37956341

RESUMEN

The field of valleytronics considers the creation and manipulation of "valley states", charge excitations characterized by a particular value of the crystal momentum in the Brillouin zone. Here we show, using the example of minimally gapped (≤40 meV) graphene, that there exist lightforms that create almost perfect valley contrasting current states (up to ∼80% valley purity) in the absence of a valley contrasting charge excitation. These "momentum streaked" THz waveforms act by deforming the excited state population in momentum space such that current flows at one valley yet is blocked at the conjugate valley. This approach both unlocks the potential of graphene as a materials platform for valleytronics, as gaps of 10-40 meV are robustly found in useful experimental contexts such as graphene/hBN systems, while simultaneously providing a tool toward ultrafast light control of valley currents in diverse minimally gapped matter, including many topological insulator systems.

2.
Environ Sci Pollut Res Int ; 27(22): 28276-28287, 2020 Aug.
Artículo en Inglés | MEDLINE | ID: mdl-32415449

RESUMEN

Marine sediment is the final sink of polycyclic aromatic hydrocarbons (PAHs) from river input and atmospheric deposition. Such kind of pollutant cycles in the marine environment is usually controlled by hydrodynamic conditions. Many previous studies have explored how ocean currents influence pollutant distribution, but very few studies have focused on the relationships between the distribution patterns of pollutant and residual currents or sediment transport. In this study, 16 monomers of PAHs from 135 surface sediment samples collected in the Hangzhou Bay, a typical macrotidal bay, were systematically identified and their sources were analyzed. The sediment characteristics and distribution pattern were also comprehensively analyzed. The results showed the seabed sediments were moderately polluted by PAHs with a level of 38.58-1371.06 ng/g (median 186.70 ng/g). Most of the PAHs are composed of three to five rings, originated from combustion of coal and firewood. The combustion of oil also contributes to PAHs in seabed sediments for some areas. The PAHs are found to be concentrated within the estuary and the offshore areas, as well in coastal ocean. Fine-grained sediment transport is controlled by residual currents, which leads to PAH accumulation in the bay and the offshore areas, forming a high-value distribution pattern. Hence, we conclude that residual current is the main factors that control the long-term distribution of PAHs in the seabed sediments of the macrotidal bay. Temporal and spatial varying models of PAHs were needed in a further study to explore further the mechanisms how PAHs are transported in coastal areas.


Asunto(s)
Contaminantes Ambientales , Hidrocarburos Policíclicos Aromáticos/análisis , Contaminantes Químicos del Agua/análisis , Bahías , China , Monitoreo del Ambiente , Sedimentos Geológicos
3.
Mar Pollut Bull ; 141: 91-103, 2019 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-30955786

RESUMEN

Riverine input is an important source of contaminants in the marine environments. Based on a hydrodynamic model, the dilution characteristics of riverine contaminants in the Seto Inland Sea and their controlling factors were studied. Results showed that contaminant concentration was high in summer and low in winter. Contaminant concentration decreased with the reduction of its half-life period, and the relationship between them followed power functions. Sensitivity experiments suggested that the horizontal current and vertical stratification associated with air-sea heat flux controlled the seasonal cycle of contaminant concentration in the water column; however, surface wind velocity was the dominant factor affecting the surface contaminant concentration. In addition, contaminant concentration in a sub-region was likely controlled by the variations in river discharges close to the sub-region. These results are helpful for predicting contaminant concentrations in the sea and are expected to contribute to assessing the potential ecological risks to aquatic organisms.


Asunto(s)
Monitoreo del Ambiente/métodos , Ríos/química , Agua de Mar/química , Contaminantes Químicos del Agua/análisis , Japón , Modelos Teóricos , Estaciones del Año , Movimientos del Agua
4.
Mar Pollut Bull ; 116(1-2): 270-290, 2017 Mar 15.
Artículo en Inglés | MEDLINE | ID: mdl-28089551

RESUMEN

Due to the continuous human activities linked to economic expansion in the Arabian Gulf area (also known as Persian Gulf), various activities have had an adverse impact on the coastal environment. Furthermore, reduction of precipitation and river flows has resulted in alterations to the hydro-environment regime at various levels. The current study uses a detailed numerical model that was validated with recent field measurements to determine the comprehensive seasonal circulations of the Northern Arabian/Persian Gulf (NAG). The seasons were studied individually using a three-dimensional setup and by considering the baroclinic effects and meteorological forcing. It was found that the NAG exhibits distinctive circulation characteristics each season. In winter, a dense water mass that forms near Kuwait flows toward the southeast near-bed, whereas relatively weak Indian Ocean Surface Waters (IOSW) flow along the Iranian coast and, to a lesser extent, oppose these currents. In spring, the southeast near bed circulations are weaker, while the IOSW is in highest conditions reaching the northern latitudes of the Gulf without being significantly diluted. In summer, a thermocline develops, particularly at the main axis of the NAG, and increases the chances of upwelling. The surface water during this season is significantly controlled by wind. Most distinctive, a non-uniform flow is evident at the offshore regions along the Arabian coast due to strong density gradients. In the fall, the circulations are relatively weaker compared to other seasons; however, cyclonic features are evident at the southeast of the estuary. Well-known counter clockwise circulations NAG are evident throughout the season, but at various strengths; summer is the most active season, while fall is the least active season. In a similar manner, the along shore current varied spatially and temporally throughout the seasons.


Asunto(s)
Estaciones del Año , Movimientos del Agua , Océano Índico , Irán , Ríos , Viento
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