RESUMEN
Black liquor (BL) is the major bioproduct and biomass fuel in pulp mill processes. However, the high viscosity of BL makes it a challenging material to work with, resulting in issues with evaporators and heat exchangers during its transport and processing. The thermal and rheological properties of BLs from Pinus sp. (PBL) and Eucalyptus sp. (EBL) were studied. FTIR spectra revealed the presence of the characteristic functional groups and the chemical composition in liquors. TGA/DTG curves showed three characteristic degradation stages related to evaporation of water, pyrolysis of organic groups, and condensation of char. Rheologically, liquors are classified as non-Newtonian and with comportment pseudoplastic. Their rheological dynamic shear properties included a linear viscoelastic region up to 1% shear strain, while frequency sweeps showed that storage modulus (G') > loss modulus (G''), thus confirming the solid-like behavior of both BLs. The rheological study demonstrated that increasing the temperature and oscillatory deformations of PBL and EBL decreased their degree of viscoelasticity, which could favor their pumping and handling within the pulp mill, as well as the droplet formation and swelling characteristics in the recovery furnace.
Asunto(s)
Eucalyptus , Pinus , Reología , Eucalyptus/química , Pinus/química , Viscosidad , Brasil , Finlandia , Temperatura , Espectroscopía Infrarroja por Transformada de FourierRESUMEN
In kraft paper mills, supersonic steam jets are used to remove deposits that build up on the heat exchanger tubes in the recovery boiler. In this study, the fracture toughness KC and work of fracture, WF, of simulated boiler deposits were measured at temperatures up to 500 °C to determine the optimal conditions for deposit removal. The model deposits experienced an important brittle to ductile transition at ~450 °C. Above this temperature, ductile deposits required lower peak force, but four times more energy to fracture when compared to those tested at lower temperatures. The transition was clear in scanning electron micrographs of the fracture surfaces. The findings have significant implications for mills wishing to optimize sootblower performance.
RESUMEN
The flue gas composition and the flue gas temperature at outlet of the economizer were tested, and the influence of flue gas recirculation (FGR) on the efficiency of the incinerator-waste heat boiler and NOx emission in a waste incineration power plant with a waste disposal capacity of 500 t/d was explored experimentally. The results indicate that the largest proportion of the total heat loss is the exhaust heat loss under different loads, and the next is the heat loss of slag. Within the test range, the efficiency of the incinerator-waste heat boiler increases from 80.26% to 80.42% as the ratio of the recirculating flue gas increases from 0 to 16.43%. The oxygen content in the flue gas and FGR have significant influence on NOx emissions. The NOx concentration at outlet of the economizer increases from 209.54 mg/m3 to 307.30 mg/m3, that is an increase of 46.65%, when the oxygen content at outlet of the economizer increases from 4.52% to 8.00%. Compared with the shutdown of FGR system, the NOx concentration at outlet of the economizer decreases from 209.54 mg/m3 to 126.15 mg/m3 when the FGR valve is fully opened. The results have important reference significance for the design of incinerator-waste heat boiler and the optimal operation of power plant.