RESUMEN
The biological activated carbon (BAC) process has been widely used in drinking water treatment to improve the removal of pollutants, including the precursors of nitrogenous disinfection byproducts (N-DBPs). Nevertheless, old BAC filter effluent DON concentration is heightened, increasing the highly toxic N-DBPs formation potential. Herein, the variation of dissolved organic nitrogen (DON) was comprehensively explored during one backwashing cycle, focusing on four BAC age (0.3, 2, 5, and 10 years) for BAC filters in drinking water. Comparatively, the removal rate of DON by four BAC followed the order 0.3-yr BAC (39.69%-66.96%) >2-yr BAC (10.10%-39.78%) >5-yr BAC (-4.18%-29.63%)>10-yr BAC (-20.88%-19.87%). When at day 7 after backwashing, 10-yr BAC filter effluent increased at least 13.71% of DON and considerably elevated the N-DBPs formation potential, which was attributed to the ultimate production of more various proteins/amino sugars-like compounds by microbes. In comparisons of microbial community between all BAC samples, Rhizobials were more prevalent in 10-yr BAC and could produce microbe-derived DON associated with amino acids. Moreover, microbes regulated metabolic pathways, including amino acid biosynthesis, TCA cycle, purine metabolism, and pyrimidine metabolism, to enhance the adaptive cellular machinery in response to environmental stressors, and therefore accelerated microbial secretion of microbe-derived DON. Structural equation model (SEM) analysis investigated that BAC age had bio-effects on N-DBPs formation potential, which were delivered via the linkage of " BAC age, microbial community, microbial metabolism, and DON molecular characteristics". Our findings demonstrate the necessity of reconsidering the feasibility of BAC filters for long-time operation, which has implications for future N-DBPs precursors control in drinking water.
Asunto(s)
Agua Potable , Contaminantes Químicos del Agua , Purificación del Agua , Carbón Orgánico/química , Materia Orgánica Disuelta , Agua Potable/análisis , Contaminantes Químicos del Agua/análisis , Desinfección , Nitrógeno/análisisRESUMEN
The main objective of this work was to investigate the feasibility of using vacuum ultraviolet (VUV, 185 + 254 nm) and ultraviolet (UV, 254 nm) for the reduction of dissolved organic nitrogen (DON) and haloacetonitrile formation potential (HANFP) of surface water and treated effluent wastewater samples. The results showed that the reduction of dissolved organic carbon (DOC), DON, hydrophobicity (HPO), absorbance at 254 nm (UV254), and fluorescence excitation-emission matrix (FEEM) of both water samples by VUV was higher compared to using UV. The addition of H2O2 remarkably improved the performances of VUV and UV. VUV/H2O2 exhibited the highest removal efficiency for DOC and DON. Even though HANFP increased at the early stage, its concentration decreased (19-72%) at the end of treatment (60 min). Decreases in DON (30-41%) and DOC (51-57%) led to HANFP reduction (53-72%). Moreover, FEEM revealed that substantial reduction in soluble microbial product-like compounds (nitrogen-rich organic) had a strong correlation with HANFP reduction, implying that this group of compounds act as a main precursor of HANs. The VUV/H2O2 system significantly reduced HANFP more than UV/H2O2 and therefore is suitable for controlling HAN precursors and HAN formation in drinking water and reclaimed wastewater.
Asunto(s)
Contaminantes Químicos del Agua , Purificación del Agua , Desinfección , Peróxido de Hidrógeno , Nitrógeno , Rayos Ultravioleta , Vacio , Contaminantes Químicos del Agua/análisisRESUMEN
The comprehensive control efficiency for the formation potentials (FPs) of a range of regulated and unregulated halogenated disinfection by-products (DBPs) (including carbonaceous DBPs (C-DBPs), nitrogenous DBPs (N-DBPs), and iodinated DBPs (I-DBPs)) with the multiple drinking water treatment processes, including pre-ozonation, conventional treatment (coagulation-sedimentation, pre-sand filtration), ozone-biological activated carbon (O3-BAC) advanced treatment, and post-sand filtration, was investigated. The potential toxic risks of DBPs by combing their FPs and toxicity values were also evaluated. The results showed that the multiple drinking water treatment processes had superior performance in removing organic/inorganic precursors and reducing the formation of a range of halogenated DBPs. Therein, ozonation significantly removed bromide and iodide, and thus reduced the formation of brominated and iodinated DBPs. The removal of organic carbon and nitrogen precursors by the conventional treatment processes was substantially improved by O3-BAC advanced treatment, and thus prevented the formation of chlorinated C-DBPs and N-DBPs. However, BAC filtration leads to the increased formation of brominated C-DBPs and N-DBPs due to the increase of bromide/DOC and bromide/DON. After the whole multiple treatment processes, the rank order for integrated toxic risk values caused by these halogenated DBPs was haloacetonitriles (HANs)â«haloacetamides (HAMs)>haloacetic acids (HAAs)>trihalomethanes (THMs)>halonitromethanes (HNMs)â«I-DBPs (I-HAMs and I-THMs). I-DBPs failed to cause high integrated toxic risk because of their very low FPs. The significant higher integrated toxic risk value caused by HANs than other halogenated DBPs cannot be ignored.
Asunto(s)
Desinfectantes/análisis , Contaminantes Químicos del Agua/análisis , Purificación del Agua/métodos , Bromuros , Carbón Orgánico , Cloro , Desinfectantes/toxicidad , Desinfección , Agua Potable , Filtración , Nitrógeno , Ozono , Contaminantes Químicos del Agua/toxicidad , Abastecimiento de AguaRESUMEN
Surface water are frequently subjected to problems of algal blooms and release of algae organic matter (AOM) from the algae cells, which cause many water quality issues. This study investigated the formation of organic chloramines and nitrogenous disinfection by-products (N-DBPs) during chlor(am)ination and UV/chlor(am)ination of AOM in drinking water. AOM caused higher organic chloramine formation than humic acid and fulvic acid during chlor(am)ination. The formation of organic chloramines increased first and then decreased with the increase of free chlorine dosage, but kept increasing with the increase of NH2Cl dosage. During AOM chlorination, the formation of organic chloramines kept decreasing as the reaction time went by, and the maximum organic chloramine proportion (79.1%) in total chlorine occurred at 8 h. However, during AOM chloramination, the formation of organic chloramines increased first, decreased in the following and then increased again as the reaction time went by, and the maximum organic chloramine proportion (22.1%) in total chlorine occurred at 24 h. UV irradiation pretreatment did not effectively influence organic chloramine formation during AOM chlor(am)ination, but accelerated the degradation of organic chloramines during chloramination. Besides, UV pretreatment enhanced the formation of N-DBPs during the subsequent chlor(am)ination of AOM, especially dichloroacetonitrile.
Asunto(s)
Cloraminas , Agua Potable , Desinfección , Halogenación , Contaminantes Químicos del Agua , Purificación del AguaRESUMEN
Photodegradation of haloacetonitriles (HANs), highly carcinogenic nitrogenous disinfection by-products, in water using vacuum ultraviolet (VUV, 185 + 254 nm) in comparison with ultraviolet (UV, only 254 nm) was investigated. Monochloroacetonitrile (MCAN), dichloroacetonitrile (DCAN), trichloroacetonitrile (TCAN), and dibromoacetonitrile (DBAN) were species of HANs studied. The effect of gas purging and intermediate formation under VUV were examined. The results show that the pseudo first order rate constants for the reduction of HANs under VUV were approximately 2-7 times better than UV. The order of degradation efficiency under VUV and UV was MCAN < DCAN < TCAN < DBAN. The degradation efficiencies of individual HANs under VUV were higher than those of mixed HANs, suggesting competitive effects among HANs. Under nitrogen purging, the removal rate constants of mixed HANs was much higher than that of the aerated condition by 34.4, 34.9, 10.1, and 3.8 times for MCAN, DCAN, TCAN, and DBAN, respectively. The major degradation mechanism for HANs was different depending on HANs species. Degradation intermediates of HANs such as 2-chloropropionitrile, 2,2-dimethylpropanenitrile, and fumaronitrile were produced from the substitution, addition, and polymerization reactions. In addition, chlorinated HANs with lower number of chlorine atom including MCAN and DCAN were found as intermediates of DCAN and TCAN degradation, respectively.
Asunto(s)
Fotólisis , Agua , Cloro , Halogenación , Rayos Ultravioleta , VacioRESUMEN
The use of persulfate oxidation processes is receiving increasing interest for the removal of aquatic contaminants. However, it is unknown whether its application in the presence of iodide has the potential to directly form iodinated DBPs. This study investigated formation of six chlorinated, brominated and iodinated di-haloacetamides (DHAcAms) during persulfate oxidation in the presence of bromide and iodide. Formation of the same DHAcAms during chlorination was monitored for comparison. Persulfate oxidation of natural water formed diiodoacetamide (DIAcAm), and heat-activated persulfate, at 45 °C and 55 °C, generated bromoiodoacetamide (BIAcAm) and dibromoacetamide (DBAcAm), besides DIAcAm. At an ambient iodide concentration of 0.3 µM, total DHAcAms increased slightly from 0.43 to 0.57 nM as the water temperature increased from 4 °C to 35 °C, respectively (only DIAcAm detected), then significantly increased to 1.6 nM at 55 °C (DIAcAm, BIAcAm and DBAcAm detected). Equivalent total DHAcAm concentrations in the presence of 3.0 µM iodide were 0.5, 0.91 and 2.1 nM, respectively. Total DHAcAms formed during chlorination, predominantly dichloroacetamide (DCAcAm) and bromochloroacetamide (BCAcAm), were always significantly higher than that during persulfate oxidation. However, an integrated risk assessment showed the toxicity resulting from the DHAcAms was higher during persulfate oxidation than chlorination. An increase in water temperature from 25 °C to 55 °C significantly increased the integrated toxic risk values for both persulfate oxidation and chlorination. Use of persulfate oxidation should be weighed against the formation of high-toxicity iodinated HAcAms in waters with high ambient iodide concentrations.
Asunto(s)
Temperatura , Agua , Desinfección , Halogenación , Contaminantes Químicos del Agua , Purificación del AguaRESUMEN
Pilot-scale tests were performed to reduce the formation of a range of carbonaceous and nitrogenous disinfection by-products (C-, N-DBPs), by removing or transforming their precursors, with an integrated permanganate oxidation and powdered activated carbon adsorption (PM-PAC) treatment process before conventional water treatment processes (coagulation-sedimentation-filtration, abbreviated as CPs). Compared with the CPs, PM-PAC significantly enhanced the removal of DOC, DON, NH3(+)-N, and algae from 52.9%, 31.6%, 71.3%, and 83.6% to 69.5%, 61.3%, 92.5%, and 97.5%, respectively. PM pre-oxidation alone and PAC pre-adsorption alone did not substantially reduce the formation of dichloroacetonitrile, trichloroacetonitrile, N-nitrosodimethylamine and dichloroacetamide. However, the PM-PAC integrated process significantly reduced the formation of both C-DBPs and N-DBPs by 60-90% for six C-DBPs and 64-93% for six N-DBPs, because PM oxidation chemically altered the molecular structures of nitrogenous organic compounds and increased the adsorption capacity of the DBP precursors, thus highlighting a synergistic effect of PM and PAC. PM-PAC integrated process is a promising drinking water technology for the reduction of a broad spectrum of C-DBPs and N-DBPs.
Asunto(s)
Carbón Orgánico/química , Desinfección , Compuestos de Manganeso/química , Óxidos/química , Contaminantes Químicos del Agua/aislamiento & purificación , Purificación del Agua/métodos , Adsorción , Amidas/química , Amidas/aislamiento & purificación , Hidrocarburos Halogenados/química , Hidrocarburos Halogenados/aislamiento & purificación , Compuestos de Nitrógeno/química , Compuestos de Nitrógeno/aislamiento & purificación , Oxidación-Reducción , Proyectos Piloto , Contaminantes Químicos del Agua/químicaRESUMEN
Previous research demonstrated that ozone dosed before biological activated carbon (BAC) filtration reduces the formation of disinfection by-products (DBPs) upon subsequent chlorination. The current work aimed to evaluate the impact of terminating this pre-ozonation on the ability of the BAC to remove the precursors of N-DBPs. More N-DBP precursors passed into the post-BAC water when the pre-ozonation was terminated, resulting in greater formation of N-DBPs when the water was subsequently chlorinated, compared to a parallel BAC filter when the pre-ozonation was run continuously. Moreover, the N-DBP formation potential was significantly increased in the effluent of the BAC filter after terminating pre-ozonation, compared with the influent of the BAC filter (i.e. the effluent from the sand filter). Therefore, while selectively switching pre-ozonation on/off may have cost and other operational benefits for water suppliers, these should be weighed against the increased formation of N-DBPs and potential associated health risks.