RESUMEN

This work aims to explore the effects of the magnetic polystyrene particles (MPS) on contaminants removal of the high emulsified oil wastewater. 26 days intermittently-aerated progress illustrated that COD removal efficiency and the resistance to the shock loading was promoted in the presence of MPS. Gas chromatography (GC) results also indicated that MPS enhanced the number of organic species reduced. According to the cyclic voltammetry test, conductive MPS appeared special redox performance which was considered could to facilitate the extracellular electron transfer. Furthermore, MPS dosing accelerated the electron-transporting system (ETS) activity by 24.91% compared the control. Based on the superior performance above, the conductivity of MPS is considered to be responsible for the enhanced organic removal efficiency. Moreover, the high-throughput sequencing displayed that electroactive Cloacibacterium and Acinetobacter accounted for a higher proportion in the MPS reactor. Additionally, Porphyrobacter and Dysgonomonas which were capable of degrading organics were also enriched more by MPS. To sum up, MPS is a promising additive to enhance the organic substances removal for the high emulsified oil wastewater.

Asunto(s)

Eliminación de Residuos Líquidos , Aguas Residuales , Eliminación de Residuos Líquidos/métodos , Poliestirenos , Biopelículas , Reactores Biológicos , Fenómenos Magnéticos

RESUMEN

Liquid-borne particles sampling and cantilever-based mass detection are widely applied in many industrial and scientific fields e.g., in the detection of physical, chemical, and biological particles, and disease diagnostics, etc. Microscopic analysis of particles-adsorbed cantilever-samples can provide a good basis for measurement comparison. However, when a particles-laden droplet on a solid surface is vaporized, a cluster-ring deposit is often yielded which makes particles counting difficult or impractical. Nevertheless, in this study, we present an approach, i.e., on-cantilever particles imprinting, which effectively defies such odds to sample and deposit countable single particles on a sensing surface. Initially, we designed and fabricated a triangular microcantilever sensor whose mass m0, total beam-length L, and clamped-end beam-width w are equivalent to that of a rectangular/normal cantilever but with a higher resonant frequency (271 kHz), enhanced sensitivity (0.13 Hz/pg), and quality factor (~3000). To imprint particles on these cantilever sensors, various calibrated stainless steel dispensing tips were utilized to pioneer this study by dipping and retracting each tip from a small particle-laden droplet (resting on a hydrophobic n-type silicon substrate), followed by tip-sensor-contact (at a target point on the sensing area) to detach the solution (from the tip) and adsorb the particles, and ultimately determine the particles mass concentration. Upon imprinting/adsorbing the particles on the sensor, resonant frequency response measurements were made to determine the mass (or number of particles). A minimum detectable mass of ~0.05 pg was demonstrated. To further validate and compare such results, cantilever samples (containing adsorbed particles) were imaged by scanning electron microscopy (SEM) to determine the number of particles through counting (from which, the lowest count of about 11 magnetic polystyrene particles was obtained). The practicality of particle counting was essentially due to monolayer particle arrangement on the sensing surface. Moreover, in this work, the main measurement process influences are also explicitly examined.

RESUMEN

Cantilever-based sensors have attracted considerable attention in the recent past due to their enormous and endless potential and possibilities coupled with their dynamic and unprecedented sensitivity in sensing applications. In this paper, we present a technique that involves depositing and vaporizing (at ambient conditions) a particle-laden water droplet onto a defined sensing area on in-house fabricated and commercial-based silicon microcantilever sensors. This process entailed the optimization of dispensing pressure and time to generate and realize a small water droplet volume (Vd = 49.7 ± 1.9 pL). Moreover, we monitored the water evaporation trends on the sensing surface and observed total evaporation time per droplet of 39.0 ± 1.8 s against a theoretically determined value of about 37.14 s. By using monodispersed particles in water, i.e., magnetic polystyrene particles (MPS) and polymethyl methacrylate (PMMA), and adsorbing them on a dynamic cantilever sensor, the mass and number of these particles were measured and determined comparatively using resonant frequency response measurements and SEM particle count analysis, respectively. As a result, we observed and reported monolayer particles assembled on the sensor with the lowest MPS particles count of about 19 ± 2.