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1.
Sci Bull (Beijing) ; 69(17): 2776-2792, 2024 Sep 15.
Artículo en Inglés | MEDLINE | ID: mdl-39098564

RESUMEN

With the vigorous development and huge demand for portable wearable devices, wearable electronics based on functional fibers continue to emerge in a wide range of energy storage, motion monitoring, disease prevention, electromagnetic interference (EMI) shielding, etc. MXene, as an emerging two-dimensional inorganic compound, has shown great potential in functional fiber manufacturing and has attracted much research attention due to its own good mechanical properties, high electrical conductivity, excellent electrochemical properties and favorable processability. Herein, this paper reviews recent advances of MXene-based fibers. Speaking to MXene dispersions, the properties of MXene dispersions including dispersion stability, rheological properties and liquid crystalline properties are highlighted. The preparation techniques used to produce MXene-based fibers and application progress regarding MXene-based fibers into supercapacitors, sensors, EMI shielding and Joule heaters are summarized. Challenges and prospects surrounding the development of MXene-based fibers are proposed in future. This review aims to provide processing guidelines for MXene-based fiber manufacturing, thereby achieving more possibilities of MXene-based fibers in advanced applications with a view to injecting more vitality into the field of smart wearables.

2.
Int J Pharm ; 642: 123171, 2023 Jul 25.
Artículo en Inglés | MEDLINE | ID: mdl-37356509

RESUMEN

Quality issues related to compressed oral solid dosage (OSD) forms, such as tablets, arise during the design, development, and production stages, despite established processes and robust production tools. One of the primary quality concerns is the disintegration properties and drug release profile of immediate-release OSD products, which depend on their micro-texture and micro-viscoelastic properties at the grain level. These properties are influenced by the composition of the formulation, particularly the disintegrant level in the tablet matrix and the porosity of the matrix. In this study, a novel, rapid, non-destructive ultrasonic characterization technique was proposed to correlate the sensitivity of propagating elastic wave speeds, physical/mechanical properties, and the dispersion profile of the OSD material with the disintegrant level (% w/w) in the formulation and the compression force applied during tableting. The proposed characterization framework involves transmitting pressure (longitudinal) and shear (transverse) waves through the OSDs to calculate the speed of sound, which in turn provides information on the apparent Young's and shear moduli. In addition, the attenuation profile of the propagating wave is obtained through dispersion analysis. To investigate the impact of disintegrants and compression force on ultrasonic wave propagation in OSDs, we incorporated seven levels of a frequently used disintegrant. In each formulation, OSDs are compacted in five compaction forces. The sensitivity of wave speeds, physical/mechanical properties, and attenuation profile was observed with each disintegrant and compression force level. The utilization of ultrasonic techniques may present a viable solution for rapid, non-destructive, non-invasive, and cost-effective testing methods required in continuous manufacturing (CM) and real-time release testing (RTRT), and its practical utility in pharmaceutical manufacturing is also discussed.


Asunto(s)
Excipientes , Fenómenos Mecánicos , Comprimidos , Porosidad , Presión
3.
Biomater Adv ; 134: 112722, 2022 Mar.
Artículo en Inglés | MEDLINE | ID: mdl-35584980

RESUMEN

Metal matrix composites have been recognized as a feasible approach to obtain a new generation of biodegradable Zn-based material. Nevertheless, there is a great challenge in achieving good dispersion properties of the bioactive reinforcements within zinc matrix. A novel and facile approach, namely graphene oxide (GO)-assisted hetero-aggregation, were developed to achieve uniformly dispersed nanoceramics in the Zn matrix, by using very low-content (0.03 vol%) GO as a linker between the Zn matrix and reinforcement. The negatively-charged GO becomes a suitable "bridge" connected the positively-charged metallic powder and bioactive reinforcement by charge neutralization in polarity solvent. Three kinds of reinforcements, including MgO, ZnO and CuO, were used to verify the feasibility of the above-mentioned method. As-sintered 3CuO/Zn matrix composites, which possessed uniformly distributed reinforcement, uniaxial compressive strength of 301.2 MPa, failure strain over 40%, moderate corrosion rate of 0.063 mm·y-1, acceptable cytocompatibility and antibacterial property, should be a useful material for orthopedic applications.


Asunto(s)
Óxido de Zinc , Cobre , Grafito , Óxido de Magnesio , Ensayo de Materiales , Zinc
4.
J Colloid Interface Sci ; 509: 307-317, 2018 Jan 01.
Artículo en Inglés | MEDLINE | ID: mdl-28918373

RESUMEN

Although carbon nanotubes (CNTs) have outstanding physical properties, there are still challenging issues such as poor dispersibility and miscibility between organic polymers and CNTs for polymer nanocomposites. Chemical modifications (e.g., strong acid based oxidation, carboxylation, etc.) can improve dispersion properties and compatibility, but such surface modification methods often lead to damage to the pristine CNT structure and also deteriorate the mechanical properties of CNTs. Here we demonstrate a simple, defect-free and scalable method for well-dispersed CNTs in common organic solvents, using dopamine and amine-terminated polyethylene glycol derivatives. This method makes it possible to prepare solubility-tunable CNTs without any severe structural deformation. As-modified CNTs were successfully characterized by thermal gravimetric analysis (TGA), Fourier-transformed infrared spectroscope (FT-IR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscope (TEM). The surface modified-CNTs were well-dispersed in polar and/or non-polar common solvents. The well-dispersed CNTs can be used in a nanofiller in commercial polymers such as thermoplastic polyurethane (TPU) polymer. The CNT/TPU composite showed improved tensile strength without sacrificing elongation at break relative to those of pristine TPU.

5.
Sheng Wu Yi Xue Gong Cheng Xue Za Zhi ; 34(4): 606-613, 2017 08 25.
Artículo en Chino | MEDLINE | ID: mdl-29745560

RESUMEN

In order to explore the application of the dielectric properties of white matter and grey matter in ß, δ and γ dispersion transition zones used in clinical medicine and microwave imaging technology, we calculated the dielectric constant and its increment by using Cole-Cole equation. Based on the mutation of the increment of dielectric constant, the frequency range of three dispersions were evaluated. The dominate dispersion and the corresponding polarization mechanism were analyzed by using Cole-Cole circle. The results showed that there are 3 transition zones in brain white matter, which occur between ß and δ dispersion, δ and γ dispersion and ß and γ dispersion respectively. In grey matter, there are only 2 transition zones, which are between ß and δ dispersion and δ and γ dispersion respectively. By comparing the frequency range of white matter and grey matter, the frequency range in white matter is broader than that in grey matter for the transition zone of ß and δ dispersion with the ß dispersion occupying dominate position in both tissues, and the corresponding polarization mechanism is interfacial polarization. For the transition zone of δ and γ dispersion, the frequency range in white matter is also broader than that in grey matter with the δ dispersion occupying dominate position in both tissues, and the corresponding polarization mechanism is orientation polarization. This study can provide basic theory and reference for diagnosis of brain diseases and microwave imaging technology.

6.
Nanoscale Res Lett ; 11(1): 116, 2016 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-26925864

RESUMEN

Nanostructure porous films with arrays of gold nanoparticles (Au NPs) have been produced by pulsed laser deposition. Dispersion properties of surface plasmons have been studied by the modulation-polarization spectroscopy technique. The dispersion relations for radiative modes and two types of non-radiative modes of localized and propagating surface plasmons were obtained. The branches of propagating modes were characterized by negative group velocity caused by spatial dispersion of dielectric function. The propagating modes are caused by dipole-dipole interactions between adjacent Au NPs. The frequencies and relaxation parameters of surface plasmon resonances and the plasma frequencies for Αu NPs were obtained. The relation between the surface plasmon's properties and formation conditions of films with arrays of Αu NPs is discussed.

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