RESUMEN
The synthesis of materials with a multicomponent hierarchical structure is an essential strategy for achieving high-performance electromagnetic wave (EMW) absorption. However, conventional design strategies face challenges in terms of the rational construction of specific architecture. In this study, we employ a combined space-restricted and hierarchical construction strategy to surface-plant MoS2 nanosheets on yolk-shell structural carbon-modified Co-based composites, leading to the development of high-performance Co/NC@void@C@MoS2 absorbers with advanced architecture. The surface-planted MoS2 nanosheets, the Co/NC magnetic yolk, and the dielectric carbon shell work together to enhance the impedance matching characteristics and synergistic loss capabilities in the composites. Experimental results indicate that Co/NC@void@C-700@MoS2 exhibited the best absorption performance with an effective absorption bandwidth of 7.54 GHz (at 2.05 mm) and a minimum reflection loss of -60.88 dB (at 1.85 mm). Furthermore, radar cross-section simulation results demonstrate that Co/NC@void@C-700@MoS2 effectively suppresses the scattering and transmission of EMWs on perfect electric conductor substrates, implying its superior practical application value. This study provides inspiration and experimental basis for designing and optimizing EMW absorption materials with hierarchical yolk-shell architecture.
RESUMEN
Recently, microwave absorption (MA) materials have attracted intensive research attention for their ability to counteract the effects of ever-growing electromagnetic pollution. However, conventional microwave absorbers suffer from complex fabrication processes, poor stability and different optimal thicknesses for minimum reflection loss (RLmin) and widest effective absorption bandwidth (EAB). To address these issues, we have used electrospinning followed by high-temperature annealing in argon to develop a flexible microwave absorber with strong wideband absorption. The MA properties of the carbon nanofibers (CNFs) can be tuned by adjusting annealing temperature, and are dependent on the composition and microstructure of the CNFs. The absorber membrane obtained at 800 °C consists of Fe0.64Ni0.36@graphite core-shell nanoparticles (NPs) embedded in CNFs, formed via a corrosion-like transformation from NiFe2O4 to Fe0.64Ni0.36 followed by surface graphitization. This nanostructure greatly enhances magnetic-dielectric synergistic loss to achieve superior MA properties, with an RLmin of -57.7 dB and an EAB of 6.48 GHz (11.20-17.68 GHz) both acquired at a thickness of 2.1 mm. This work provides useful insights into structure-property relationship of the CNFs, sheds light on the formation mechanism of Fe0.64Ni0.36@graphite NPs, and offers a simple synthesis route to fabricate light-weight and flexible microwave absorbers.