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In this article, the application of a polymer film containing the ionic liquid Cyphos IL 101 for the simultaneous recovery of precious and heavy metal ions ((Ni(II), Zn(II), Co(II), Cu(II), Sn(II), Pb(II), Ag(I), Pd(II), and Au(III)) from waste electrical and electronic equipment (WEEE) is described. The experiments were performed for solutions containing metal ions released from computer e-waste due to leaching carried out with concentrated nitric(V) acid and aqua regia. It was found that the applied polymer film allows for the efficient recovery of precious metals (98.9% of gold, 79.3% of silver, and 63.6% of palladium). The recovery of non-ferrous metals (Co, Ni, Cu, Zn, Sn, and Pb) was less efficient (25-40%). Moreover, the results of the performed sorption/desorption processes show that the polymer film with Cyphos IL 101 can be successfully used after regeneration to recover metals ions several times.

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Reactive dyes are highly soluble in water, and carcinogenic. Therefore, it is essential to remove these dyes from their aqueous solutions. This study focused on the simultaneous removal of reactive orange 16 (RO) and reactive green 19 (RG) dyes from their binary dye solution using Cyphos IL101-impregnated Amberlite XAD7HP resin (ILX7) in batch and recirculating stirrer vessel (RSV). In the batch study, the experimental operating conditions were designed by using central composite design of response surface methodology. Influence of important input variables (RO dye concentration, RG dye concentration, pH, and resin dosage) on the dye adsorption was studied and their values were optimized. At the optimum values of input variables, equilibrium, kinetic, and thermodynamic studies were performed for the binary dye mixture. The equilibrium and kinetic adsorption data were best fitted with extended-Freundlich and pseudo-second-order models, respectively. Now to intensify the process, continuous studies were performed in a RSV at optimum conditions and at different flow rates and stirring speeds. The impregnated resin was regenerated by using 80% v/v ethanol and successfully reused up to 3 cycles with slight decrease in the adsorption capacity.

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A poly(vinylidene fluoride-co-hexafluoropropylene)-based polymer inclusion membrane (PIM) using Cyphos® IL 101 (i.e. trihexyl(tetradecyl)phosphonium chloride) as the carrier and 2-nitrophenyl octyl ether as a plasticizer in a mass ratio of 55/35/10 was employed for the on-line extractive separation of V(V) prior to its spectrophotometric determination in a flow injection analysis (FIA) system using xylenol orange as the colorimetric reagent. The selectivity of the membrane allowed the determination of V(V) in sulfate solutions in the presence of a variety of cations and anions. The interference of molybdenum(VI) was eliminated by off-line extraction using the same PIM. A univariate sequential optimization of the newly developed FIA system was conducted and under optimal conditions the system is characterized by a linear concentration range of 0.5-8.0mgL-1, detection limit of 0.08mgL-1 and sample throughput of 4h-1. The relative standard deviation at the 3mgL-1 level of V(V) was 2.9% based on 8 replicate determinations. The membrane was stable, which was reflected by the standard deviation value for determinations over three consecutive days (24 determinations of 3mgL-1 V(V)) of 3.6%. The newly developed FIA system was applied to the determination of V(V) in water and dietary supplements samples and a good agreement with inductively coupled plasma optical emission spectrometry was observed.

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The aim of this work is to investigate extraction of ruthenium(III) from acidic aqueous solutions with phosphonium ionic liquids such as trihexyl(tetradecyl)phosphonium chloride (Cyphos IL 101), trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate (Cyphos IL 104) and tributyl(tetradecyl)phosphonium chloride (Cyphos IL 167) as extractants. The influence of HCl content in the feed solutions on extraction of Ru(III) was investigated. The research was performed for model solutions containing Ru(III) and a mixture of waste solutions containing Ru(III) and Rh(III). In addition, investigation of the type of extractant and its concentration in the organic phase on extraction of Ru(III) was carried out. Co-extraction of protons to the organic phase was determined. To the best of our knowledge, the extraction of Ru(III) with Cyphos IL 167 (tributyl(tetradecyl)phosphonium chloride) as an extractant has not yet been described in the scientific literature.

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Facilitated transport through polymer inclusion membranes (PIMs) is a promising method for simultaneous separation and removal of valuable and toxic metal ions from aqueous solutions. Recently, ionic liquids (ILs) have been used as extracting agents for metal ions due to their unique physicochemical properties. This paper presents research on the facilitated transport of cadmium(II) and copper(II) ions from aqueous chloride solutions through PIMs with phosphonium ILs as new selective ion carriers. Cellulose triacetate membranes containing o-nitrophenyl octyl ether (ONPOE) as a plasticizer and Cyphos IL 101 [trihexyl(tetradecyl)phosphonium chloride] or Cyphos IL 104 [trihexyl(tetradecyl)phosphonium bis(2,4,4-trimethylpentyl)phosphinate] as the ion carriers have been prepared and applied for investigations. Cd(II) ions were transported preferably from hydrochloric acid solutions containing Cu(II) ions through the PIMs. Higher selectivity coefficient of Cd(II) over Cu(II) (SCd/Cu) from 0.1 mol·dm-3 hydrochloric acid was obtained for PIM with Cyphos IL 104 as the ion carrier. The influence of HCl and NaCl concentrations in the source phase on metal ion transport across PIM doped with Cyphos 104 was studied. It was found that the initial fluxes of Cd(II) and Cu(II) increase with increasing chloride ions concentration in the source phase. The selectivity coefficient for Cd(II) over Cu(II) decreases with increasing HCl concentration in the source phase. The results suggest that the separation system presented in this paper can be useful for the removal of Cd(II) from acidic chloride solutions in the presence of Cu(II).

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A simple and green technique named polymer-supported ionic liquid solid phase extraction (PSIL-SPE) was developed for mercury (Hg) species determination. Inorganic Hg (InHg) species was complexed with chloride ions followed by its introduction into a flow injection on-line system to quantitatively retain the anionic chlorocomplex (HgCl4(2-)) in a column packed with CYPHOS(®) IL 101-impregnated resin. The trapped InHg was then reduced with stannous chloride (SnCl2) and eluted with the same flow of reducing agent followed by cold vapor atomic absorption spectrometry (CV-AAS) detection. Organic mercury species (OrgHg) did not interact with the impregnated resin and were not retained into the column. Total concentration of OrgHg was evaluated by difference between total Hg and InHg concentration. A 95% extraction efficiency was achieved for InHg when the procedure was developed under optimal experimental conditions. The limit of detection obtained for preconcentration of 40 mL of sample was 2.4 ng L(-1) InHg. The relative standard deviation (RSD) was 2.7% (at 1 µg L(-1) InHg and n=10) calculated from the peak height of absorbance signals (Gaussian-shape and reproducible peaks). This work reports the first polymer-supported IL solid phase extraction approach implemented in a flow injection on-line system for determination of Hg species in mineral, tap and river water samples.

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