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Adsorption-desorption experiments of three heavy metal ions (i.e., lead, copper, cadmium) in silty soil were carried out at different temperatures, and the microscopic characteristics of silty soil loaded with the three heavy metal ions were analyzed. A one-dimensional soil column was used to discuss the influences of heavy metal ion types and concentrations on the soil moisture distribution and the migration level of different heavy metal ions, especially during the dynamic change process from an unsaturated state to a saturated state. Studies show that the adsorption of heavy metal ions onto silty soil is closely related to the mineral composition and functional groups in silty soil. In addition to physical adsorption, the adsorption of heavy metal ions is closely related to the hydrolysis reaction of mineral components such as kaolinite, calcite, dolomite, plagioclase and quartz. Under constant temperature, the types and concentrations of heavy metal ions play an important role in the moisture migration of unsaturated soil. In the presence of heavy metal ions, the penetration of lead ions is the greatest, followed by copper ions and then cadmium ions. The greater the ion concentration is, the stronger the penetration of heavy metal ions in silty soils.

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With the increasing requirement of maintaining world energy security and strategic reserves, oil storage and transportation facilities are being built at a large scale. Taking the safe and efficient operation of petroleum storage projects as the goal, a set of experimental apparatus to investigate the migration of contaminants in fractures filled with media was developed to predict and evaluate the environmental risk of oil contaminants leakage. A multiphase numerical flow model based on COMSOL was built based on the laboratory experimental model. Specifically, the migration behaviour of Light Non-aqueous Phase Liquid (LNAPL) through a sand-filled fractured medium was studied by laboratory experiments and numerical simulations. Image and chemical analyses methods were used to monitor and study LNAPL migration behaviour for varying grain sizes of porous medium filling the fractures and varying groundwater table elevations. Laboratory experimental results showed that the LNAPL migration velocity in filled fracture network was significantly faster than that in adjoining porous media during the initial stage of infiltration. The migration velocity increased with the relative permeability of filled sand, which was closely related to the Van Genuchten (VG) model parameters α and n. LNAPL migrated downward with the falling groundwater table and became entrapped with the rising groundwater table, and the amount of entrapment depended on VG model parameters. Hydrogeological parameters were calibrated and LNAPL migration in filled fractured media was predicted using the calibrated numerical model. Simulation results revealed that fracture inclination had an important influence on LNAPL migration in filled fractured media and its migration velocity decreased with a decrease in fracture inclination. These research results can be applied to the control and remediation of oil-contaminated sites in fractured rock settings, such as at underground oil storage tanks and caverns, as well as at underground oil pipelines.

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The presence of microplastics (MPs) has been recognized as a significant environmental threat due to adverse effects spanning from molecular level, organism health, ecosystem services to human health and well-being. MPs are complex environmental contaminants as they bind to a wide range of other contaminants. MPs associated contaminants include toxic chemical substances that are used as additives during the plastic manufacturing process and adsorbed contaminants that co-exist with MPs in aquatic environments. With the transfer between the water column and sediments, and the migration within aquatic systems, such contaminants associated MPs potentially pose high risk to aquatic systems. However, only limited research has been undertaken currently to link the environmental risk associated with MPs occurrence and movement behaviour in aquatic systems. Given the significant environmental risk and current knowledge gaps, this review focuses on the role played by the abundance of different MP species in water and sediment compartments as well as provides the context for assessing and quantifying the multiple risks associated with the occurrence and movement behaviour of different MP types. Based on the review of past literature, it is found that the physicochemical properties of MPs influence the release/sorption of other contaminants and current MPs transport modelling studies have primarily focused on virgin plastics rather than aged plastics. Additionally, risk assessment of contaminants-associated MPs needs significantly more research. This paper consolidates the current state-of-the art knowledge on the source to sink movement behaviour of MPs and methodologies for assessing the risk of different MP species. Moreover, knowledge gaps and emerging trends in the field are also identified for future research endeavours.

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Tiny plastic particles considered as emerging contaminants have attracted considerable interest in the last few years. Mechanical abrasion, photochemical oxidation and biological degradation of larger plastic debris result in the formation of microplastics (MPs, 1 µm to 5 mm) and nanoplastics (NPs, 1 nm to 1000 nm). Compared with MPs, the environmental fate, ecosystem toxicity and potential risks associated with NPs have so far been less explored. This review provides a state-of-the-art overview of current research on NPs with focus on currently less-investigated fields, such as the environmental fate in agroecosystems, migration in porous media, weathering, and toxic effects on plants. The co-transport of NPs with organic contaminants and heavy metals threaten human health and ecosystems. Furthermore, NPs may serve as a novel habitat for microbial colonization, and may act as carriers for pathogens (i.e., bacteria and viruses). An integrated framework is proposed to better understand the interrelationships between NPs, ecosystems and the human society. In order to fully understand the sources and sinks of NPs, more studies should focus on the total environment, including freshwater, ocean, groundwater, soil and air, and more attempts should be made to explore the aging and aggregation of NPs in environmentally relevant conditions. Considering the fact that naturally-weathered plastic debris may have distinct physicochemical characteristics, future studies should explore the environmental behavior of naturally-aged NPs rather than synthetic polystyrene nanobeads.

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The Hazaribagh tannery area of Bangladesh is currently facing an enormous problem regarding the harmful impacts of wastewater produced from leather industries on the surrounding environment due to the presence of contaminants at a toxic level. As such, the current study aims to analyze the entrapment of tannery wastewater's pollutants inside the mortar specimens for sustainability. Two types of binding agents such as Portland Composite Cement (PCC) and Ready Mixed Dry Mortar (RMDM) were employed to prepare separate mortar pastes in which the collected tannery wastewater was used as mixing liquid. Also, five types of samples including brick walls made with only the PCC, where tiles walls and blocks constructed with both types of binding agents were built. Analytical results show that the surrogate contaminated water mixed mortar blocks possessed about 6-14% lower compressive strength than that of the blocks prepared with drinking water. Moreover, the examined heavy metals were observed below the limit of detection in the curing liquid of studied tiles walls during the whole test protocol of 360 days period. The explicit outcomes of this study might be a promising solution to minimize the effects of tannery wastewater contaminants on the environment by utilizing this wastewater as a mixing component in the tiles fixing mortar of walls and floors.

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Volatile contaminants may migrate with carbon dioxide (CO2) injection or leakage in subsurface formations, which leads to the risk of the CO2 storage and the ecological environment. This study aims to develop an analytical model that could predict the contaminant migration process induced by CO2 storage. The analytical model with two moving boundaries is obtained through the simplification of the fully coupled model for the CO2-aqueous phase -stagnant phase displacement system. The analytical solutions are confirmed and assessed through the comparison with the numerical simulations of the fully coupled model. Then, some key variables in the analytical solutions, including the critical time, the locations of the dual moving boundaries and the advance velocity, are discussed to present the characteristics of contaminant migration in the multi-phase displacement system. The results show that these key variables are determined by four dimensionless numbers, Pe, RD, Sh and RF, which represent the effects of the convection, the dispersion, the interphase mass transfer and the retention factor of contaminant, respectively. The proposed analytical solutions could be used for tracking the migration of the injected CO2 and the contaminants in subsurface formations, and also provide an analytical tool for other solute transport in multi-phase displacement system.

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INTRODUCTION: This study focused on using analytical and numerical models to develop and manage groundwater resources, and predict the effects of management measurements in the groundwater system. Movement of contaminants can be studied based on groundwater flow characteristics. This study can be used for prediction of ion concentration and evaluation of groundwater pollution as the theoretical basis. CASE DESCRIPTION: The Yimin open-pit mine is located in the northern part of the Inner Mongolia Autonomous Region of China. High concentrations of iron and manganese are observed in Yimin open-pit mine because of exploitation and pumping that have increased the concentration of the ions in groundwater. In this study, iron was considered as an index of contamination, and the solute model was calibrated using concentration observations from 14 wells in 2014. DISCUSSION AND EVALUATION: The groundwater flow model and analytical solutions were used in this study to forecast pollution concentration and variation trend after calibration. With continuous pumping, contaminants will migrate, and become enriched, towards the wellhead in the flow direction. The concentration of the contaminants and the range of pollution increase with the flow rate increased. CONCLUSIONS: The suitable flow rate of single well should be <380 m/day at Yimin open-pit for the standard value of pollution concentration.