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Biomaterials like chitosan, hydroxyapatite have been used in biomedical and pharmaceutical field, due to its valuable biochemical and physiological properties. In current work firstly our group has isolated a polysaccharide chitosan along with hydroxyapatite biomaterial from the same source by varying the process condition via greener approach. We have adapted greener approach for the isolation of chitosan within a short period of time and this is the very first report for the isolation of both chitosan and hydroxyapatite simultaneously from the same waste edible garden snail shells. Both these materials were thoroughly characterized by using UV, FT-IR, SEM techniques. Among synthetic colourants, congo red dye is recognized as carcinogens, which are usually used in the textile manufacturing. Interestingly, one of our biomaterial hydroxyapatite has shown good selectivity towards Congo red dye. The sensitivity range was obtained from 10 to 100 µM within the LOD of 101.52 nM. The developed sensor has been tested for various industrial effluents and shown good agreement with our results. Meanwhile these chitosan and hydroxyapatite have also been used as capping agent for the preparation of stable gold nanoparticles.

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In recent times, the application of biochar (BC) as an upcoming catalyst for the elimination of recalcitrant pollutants has been widely explored. Here, an iron loaded bamboo biochar activated peroxymonosulphate (PMS) process was tested for removing Congo red (CR) dye from water medium. The catalyst was synthesized using a green synthesis method using neem extracts and characterized using SEM, FTIR, and XRD. The effects of various operating parameters, including solution pH, catalyst dosage, and pollutant dosage, on dye degradation efficiency were examined. The results showed that at the optimized conditions of 300 mg L-1 PMS concentration, 200 mg L-1 catalyst dosage, and pH 6, about 89.7% of CR dye (initial concentration 10 ppm) was removed at 60 min of operation. Scavenging experiments revealed the significant contribution of O2•-, •OH, and 1O2 for dye degradation, with a major contribution of O2•-. The activation of PMS was mainly done by biochar rather than iron (loaded on biochar). The catalyst was highly active even after four cycles.

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In the present investigation of copper ferrite, a CuFe2O4 nanocomposite adsorbent was synthesized using the sol-gel method, and its relevance in the adsorptive elimination of the toxic Congo red (CR) aqueous phase was examined. A variety of structural methods were used to analyze the CuFe2O4 nanocomposite; the as-synthesized nanocomposite had agglomerated clusters with a porous, irregular, rough surface that could be seen using FE-SEM, and it also contained carbon (23.47%), oxygen (44.31%), copper (10.21%), and iron (22.01%) in its elemental composition by weight. Experiments were designed to achieve the most optimized system through the utilization of a central composite design (CCD). The highest uptake of CR dye at equilibrium occurred when the initial pH value was 5.5, the adsorbate concentration was 125 mg/L, and the adsorbent dosage was 3.5 g/L. Kinetic studies were conducted, and they showed that the adsorption process followed a pseudo-second-order (PSO) model (regression coefficient, R2 = 0.9998), suggesting a chemisorption mechanism, and the overall reaction rate was governed by both the film and pore diffusion of adsorbate molecules. The process through which dye molecules were taken up onto the particle surface revealed interactions involving electrostatic forces, hydrogen bonding, and pore filling. According to isotherm studies, the equilibrium data exhibited strong agreement with the Langmuir model (R2 = 0.9989), demonstrating a maximum monolayer adsorption capacity (qmax) of 64.72 mg/g at pH 6 and 302 K. Considering the obtained negative ΔG and positive ΔHads and ΔSads values across all tested temperatures in the thermodynamic investigations, it was confirmed that the adsorption process was characterized as endothermic, spontaneous, and feasible, with an increased level of randomness. The CuFe2O4 adsorbent developed in this study is anticipated to find extensive application in effluent treatment, owing to its excellent reusability and remarkable capability to effectively remove CR in comparison to other adsorbents.

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Ecologically inspired to develop silver, gold and silver/gold bimetallic nanoparticles from discarded orange peel extract. The plant-derived compounds included in discarded orange peel extract have been accountable for the development of Ag, Au and Ag-Au bimetallic nanoparticles, that might be used in the biosynthetic process. The qualitative assessment of developed silver, gold and silver/gold bimetallic nanoparticles has been performed by UV-visible, XRD pattern, FT IR analysis, TEM/HRTEM, EDX and BET isotherm analysis. In this investigation, the photocatalytic effect of developed silver, gold and silver/gold bimetallic nanoparticles on Congo red dye breakdown efficiency was achieved at 96%, 94%, and 99.2%, respectively. Due to prolonged electron-hole recombination process was investigated using UV irradiation and reused for up to 5 consecutive runs without significant loss of photocatalytic activity. Moreover, silver, gold, and silver/gold bimetallic nanoparticles manufactured in an environmentally benign manner could potentially contribute to the ecological cleanup.

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In our previous work, three different weight ratios of chitosan/PVA (1:3, 1:1, and 3:1) were blended and then cross-linked with trimellitic anhydride isothiocyanate (TAI) at a concentration depending on their chitosan content, obtaining three hydrogels symbolized by H13, H11, and H31. Pure chitosan was cross-linked with TAI, producing a hydrogel symbolized by H10. Further, three H31-based silver nanoparticles composites (H31/AgNPs1%, H31/AgNPs3%, and H31/AgNPs5%) were also synthesized. They were investigated, for the first time in this study, as adsorbents for Congo Red (CR) and Crystal Violet (CV) dyes. The removal efficiency of CR dye increased with increasing H10 content in the hydrogels, and with increasing AgNP content in the composites, reaching 99.91% for H31/AgNPs5%. For CV dye, the removal efficiency increased with the increase in the PVA content. Furthermore, the removal efficiency of CV dye increased with an increasing AgNP content, reaching 94.7% for H31/AgNPs5%. The adsorption capacity increased with the increase in both the initial dye concentration and temperature, while with an increasing pH it increased in the case of CV dye and decreased in the case of CR dye. The adsorption of CV dye demonstrated that the Freundlich isotherm model is better suited for the experimental results. Moreover, the results were best fitted with pseudo-second-order kinetic model.

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Presence of colors, organic surface finishing agents and surfactants in textile industry effluent makes it highly detrimental for surrounding environment. Hence the effluent from textile industry needs treatment for removal of these colors, organic and inorganic components before its disposal. Hence applicability of low cost and environmental friendly biosorbents, Azospirillium biofertilizer and Rhizobium biofertilizer were investigated for removal of Congo red dye. Batch experimentation was carried out to check operating parameters like, temperature, dose of adsorbent, pH, agitation speed, contact time and initial concentration. The biosorption capacity for Congo red dye was 67.114 and 101.01 mg/g, for Azospirillium biofertilizer and Rhizobium biofertilizer, respectively at optimized parameters. RL factor was 0.558 and 0.568 for Azospirillium biofertilizer and Rhizobium biofertilizer. The data showed combination of interaction-based separation through better fitting of Langmuir isotherm compared to Freundlich. Its separation is well described by Pseudo-second order and intraparticle diffusion model. Adsorption was favorable at lower temperature suggesting exothermic and spontaneous nature. Reusability for Azospirillium biofertilizer and Rhizobium biofertilizer was checked for 25 mg/land. While the biological nature of Azospirillium and Rhizobium biofertilizer makes removal of Congo red dye environmentally benign.

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The present research is targeted at E. cardamomum-derived TiO2-photocatalyst synthesis, reporting for the first time. The structural properties observed from the XRD pattern reveal that EC:TiO2 has an anatase phase and crystallite size is assessed by Debye-Scherrer's method (3.56 nm), WH-method (3.30 nm), and Modified-Debye-Scherrer's method (3.27 nm). An optical study by the UV-Vis spectrum shows strong absorption at 313 nm, and the corresponding band gap value is 3.28 eV. The topographical and morphological properties revealed by SEM and HRTEM images, elucidate the formation of multi-shaped particles of nano-size. Further, the phytochemicals on the EC:TiO2 NPs' surface are confirmed by the FTIR spectrum. The photocatalytic activity is well studied under UV light towards Congo Red dye, along with an effect of the dose of catalyst. EC:TiO2 (20 mg) has exhibited high photocatalytic efficiency up to 97% for 150 min of exposure due to the morphological, structural, and optical properties. CR degradation reaction exhibits pseudo-first-order kinetics, displaying a rate constant value of 0.01320 min-1. Reusability investigations reveal that after four photocatalysis cycles, EC:TiO2 has an effective efficiency of >85%. Additionally, EC:TiO2 NPs have been assessed for antibacterial activity and show potential against two bacterial species (S. aureus and P. aeruginosa). Therefore, these research outcomes from the eco-friendly and low-cost synthesis, are promising for the use of EC:TiO2 as a talented photocatalyst towards the removal of crystal violet dye as well as an antibacterial agent against bacterial pathogens.

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Synthetic dyes are considered toxic compounds and as such are not easily removed by conventional water treatment processes. This study demonstrated the synthesis of pure and manganese- (Mn), silver- (Ag), and iron- (Fe) doped zinc oxide (ZnO) nanoparticles via the wet chemical route. In particular, it investigated the batch adsorption studies and physiochemical properties of synthesized pure and doped ZnO materials for removing toxic congo red (CR) dye. X-ray diffraction (XRD), Raman spectroscopy, and energy-dispersive X-ray spectroscopy (EDS) confirmed the synthesis of the pure and doped ZnO materials. The batch adsorption investigation revealed adsorption efficiencies of 99.4% for CR dye at an optimal dose of 0.03 g/30 ml for Mn-doped ZnO at a solution pH of 2. The adsorption capacity of each of the synthesized materials was found to be in order Mn-doped ZnO (232.5 mg/g) > Ag-doped ZnO (222.2 mg/g) > pure ZnO (212.7 mg/g) > Fe-doped ZnO (208.3 mg/g). Both pseudo-second-order kinetics model and the Langmuir isotherm model accurately explained the adsorption behaviors of CR dye. As such, Van der Waal interactions, H-bonding, and electrostatic interaction were found to be the adsorption mechanisms responsible for dye removal. In addition, the desorption-regeneration investigation indicated the successful reuse of the exhausted Mn-doped ZnO material for five cycles of CR dye adsorption with an efficiency of 83.1%. Overall, this study has demonstrated that Mn-doped ZnO could be considered a viable adsorbent for the cleanup of dye-contaminated water.

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Copper oxide nanocarriers have attracted increasing interest in the scientific community, including antimicrobial applications. Candida biofilm developed causes serious clinical problems, leading to drug failure caused by its inherent drug tolerance. Nanocarriers are a good alternative approach to solving this challenge because of their excellent penetration power inside biofilms. Hence, main objectives of this research were to prepare gum arabic-embedded L-cysteine-capped copper oxide nanocarriers (GCCuO NCs) and tested against C. albicans and explore another application. To achieve the main research objectives, GCCuO NCs were synthesized and investigated for antibiofilm potency against C. albicans. Various methods were employed to measure antibiofilm potency such as biofilm assay etc., of NCs. The nano size of GCCuO NCs is advantageous for augmenting penetration power and retention into biofilms. GCCuO NCs at 100 µg/mL exhibited significant antibiofilm activity against the C. albicans DAY185 by switching of yeast-to-hyphae and gene perturbation. The level of CR dye adsorption was 58.96 % using 30 µg/mL of NCs. Based on effective C. albicans biofilm inhibition and CR dye adsorption capacity of NCs, it can be suggested that present research work opens an innovative path to treat biofilm-associated fungal infections, and these NCs can be used for environmental remedies.

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The objective of this work was to develop a low-cost and efficient biocarrier for biodegradation of azo dye (i.e., Congo red (CR) dye). The potential bacterial species, i.e., Lysinibacillus fusiformis KLM1 and Lysinibacillus macrolides KLM2, were isolated from the dye-contaminated site. These bacterial species were immobilized onto the polypropylene-polyurethane foam (PP-PUF) and employed in a moving bed biofilm reactor (MBBR) for the treatment of CR dye. The effectiveness of the MBBR was investigated by operating the bioreactor in a continuous mode at various initial CR dye concentrations (50-250 mg/L) for 113 days. The removal efficiency was found in the range of 88.4-64.6% when the initial dye concentration was varied from 50 to 250 mg/L. The maximum elimination capacity (EC) of 213.18 mg/L.d was found at 250 mg/L of CR dye concentration. In addition, the CR dye utilization rate in the MBBR was studied by using two kinetics, namely, first-order and second-order (Grau) models. The high regression coefficients (R2 > 0.97) and the satisfactory root mean square (RMSE) values (0.00096-0.02610) indicated the reasonable prediction of CR dye degradation rate by the Grau model.

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Industrial waste, for instance, textile effluents when released into the ecological system without first being treated or with inappropriate levels of treatment, can lead to serious issues deteriorating the environment and human health. Moreover, solid waste from various industries has also become a major issue due to massive urbanization. For instance, the waste from the metal industry has been rapidly increasing such as Jarosite which has various metals, metal oxides, and silica in its composition. Therefore, Jarosite was utilized as an adsorbent for the adsorption of anionic Congo red (CR) and cationic Methylene blue (MB) dyes from aqueous solutions. The processed adsorbent sample was characterized by BET, XRD, SEM, EDS, FTIR, and XPS techniques. The effects of initial dye concentration, pH, adsorbent dose, temperature, and contact time were examined. The metal industry waste is used as a low-cost abundant adsorbent with great potential for adsorption ability to remove the CR (97.5%) and MB (68.5%) at pH 7, contact time 90 min, adsorbent dose 0.1 g, and initial dye concentration 50 mg/L. The adsorption data followed the adsorption isotherm and Kinetics for both dyes. The removal of both dyes was a physical adsorption process, endothermic and spontaneous reaction. Column adsorption investigation was described by AB (Adams-Bohart) and YN (Yoon-Nelson) models. According to the economic view, the utilization of jarosite for dye removal is a cost-effective approach, because it is collected free of cost from industries. Henceforth, for the first time, toxic metal industry waste was successfully utilized as an adsorbent for wastewater treatment.

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Brass spiral nails were functionalized with CoFe2O4 nanoparticles and utilized as a substrate for the growth of extremely long CNTs with helical structures and diameters smaller than 20 nm. Different methods were used to characterize the grown CNTs' structures and morphologies. The characteristic Raman peaks of CNTs were amplified four times after being uploaded on the spiral nail, making the substrates for surface-enhanced Raman spectroscopy (SERS) more sensitive. To detect Hg2+ and Cd2+ at concentrations ranging from 1 to 1000 ppb, a CNT/spiral brass nail was used as a SERS substrate. The proposed sensor demonstrated high sensitivity and selectivity between these heavy metal ions. As a result, the proposed CNTs/spiral brass sensor can be an effective tool for identifying heavy metal ions in aqueous solutions. In addition, Congo red (CR) adsorption as a function of initial dye concentration and contact time was investigated. For CR dye solutions with concentrations of 5, 10, and 20 mg/L, respectively, the highest removal percentage was determined to be ~99.9%, 85%, and 77%. According to the kinetics investigation, the pseudo-first-order and pseudo-second-order models effectively handle CR adsorption onto CNTs/spiral nails. The increase in the dye concentration from 5 ppm to 20 ppm causes the rate constant to drop from 0.053 to 0.040 min-1. Therefore, our sample can be employed for both the effective degradation of CR dye from wastewater and the detection of heavy metals.

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In this work, five different magnetic biofilters, containing magnetic nanoparticles (142 nm), immobilized laccase on nanoparticles (190 nm) and permanent magnetic elements, such as neodymium magnets and metallic meshes, were designed, manufactured and tested. The five types of filters were compared by measuring the decolorization of Congo Red dye inside bioreactors, the half-life of the filters and the amount of magnetic nanoparticle and enzyme lost during multiple cycles of operation. Filters containing laccase immobilized on magnetite (Laccase-magnetite), permanent magnets and metallic mesh presented the highest Congo Red decolorization (27%) and the largest half-life among all types of filters (seven cycles). The overall dye decolorization efficiencies were 5%, 13%, 17%, 23%, and 27% for the paper filter, paper filter with magnetite, paper filter with Laccase-magnetite, paper filter with Laccase-magnetite with magnets and paper filter with Laccase-magnetite with magnets and metallic mesh, respectively. Although the highest losses of magnetite occurred when using the filters containing magnets (57 mg), the use of permanent magnetic elements in the filters increased the half-life of the filter three-fold compared to the filters without enzymatic properties and two-fold compared to the filters with Laccase-magnetite. Results indicate that the novel use of permanent magnetic elements improved the nanoparticle retention in the filters and promoted the mass transfer between the dye and the biocatalyst to enhance wastewater treatment.

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The silver/palladium nanoparticles (Ag/Pd NPs) were efficiently absorb UV-Visible light and reveal greater photocatalytic activity as compared to monometallic NPs. The aim of this study is photodegradation of the industrial azo dye using bimetallic Ag/Pd NPs and monometallic Ag NPs in presence of UV light for wastewater treatment. Bacillariophyceae (diatom) algae extract was utilized for the green synthesized Ag and Ag/Pd NPs. Biosynthesized nanoparticles were characterized by various useful characterization techniques viz. UV-Vis, FT-IR, SEM, TEM, and XRD. The crystallite size is found to be ∼23 nm and ∼56 nm for Ag NPs and Ag/Pd NPs, respectively, which is same as results obtained from TEM analysis, as the particle size and shape were analyzed as ∼27 and ∼56 nm, with a spherical geometry. The NPs was used to develop the optimization parameters for dye degradation such as time, temperature, and NP concentrations. A total 15 runs were considered for the study and procured by statistical software. Response surface methodology technique was implied and Box-Behnken design (BBD) design was built into the workflow. The results of the present study manifested a good connection between experimental and predicted values (R2 = 0.9838). Therefore, present study promises that the prepared NPs possess excellent photocatalytic activity against harmful dyes.

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This study presents the first known exploration of Congo red dye (CR) adsorption by a polycationic Fe/Al Di-metal nanostructured composite (PDFe/Al) synthesised using Fe(III) and Al(III) recovered from authentic acid mine drainage (AMD). The PDFe/Al successfully removed CR from the aqueous solution. The mineralogical, microstructural, and chemical properties of the synthesised PDFe/Al adsorbent (before and after adsorption) were studied using state-of-the-art analytical instruments. The optimum conditions were observed to be 100 mg·L-1 CR, 1 g of the PDFe/Al in 500 mL adsorbate solution, 20 min of shaking, pH = 3-8, and a temperature of 35 °C. At optimised conditions, the PDFe/Al showed ≥99% removal efficacy for CR dye and an exceptionally high Langmuir adsorption capacity of 411 mg·g-1. Furthermore, a diffusion-limited adsorption mechanism was observed, with two distinct surfaces involved in the adsorption of CR from an aqueous solution. It was determined that the adsorption of CR induced internal strain and deformation within the matrices and interlayers of the PDFe/Al which resulted in a marked increase in the adsorbent pore surface area and pore volume. The remarkably high adsorption capacity could be attributed to the high surface area. A regeneration study showed that the adsorbent could be reused more than four times for the adsorption of CR. The findings from this study demonstrated the feasibility of recovering valuable minerals from toxic and hazardous AMD and demonstrated their potential for the treatment of industrial wastewaters.

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Dyes are an important class of organic pollutants and are well known for their adverse effects on aquatic life and human beings. In this work, an effort has been made to treat the dye-containing wastewater using modified biocarriers in packed bed bioreactors (PBBRs). Lysinibacillus sp. immobilized polyurethane foam combined with activated carbon and sodium alginate was used for the biodegradation of Congo red dye. The optimum values of process time, glucose concentration, and dye concentration were obtained to be 4.0 days, 2.0 g/L, and 50 mg/L, respectively. The maximum dye removal efficiency (RE) of 92.63 % was obtained at the optimized conditions. The continuous PBBR offered a maximum RE and elimination capacity of 90.73% and 10.89 mg/L. d, respectively, at an inlet loading rate of 12 mg/L. d. Moreover, the growth kinetic of Lysinibacillus sp. was well predicted by the Andrew-Haldane model with a regression coefficient of 0.98.

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Novel Uracil-modified chitosan (UCs) adsorbent has successfully been synthesized through a four-step method during which the amino groups of chitosan have been protected, then epoxy nuclei have been incorporated, afterwards the latter have been opened using 6-amino-1,3-dimethyl uracil, and finally the amino groups have been regained via removing the protection. Its structure was checked using FTIR, XRD and SEM techniques. The adsorption capacity of UCs for anionic Congo Red (CR) dye was studied under various conditions. It decreased significantly with increasing the solution pH value and dye concentration, while increased with increasing temperature. The adsorption of UCs for CR dye at different temperatures, solution pH and dye concentrations fitted to the kinetic model of pseudo-second order and Elovich model. The intraparticle diffusion model showed that the adsorption process involves multi-step process. The isotherm of CR dye adsorption by UCs conforms to the Langmuir isotherm model indicating the monolayer nature of adsorption. The maximum monolayer coverage capacity, qmax, was 434.78 mg g-1. Studying the thermodynamic showed that the adsorption of CR dye onto UCs was endothermic as illustrated from the positive value of enthalpy (21.37 kJ mol-1). According to the values of ΔG°, the adsorption process was spontaneous at all selected temperatures. The value of ΔS° showed an increase in randomness for the adsorption of CR dye by UCs. The value of activation energy was 18.40 kJ mol-1.

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In this study, gold nanoparticles (AuNPs) were electrodeposited on samples of a carbon-paste electrode (CPE) with different thicknesses. The prepared AuNPs were characterized using different analysis techniques, such as FTIR, UV-Vis, SEM, EDX, TEM images, and XRD analysis. The fabricated modified electrode AuNPs/CPE was used for the sensitive detection of Congo red (CR) dye. Electrochemical sensing was conducted using square-wave voltammetry (SWV) in a 0.1 M acetate buffer solution at pH 6.5. The proposed sensor exhibited high efficiency for the electrochemical determination of CR dye with high selectivity and sensitivity and a low detection limit of 0.07 µM in the concentration range of 1-30 µM and 0.7 µM in the concentration range of 50-200 µM. The practical application of the AuNPs/CPE was verified by detecting CR dye in various real samples involving jelly, candy, wastewater, and tap water. The calculated recoveries (88-106%) were within the acceptable range.

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Fe3O4 nanospheres (Nsps) and chitosan (Cts)/Fe3O4 Nsps were prepared using a one-pot hydrothermal method and subsequently used as photocatalysts against the degradation of Congo red (CR) dye molecules. The sphere-shaped Fe3O4 nanoparticles were heterogeneously decorated by the Cts matrix, which was confirmed by powder X-ray diffraction, scanning and transmission electron microscopies. The Cts/Fe3O4 Nsps demonstrated 98% efficient photocatalytic activity against CR dye molecules upon 60 min exposure to visible light compared to Fe3O4 Nsps (77% for 60 min). When compared to Fe3O4 Nsps, the visible light photocatalytic efficiency of Cts/Fe3O4 Nsps against CR dye molecules was significantly improved.

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BACKGROUND: Several cross-sectional studies have investigated the incidence of urinary Congo-red dye positivity in women with preeclampsia (PE), compared to unaffected pregnancies, and reported very high sensitivity and low false positive rate in the diagnosis of PE. OBJECTIVE: To determine the performance of the urinary Congo-red dot paper test at 35-37 weeks' gestation in the prediction of delivery with PE at ≤2 and >2 weeks after assessment. METHODS: This was a prospective observational study in women attending for a routine hospital visit at 35+0 to 36+6 weeks' gestation in a maternity hospital in England. Urine samples were collected and the Congo-red dot paper test was used to assess the degree of Congo-red dye positivity. The test uses a scoring system from 1 to 8 and the higher the score the greater the degree of Congo-red dye positivity. We examined and compared the degree of Congo-red dye positivity in the groups that delivered with PE at ≤2 and >2 weeks with those that remained normotensive. Reproducibility was assessed by examining the inter- and intra-observer reliability of scoring on stored images with the researchers blinded to previous results. RESULTS: The study population of 2140 women included 46 (2.1%) that subsequently developed PE (2.1%). The urinary Congo-red dot test was positive in 8.3% (1/12) and 2.9% (1/34) that delivered with PE at ≤2 and >2 weeks from assessment and in 0.2% (4/2094) of the unaffected pregnancies when the cutoff for Congo-red dye positivity was ≥5. The respective values when the cutoff used was ≥3 were 66.7%, 23.5%, and 16.5%, respectively. The intraclass correlation coefficient for the inter-observer reliability was 0.926 (95% CI 0.890-0.953, p<.0001) and Cohen's kappa coefficient for the intra-observer reliability was 0.904, p<.0001. CONCLUSIONS: The performance of the urinary Congo-red dot paper test at 35-37 weeks' gestation in the prediction of PE is very poor.

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