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1.
Sci Rep ; 14(1): 21888, 2024 Sep 19.
Artículo en Inglés | MEDLINE | ID: mdl-39300148

RESUMEN

Freeze-thaw (F-T) cycling poses a significant challenge in seasonally frozen zones, notably affecting the mechanical properties of soil, which is a critical consideration in subgrade engineering. Consequently, a series of unconfined compressive strength tests were conducted to evaluate the influence of various factors, including fiber content, fiber length, curing time, and F-T cycles on the unconfined compression strength (UCS) of fiber-reinforced cemented silty sand. In parallel, acoustic emission (AE) testing was conducted to assess the AE characteristic parameters (e.g., cumulative ring count, cumulative energy, energy, amplitude, RA, and AF) of the same material under F-T cycles, elucidating the progression of F-T-induced damage. The findings indicated that UCS initially increased and then declined as fiber content increased, with the optimal fiber content identified at 0.2%. UCS increased with prolonged curing time, while increases in fiber length and F-T cycles led to a reduction in UCS, which then stabilized after 6 to 10 cycles. Stable F-T cycles resulted in a strength loss of approximately 30% in fiber-reinforced cemented silty sand. Furthermore, AE characteristic parameters strongly correlated with the stages of damage. F-T damage was segmented into three stages using cumulative ring count and cumulative energy. An increase in cumulative ring count to 0.02 × 104 times and cumulative energy to 0.03 × 104 mv·µs marked the emergence of critical failure points. A sudden shift in AE amplitude indicated a transition in the damage stage, with an amplitude of 67 dB after 6 F-T cycles serving as an early warning of impending failure.

2.
Chemosphere ; 365: 143384, 2024 Sep 20.
Artículo en Inglés | MEDLINE | ID: mdl-39306106

RESUMEN

The first investigation based on constructed wetlands coupled with modified basalt fiber bio-nest (MBF-CWs) was performed under exposure of short- and long-chain perfluorocarboxylic acids (PFCAs). In general, both perfluorooctanoic acid (PFOA) and perfluorobutanoic acid (PFBA) caused significant decline of chemical oxygen demand removal by 10.83 % and 4.73 %. However, only PFOA led to marked inhibition on total phosphorus removal by 12.51 % in whole duration. Suppression of removal performance resulted from side impacts on microbes by PFOA. For instance, activities of key enzymes like dehydrogenase (DHA), urease (URE), and phosphatase (PST) decreased by 52.77 %, 40.70 %, and 56.94 % in maximum under PFOA stress, while URE could alleviate over time. By contrast, distinct inhibition was only found on PST in later phases with PFBA exposure. PFCAs had adverse influence on alpha diversity of MBF-CWs, particularly long-chain PFOA. Both PFCAs caused enrichment of Proteobacteria, owing to increase of Gammaproteobacteria and Plasticicumulans by 22.04-35.79 % and 22.91-219.77 %. Nevertheless, some dominant phyla (like Bacteroidota and Acidobacteriota) and genera (like SC-I-84, Thauera, Subgroup_10, and Ellin6067) were only suppressed by PFOA, causing more hazards to microbial decontamination than PFBA did. As for plants, chlorophyll contents tend to decrease with PFOA treatment. Whereas, higher antioxidase activities and more lipid peroxidation products were uncovered in PFOA group, demonstrating more reactive oxygen species brought by long-chain PFCAs. This work offered new findings about ecological effects of MBF-CWs under PFCAs exposure, evaluating stability and sustainability of MBF-CW systems to treat sewage containing complex PFCAs.

3.
Materials (Basel) ; 17(15)2024 Aug 01.
Artículo en Inglés | MEDLINE | ID: mdl-39124462

RESUMEN

Based on mortar composites with a low water-cement ratio, the effects of hybrid aramid fiber (AF), calcium sulfate whisker (CSW), and basalt fiber (BF) on their mechanical properties and wear resistance were studied, and the correlation between wear resistance and compressive strength are discussed. A microstructure analysis was conducted through scanning electron microscopy (SEM) and the nitrogen-adsorption method (BET). The research results show that compared with the control group, the compressive strength, flexural strength, and wear resistance of the hybrid AF, CSW, and BF mortar composites with a low water-cement ratio increased by up to 33.6%, 32%, and 40.8%, respectively; there is a certain linear trend between wear resistance and compressive strength, but the discreteness is large. The microstructure analysis shows that CSW, AF, and BF mainly dissipate energy through bonding, friction, mechanical interlocking with the mortar matrix, and their own pull out and fracture, thereby enhancing and toughening the mortar. A single doping of CSW and co-doping of CSW and AF can refine the pore structure of the mortar, making the mortar structure more compact.

4.
J Hazard Mater ; 478: 135608, 2024 Oct 05.
Artículo en Inglés | MEDLINE | ID: mdl-39180996

RESUMEN

This study addresses the need for high-performance and sustainable air filters by developing a bio-based, high-efficiency particulate air (HEPA) filter. Current HEPA filters often rely on non-biodegradable materials, creating environmental burdens. In this paper, we presented a HEPA filter fabricated from natural basalt fiber (BF) and nanocellulose fiber. The developed filter featured a sandwich structure with electrospun nanocellulose fiber deposited onto a base BF layer, followed by a second BF layer and heat treatment. Various techniques were employed to characterize the obtained sample, and the results showed that the nonwoven BF fabric significantly reduced the pressure drop of the filter by up to 60 %. The nanocellulose fiber played a crucial role in achieving a remarkable filtration efficiency of 99.99 % for PM0.3. BF-based filter demonstrated exceptional fire resistance, hydrophobia, durability, and ease of cleaning, maintaining its effectiveness at temperatures up to 150 °C. Notably, it exhibited significantly better biodegradability than commercially available HEPA filters. By employing a hierarchical structure of sustainable basalt and cellulose fibers, this study paved the way for the development of next-generation hazardous particulate matter filters with exceptional performance in harsh conditions and reduced environmental impact.

5.
Polymers (Basel) ; 16(14)2024 Jul 15.
Artículo en Inglés | MEDLINE | ID: mdl-39065333

RESUMEN

Recycled asphalt pavement (RAP) mixtures are widely adopted due to their significant economic and social benefits from utilizing pavement recycling materials. This study incorporates basalt fibers (BF) and polyester fibers (PF) into plant-mixed hot recycled asphalt mixtures to analyze their enhancement effects on the high-temperature, low-temperature, and fatigue performance at different RAP content levels. Additionally, the study investigates the impact of fiber and RAP additions on the compaction characteristics of the mixtures using gyratory compaction tests, aiming to increase the RAP content of plant-mixed hot recycled asphalt mixtures. Experimental results demonstrate that at 30% and 50% RAP content levels, basalt fibers exhibit more pronounced enhancement effects on the performance of recycled asphalt mixtures compared to polyester fibers. Incorporating basalt fibers increases the fracture energy of recycled asphalt mixtures by 8.63% and 13.9%, and improves fatigue life by 154% and 135%, respectively. Moreover, the addition of both types of fibers increases compaction difficulty, with polyester fibers showing a more significant influence on the compaction energy index (CEI).

6.
Polymers (Basel) ; 16(14)2024 Jul 15.
Artículo en Inglés | MEDLINE | ID: mdl-39065335

RESUMEN

The precast segmental column (PSC) has been proposed for reducing onsite construction time and minimizing impacts on traffic and the environment. It has been proven to have good seismic performance according to previous studies. However, due to the rocking behavior of the column, the toe of the bottom segment could experience excessive compressive damage. In addition, the commonly used steel rebars in the PSC could experience corrosion problems during the service life of the structure. Moreover, ordinary Portland cement concrete (OPC) is normally used in the construction of the PSC, but the manufacturing processes of the OPC could emit a lot of carbon dioxide. This paper investigates the seismic performance of PSCs incorporating Basalt Fiber Reinforced Polymer (BFRP) bars and geopolymer concrete (GPC) segments. To mitigate the concrete crushing damage of the segment, the BFRP sheet was used to wrap the bottom segment of one of the specimens. The results revealed that the BFRP-reinforced geopolymer concrete PSC exhibited good seismic performance with minimal damage and small residual displacement. Strengthening the bottom segment with BFRP wrapping proved to be effective in reducing concrete damage. As a result, the column with BFRP wrap demonstrated the ability to withstand ground motions with higher Peak Ground Acceleration (PGA) compared to the column without strengthening.

7.
Materials (Basel) ; 17(13)2024 Jun 27.
Artículo en Inglés | MEDLINE | ID: mdl-38998233

RESUMEN

Loess has the characteristics of loose, large pore ratio, and strong water sensitivity. Once it encounters water, its structure is damaged easily and its strength is degraded, causing a degree of subgrade settlement. The water sensitivity of loess can be evaluated by permeability and disintegration tests. This study analyzes the effects of guar gum content, basalt fiber content, and basalt fiber length on the permeability and disintegration characteristics of solidified loess. The microstructure of loess was studied through scanning electron microscopy (SEM) testing, revealing the synergistic solidification mechanism of guar gum and basalt fibers. A permeability model was established through regression analysis with guar gum content, confining pressure, basalt fiber content, and length. The research results indicate that the addition of guar gum reduces the permeability of solidified loess, the addition of fiber improves the overall strength, and the addition of guar gum and basalt fiber improves the disintegration resistance. When the guar gum content is 1.00%, the permeability coefficient and disintegration rate of solidified soil are reduced by 50.50% and 94.10%, respectively. When the guar gum content is 1.00%, the basalt fiber length is 12 mm, and the fiber content is 1.00%, the permeability of the solidified soil decreases by 31.9%, and the disintegration rate is 4.80%. The permeability model has a good fitting effect and is suitable for predicting the permeability of loess reinforced with guar gum and basalt fiber composite. This research is of vital theoretical worth and great scientific significance for guidelines on practicing loess solidification engineering.

8.
Materials (Basel) ; 17(13)2024 Jul 01.
Artículo en Inglés | MEDLINE | ID: mdl-38998303

RESUMEN

Fiber-reinforced plywood is a composite material that combines the natural strength and rigidity of plywood with the added durability and resilience provided by reinforcing fibers. This type of plywood is designed to offer improved characteristics over standard plywood, including enhanced strength, stiffness, resistance to impact and moisture, and environmental degradation. By integrating reinforcing fibers, such as glass, carbon, or natural fibers (like flax, bamboo, or hemp) into or onto plywood, manufacturers can create a material that is better suited for applications where traditional plywood might fall short or when a decrease in product weight or savings in wood raw material are necessary. This report reviews the current progress in fiber-reinforced plywood in the context of plywood as a construction material to better understand the potential gains in plywood applications, mechanical parameters, and material savings. It is found that a simple and cost-effective procedure of fiber reinforcement allows for substantial improvements in plywood's mechanical properties, typically to the extent of 10-40%. It is suggested that the wider adoption of fiber-reinforced plywood, especially in load- and impact-bearing applications, would greatly contribute to enhanced durability and longevity of the material while also allowing for more sustainable use of raw wood material.

9.
Materials (Basel) ; 17(13)2024 Jul 02.
Artículo en Inglés | MEDLINE | ID: mdl-38998332

RESUMEN

The external bonding (EB) of fiber-reinforced polymer (FRP) is a usual flexural reinforcement method. When using the technique, premature debonding failure still remains a factor of concern. The effect of incorporating multi-wall carbon nanotubes (MWCNTs) in epoxy resin on the flexural behavior of reinforced concrete (RC) beams strengthened with basalt fiber-reinforced polymer (BFRP) sheets was investigated through four-point bending beam tests. Experimental results indicated that the flexural behavior was significantly improved by the MWCNT-modified epoxy. The BFRP sheets bonded by the MWCNT-modified epoxy more effectively mitigated the debonding failure of BFRP sheets and constrained crack development as well as enhanced the ductility and flexural stiffness of strengthened beams. When the beam was reinforced with two-layer BFRP sheets, the yielding load, ultimate load, ultimate deflection, post-yielded flexural stiffness, energy absorption capacity and deflection ductility of beams strengthened using MWCNT-modified epoxy increased by 7.4%, 8.3%, 18.2%, 22.6%, 29.1% and 14.3%, respectively, in comparison to the beam strengthened using pure epoxy. It could be seen in scanning electron microscopy (SEM) images that the MWCNTs could penetrate into concrete and their pull-out and crack bridging consumed more energy, which remarkably enhanced the flexural behavior of the strengthened beams. Finally, an analytical model was proposed for calculating characteristic loads and characteristic deflections of RC beams strengthened with FRP sheets, which indicated a reasonably good correlation with the experimental results.

10.
Materials (Basel) ; 17(13)2024 Jul 02.
Artículo en Inglés | MEDLINE | ID: mdl-38998335

RESUMEN

To enhance the impact resistance of high-performance concrete (HPC), a novel efficient solution was adopted by incorporating basalt fibers (BF) and polypropylene fibers (PF) as reinforcement materials in this work. To this end, the effects of single BF (BHC) and PF (PHC) as well as their combinations (BPHPC) on the impact energy consumption, ductility ratio, and toughness factor were explored through drop weight impact test of concrete considering fiber volume contents (0.1%, 0.15%, 0.2%) to evaluate the impact resistance of the concrete. The Weibull distribution function model is used to fit the drop weight impact test results and predict the probability of failure. Moreover, the fracture-resistance enhancement mechanism of fiber is analyzed at a microscopic level. Test results showed that the number of impacts resisted by the HPC can follow well the two-parameter Weibull distribution. Compared with the single BF and single PF, the combination of 0.15% BF and 0.1% PF yields favorable impact resistance, thus exhibiting a positive hybrid effect.

11.
Materials (Basel) ; 17(13)2024 Jul 04.
Artículo en Inglés | MEDLINE | ID: mdl-38998380

RESUMEN

Ultra High-Performance Concrete (UHPC) is a cement-based composite material with great strength and durability. Fibers can effectively increase the ductility, strength, and fracture energy of UHPC. This work describes the impacts of individual or hybrid doping of basalt fiber (BF) and steel fiber (SF) on the mechanical properties and microstructure of UHPC. We found that under individual doping, the effect of BF on fluidity was stronger than that of SF. Moreover, the compressive, flexural, and splitting tensile strength of UHPC first increased and then decreased with increasing BF dosage. The optimal dosage of BF was 1%. At a low content of fiber, UHPC reinforced by BF demonstrated greater flexural strength than that reinforced by SF. SF significantly improved the toughness of UHPC. However, a high SF dosage did not increase the strength of UHPC and reduced the splitting tensile strength. Secondly, under hybrid doping, BF was partially substituted for SF to improve the mechanical properties of hybrid fiber UHPC. Consequently, when the BF replacement rate increased, the compressive strength of UHPC gradually decreased; on the other hand, there was an initial increase in the fracture energy, splitting tensile strength, and flexural strength. The ideal mixture was 0.5% BF + 1.5% SF. The fluidity of UHPC with 1.5% BF + 0.5% SF became the lowest with a constant total volume of 2%. The microstructure of hydration products in the hybrid fiber UHPC became denser, whereas the interface of the fiber matrix improved.

12.
Water Sci Technol ; 90(1): 270-286, 2024 Jul.
Artículo en Inglés | MEDLINE | ID: mdl-39007319

RESUMEN

The completely autotrophic nitrogen removal over nitrite (CANON) process is significantly hindered by prolonged start-up periods and unstable nitrogen removal efficiency. In this study, a novel umbrella basalt fiber (BF) carrier with good biological affinity and adsorption performance was used to initiate the CANON process. The CANON process was initiated on day 64 in a sequencing batch reactor equipped with umbrella BF carriers. During this period, the influent NH4+-N concentration gradually increased from 100 to 200 mg·L-1, and the dissolved oxygen was controlled below 0.8 mg L-1. Consequently, an average ammonia nitrogen removal efficiency (ARE) and total nitrogen removal efficiency (TNRE) of ∼90 and 80% were achieved, respectively. After 130 days, ARE and TNRE remained stable at 92 and 81.1%, respectively. This indicates a reliable method for achieving rapid start-up and stable operation of the CANON process. Moreover, Candidatus Kuenenia and Candidatus Brocadia were identified as dominant anammox genera on the carrier. Nitrosomonas was the predominant genus among ammonia-oxidizing bacteria. Spatial differences were observed in the microbial population of umbrella BF carriers. This arrangement facilitated autotrophic nitrogen removal in a single reactor. This study indicates that the novel umbrella BF carrier is a highly suitable biocarrier for the CANON process.


Asunto(s)
Procesos Autotróficos , Reactores Biológicos , Nitritos , Nitrógeno , Nitrógeno/química , Nitritos/química , Eliminación de Residuos Líquidos/métodos , Bacterias/metabolismo
13.
Polymers (Basel) ; 16(10)2024 May 09.
Artículo en Inglés | MEDLINE | ID: mdl-38794523

RESUMEN

This research investigates the mechanical behavior and damage evolution in cross-ply basalt fiber composites subjected to different loading modes. A modified Arcan rig for simultaneous acoustic emission (AE) monitoring was designed and manufactured to apply quasi-isotropic shear, combined tensile and shear loading, and pure tensile loading on specimens with a central notch. Digital image correlation (DIC) was applied for high-resolution strain measurements. The measured failure strengths of the bio-composite specimens under different loading angles are presented. The different competing failure mechanisms that contribute to the local reduction in stress concentration are described. Different damage mechanisms trigger elastic waves in the composite, with distinct AE signatures that closely follow the sequence of fracture mechanisms. AE monitoring is employed to capture signals associated with structural damage initiation and progression. The characteristic parameters of AE signals are correlated with crack modes and damage mechanisms. The evolution of AE parameters during the peak load transition is presented, which enables the timely AE detection of the maximum load transition. The combination of DIC and AE monitoring improves understanding of the mechanical response and failure mechanisms in cross-ply basalt fiber composites, offering valuable insights for possible performance monitoring and structural reliability in diverse engineering applications.

14.
Materials (Basel) ; 17(8)2024 Apr 10.
Artículo en Inglés | MEDLINE | ID: mdl-38673083

RESUMEN

In an effort to appropriately address the insufficient mechanical properties of calcined phosphogypsum, this research intends to explore how to utilize basalt fiber and calcium carbonate whiskers as reinforcing agents. The study delves deep into their impacts on the flexural and compressive strength, toughness, water resistance, and tensile strength of calcined phosphogypsum. In the individual tests, basalt fibers with different lengths (3 mm, 6 mm, 9 mm, and 18 mm) were added at dosages of 0%, 0.5%, 1.0%, and 1.5%, respectively. As clearly demonstrated by the research findings, basalt fiber effectively reinforces the flexural and compressive strength, toughness, and tensile strength of calcined phosphogypsum, though compromising water resistance. Among the various fiber lengths, the 6 mm fibers impose the most advantageous influence on the performance of calcined phosphogypsum. Afterwards, a test was conducted to explore how cross-scale fibers affect the properties of calcined phosphogypsum by mixing 6 mm basalt fibers and calcium carbonate whiskers. As illustrated by the experimental findings, calcium carbonate whisker refines the pores, thereby elevating the flexural strength and toughness of calcined phosphogypsum. Furthermore, it compensates for the water resistance limitations associated with the sole utilization of basalt fiber while further augmenting the tensile strength and strain capacity. Nonetheless, it is particularly noteworthy that heightening the dosage of both calcium carbonate whiskers and basalt fibers concurrently gives rise to augmented porosity of phosphogypsum and lowered compressive strength.

15.
Materials (Basel) ; 17(8)2024 Apr 11.
Artículo en Inglés | MEDLINE | ID: mdl-38673121

RESUMEN

In the context of green and low-carbon development, energy saving, and emission reduction, hot recycling technology (RT) has been researched, which is divided into hot central plant RT and hot in-place RT. However, due to the aged asphalt binders, the shortcomings of hot recycled asphalt mixtures have become apparent, as in comparison to new asphalt mixtures, their resistance to cracking was inferior and the cracking resistance deteriorated more rapidly. Therefore, it was very necessary to focus on the improvement of crack resistance of hot recycled asphalt mixtures. Basalt fiber has been proved to be able to effectively improve the comprehensive road performance of new asphalt mixtures. Therefore, this paper introduced basalt fiber to hot central plant recycled and hot in-place recycled asphalt mixtures, in order to improve the crack resistance of asphalt as a new type of fiber stabilizer. Firstly, six types of SMA-13 fiber asphalt mixtures were designed and prepared, i.e., hot mixtures with basalt fiber or lignin fiber, hot central plant recycled mixtures with basalt fiber or lignin fiber, and hot in-place recycled mixtures with basalt fiber or lignin fiber. Secondly, the trabecular bending test, low-temperature creep test, semi-circular bending test, and IDEAL-CT were used to comparatively study the changing patterns of low and intermediate temperature cracking resistance of hot recycled mixtures with conventional lignin fibers or basalt fibers. Finally, Pearson's correlation coefficient was used to analyze the correlation of the different cracking resistance indicators. The results show that the low and intermediate temperature cracking resistance of hot central plant recycled mixtures increased by 45.6% (dissipative energy ratio, Wd/Ws) and 74.8% (flexibility index, FI), respectively. And the corresponding cracking resistance of hot in-place recycled mixture increased by 105.4% (Wd/Ws) and 55.7% (FI). The trabecular bending test was more suitable for testing the low-temperature cracking resistance of hot recycled asphalt mixtures, while the IDEAL-CT was more suitable for testing the intermediate-temperature cracking resistance. The results can provide useful references for the utilization of basalt fiber in the hot recycling of SMA-13 asphalt mixtures.

16.
Materials (Basel) ; 17(5)2024 Feb 29.
Artículo en Inglés | MEDLINE | ID: mdl-38473599

RESUMEN

In salt lake areas, cast-in situ concrete structures are subjected to long-term corrosion by sulfate and magnesium ions. The properties of concrete can be improved by adding materials like basalt fiber (BF). To investigate the degradation process and mechanism of cast-in situ concrete with premixed BF under the dual corrosion of sulfate and magnesium salts, concrete with a content of BF ranging from 0 to 0.5% was prepared. Specimens were subjected to different internal and external corrosion conditions and immersed for 180 days. Dimension, mass, and appearance changes at different immersion times were recorded. The compressive and flexural strength of the specimens were tested and continually observed throughout the immersion time. Mineral and microstructural changes at different immersion times were determined by the XRD, TG, and SEM analysis methods. Results indicated that external sulfate-internal magnesium combined attack had a significant negative effect on the early strength. The compressive and flexural strength of the corroded specimens decreased by 17.2% and 14.1%, respectively, compared to the control group at 28 days. The premixed magnesium ions caused the decomposition of the C-S-H gel, resulting in severe spalling and lower mechanical properties after immersing for a long time. As the BF can inhibit crack development, the properties of the concrete premixed with BF were improved. Specimens exhibited superior performance at a BF content of 0.5%, resulting in a 16.2% increase in flexural strength. This paper serves as a valuable reference for the application of basalt fiber-reinforced concrete under the challenging conditions of sulfate-magnesium combined attack.

17.
Materials (Basel) ; 17(1)2024 Jan 02.
Artículo en Inglés | MEDLINE | ID: mdl-38204101

RESUMEN

Fly ash-based geopolymers represent a new material, which can be considered an alternative to ordinary Portland cement. MiniBars™ are basalt fiber composites, and they were used to reinforce the geopolymer matrix for the creation of unidirectional MiniBars™ reinforced geopolymer composites (MiniBars™ FRBCs). New materials were obtained by incorporating variable amount of MiniBars™ (0, 12.5, 25, 50, 75 vol.% MiniBars™) in the geopolymer matrix. Geopolymers were prepared by mixing fly ash powder with Na2SiO3 and NaOH as alkaline activators. MiniBars™ FRBCs were cured at 70 °C for 48 h and tested for different mechanical properties. Optical microscopy and SEM were employed to investigate the fillers and MiniBars™ FRBC. MiniBars™ FRBC showed increasing mechanical properties by an increased addition of MiniBars™. The mechanical properties of MiniBars™ FRBC increased more than the geopolymer wtihout MiniBars™: the flexural strength > 11.59-25.97 times, the flexural modulus > 3.33-5.92 times, the tensile strength > 3.50-8.03 times, the tensile modulus > 1.12-1.30 times, and the force load at upper yield tensile strength > 4.18-7.27 times. SEM and optical microscopy analyses were performed on the fractured surface and section of MiniBars™ FRBC and confirmed a good geopolymer network around MiniBars™. Based on our results, MiniBars™ FRBC could be a very promising green material for buildings.

18.
ACS Appl Mater Interfaces ; 16(3): 4045-4055, 2024 Jan 24.
Artículo en Inglés | MEDLINE | ID: mdl-38198227

RESUMEN

The flame-retardant paper has gradually evolved into a necessary material in various industries as a result of the rising importance of fire safety, energy efficiency, and environmental preservation. Traditional cellulose paper requires the addition of a large amount of flame retardants to achieve flame retardancy, which poses a serious threat to mechanical quality and the environment. Therefore, there is an urgent need to develop inorganic fiber flame-retardant paper with good flexibility, high thermal stability, and inherent flame retardancy. Herein, inspired by the "brick-and-mortar" layered structure of nature nacre, we developed a layered composite paper with a unique alternating arrangement of organic-inorganic fibers by synergistically integrating environmentally sustainable basalt fiber (BF) and high-performance aramid nanofibers (ANFs) through a vacuum-assisted filtration process. The as-prepared ANFs/BF composite paper exhibited low thermal conductivity (0.024 W m-1 K-1), high tensile strength (54.22 MPa), and excellent flexibility. Thanks to its excellent thermal stability, the mechanical strength remains at a high level (92%) after heat treatment at 300 °C for 60 min. Furthermore, the peak heat release rate and smoke generation of ANFs/BF composite paper decreased by 44.6 and 95.3%, respectively. Therefore, the composite paper is promising for applications as a protective layer in flexible electronic devices, cables, and fire-retardant and high-temperature fields.

19.
Materials (Basel) ; 16(23)2023 Nov 29.
Artículo en Inglés | MEDLINE | ID: mdl-38068180

RESUMEN

Today's sustainable development policy in Europe, which is driven by concerns about the greenhouse effect and environmental protection, mandates a reduction in CO2 emissions into the atmosphere. The cement industry and steel mills that produce reinforcing bars are among the largest and most emissions-intensive sectors emitting CO2 into the atmosphere. This article analyzes the possibility of achieving significant reductions in CO2 emissions by using basalt bars (BFRP) and glass bars (GFRP) in concrete structures, and-in the case of concrete-by using cement with the addition of metakaolinite and zeolite. There is a lack of literature reports on whether modifying concrete with the additions of metakaolinite and zeolite as substitutes for part of the cement affects the adhesion of FRP bars to concrete. It can be assumed, however, that improving the microstructure of concrete also improves the contact zone between the bar and the concrete. The aim of this research is to fill the aforementioned gap in the literature data by determining how the presence of metakaolinite and zeolite affects the adhesion of reinforcing bars to concrete and testing selected properties of hardened concrete. The test samples were prepared following the appropriate beam test procedure. The obtained results made it possible to perform a comparative analysis of reference samples and those with metakaolinite and zeolite additions. The research showed that introducing active pozzolanic additives in the form of metakaolinite and zeolite into concrete improved adhesion stress values by approximately 20% for glass GFRP bars and 15% for basalt BFRP bars, especially in the destruction phase.

20.
Materials (Basel) ; 16(22)2023 Nov 12.
Artículo en Inglés | MEDLINE | ID: mdl-38005066

RESUMEN

Freeze-thaw (F-T) is one of the principal perils afflicting concrete pavements. A remedial strategy used during construction encompasses the integration of hybrid fibers into the concrete matrix. An extant research gap persists in elucidating the damage mechanism inherent in hybrid steel fiber (SF)- and basalt fiber (BF)-reinforced concrete subjected to F-T conditions. This paper empirically investigated the durability performance of hybrid fiber-reinforced concrete (HFRC) subjected to F-T cycles. The impact of SF/BF hybridization on mass loss, abrasion resistance, compressive strength, flexural strength, damaged layer thickness, and the relative dynamic modulus of elasticity (RDME) was examined. The damage mechanism was explored using micro-hardness and SEM analysis. The results indicate that incorporating hybrid SF/BF effectively enhances the F-T resistance of concrete and prolongs the service life of concrete pavement. The mechanisms underlying these trends can be traced back to robust bonding at the fiber/matrix interface. Randomly dispersed SFs and BFs contribute to forming a three-dimensional spatial structure within the concrete matrix, suppressing the expansion of internal cracks caused by accumulated hydrostatic pressure during the F-T cycle. This research outcome establishes a theoretical foundation for the application of HFRC to concrete pavements in cold regions.

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