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1.
Sci Rep ; 14(1): 1156, 2024 Jan 12.
Artículo en Inglés | MEDLINE | ID: mdl-38212364

RESUMEN

Ensuring privacy of individuals is of paramount importance to social network analysis research. Previous work assessed anonymity in a network based on the non-uniqueness of a node's ego network. In this work, we show that this approach does not adequately account for the strong de-anonymizing effect of distant connections. We first propose the use of d-k-anonymity, a novel measure that takes knowledge up to distance d of a considered node into account. Second, we introduce anonymity-cascade, which exploits the so-called infectiousness of uniqueness: mere information about being connected to another unique node can make a given node uniquely identifiable. These two approaches, together with relevant "twin node" processing steps in the underlying graph structure, offer practitioners flexible solutions, tunable in precision and computation time. This enables the assessment of anonymity in large-scale networks with up to millions of nodes and edges. Experiments on graph models and a wide range of real-world networks show drastic decreases in anonymity when connections at distance 2 are considered. Moreover, extending the knowledge beyond the ego network with just one extra link often already decreases overall anonymity by over 50%. These findings have important implications for privacy-aware sharing of sensitive network data.

2.
J Am Dent Assoc ; 151(8): 614-624.e18, 2020 08.
Artículo en Inglés | MEDLINE | ID: mdl-32718491

RESUMEN

BACKGROUND: The best treatment option for large caries in permanent posterior teeth is still a matter of uncertainty in dental literature. The authors conducted a network meta-analysis to address the challenges related to rehabilitation of these teeth. TYPES OF STUDIES REVIEWED: The authors selected prospective and retrospective studies that compared at least 2 different treatment alternatives for permanent teeth with a minimum of 5 years of follow-up. The authors searched databases from MEDLINE, Scopus, Cochrane Library, and Web of Science in October 2019 without language or year of publication restrictions. RESULTS: From 11,263 studies identified, 43 studies fulfilled the eligibility criteria and were included in the final review. Only 13 studies were randomized controlled trials and were classified as low risk of bias. Gold (annual failure rate of 0.29%) and metal ceramic (annual failure rate of 0.52%) crowns performed better for indirect restorations and direct resin composite performed better for direct restorations (annual failure rate of 2.19%). The most substantial comparisons were between feldspathic and glass ceramics, followed by direct resin composite and amalgam; there were no statistically significant differences between these interventions. Results of the pairwise meta-analysis showed mainly glass ionomer as significantly more prone to failure than amalgam and direct composite resin. CONCLUSIONS AND PRACTICAL IMPLICATIONS: Reference standard direct and indirect materials except for glass ionomer can be used for restorations of large posterior caries.


Asunto(s)
Caries Dental , Restauración Dental Permanente , Resinas Compuestas , Materiales Dentales , Fracaso de la Restauración Dental , Humanos , Estudios Prospectivos , Estudios Retrospectivos
3.
Phys Chem Chem Phys ; 11(23): 4754-60, 2009 Jun 21.
Artículo en Inglés | MEDLINE | ID: mdl-19492129

RESUMEN

Predissociation of electronically excited OH A(2)Sigma(+) (v' = 3) is studied using velocity-map imaging of the atomic oxygen photofragments. Fine structure yields, angular distributions and alignment parameters are obtained for the O((3)P(J)), J = 2,1,0 products. Angular distributions for the O(3)P(0) (J = 0) fragment, which has no angular momentum polarization, agree well with predictions from the angular distribution simulation computer routine by Kim et al. [J. Chem. Phys., 2006, 125, 133316] which calculates the anisotropy of photofragment recoil as a function of dissociation lifetime, excitation frequency, rotational level, and rotational constant. When angular momentum polarization (i.e. non-equilibrium population distributions of the magnetic sublevels) of the atomic fragments is present, the polarization sensitivity of the O((3)P(J)) (2 + 1) resonance enhanced multiphoton ionization (REMPI) detection scheme used to detect the O((3)P(2,1)) products affects the measured angular distribution. Strong polarization effects are observed for the O((3)P(2,1)) products and accounted for in a simple sudden limit model for the photodissociation. In agreement with the sudden limit predictions for pre-dissociation of OH A(2)Sigma(+) (v' = 3) through the (4)Sigma(-) state, strongly aligned O((3)P(2)) is found to be the major product.

5.
J Chem Phys ; 126(9): 094304, 2007 Mar 07.
Artículo en Inglés | MEDLINE | ID: mdl-17362106

RESUMEN

Ultraviolet photodissociation of SH (X 2Pi, upsilon"=2-7) and SD (X 2Pi, upsilon"=3-7) has been studied at 288 and 291 nm, using the velocity map imaging technique to probe the angular and speed distributions of the S(1D2) products. Photodissociation cross sections for the A 2Sigma+<--X 2Pi(upsilon") and 2Delta<--X 2Pi(upsilon") transitions have been obtained by ab initio calculations at the CASSCF-MRSDCI/aug-cc-pV5Z level of theory. Both the experimental and theoretical results show that SH/SD photodissociation from X 2Pi (upsilon"

6.
J Chem Phys ; 126(11): 114314, 2007 Mar 21.
Artículo en Inglés | MEDLINE | ID: mdl-17381213

RESUMEN

The authors present a new potential energy curve, electric dipole moment function, and spin-orbit coupling function for OH in the X 2Pi state, based on high-level ab initio calculations. These properties, combined with a spectroscopically parametrized lambda-type doubling Hamiltonian, are used to compute the Einstein A coefficients and photoabsorption cross sections for the OH Meinel transitions. The authors investigate the effect of spin-orbit coupling on the lifetimes of rovibrationally excited states. Comparing their results with earlier ab initio calculations, they conclude that their dipole moment and potential energy curve give the best agreement with experimental data to date. The results are made available via EPAPS Document No. E-JCPSAG-017709.

7.
Faraday Discuss ; 133: 43-50; discussion 83-102, 449-52, 2006.
Artículo en Inglés | MEDLINE | ID: mdl-17191441

RESUMEN

We investigate the contribution made by Raman scattering to the formation of molecular hydrogen in astrophysical environments characteristic of the early stages of the evolution of the universe. In the Raman process that we study, a photon is scattered by a pair of colliding hydrogen atoms leaving a hydrogen molecule that is stabilized by the transfer of kinetic and binding energy to the photon. We use a formulation for calculating the photon scattering cross section in which an infinite sum of matrix elements over rovibrational levels of dipole accessible electronic states is replaced by a single matrix element of a Green's function. We evaluate this matrix element by using a discrete variable representation.

8.
J Chem Phys ; 123(7): 074310, 2005 Aug 15.
Artículo en Inglés | MEDLINE | ID: mdl-16229573

RESUMEN

High-level ab initio potential-energy curves and transition dipole moments for the OH X 2Pi, 2 2Pi, 1 2Sigma-, D 2Sigma-, 3 2Sigma-, A 2Sigma+, B 2Sigma+, 1 2Delta, 1 4Sigma-, and 1 4Pi states are computed. The results are used to estimate the (2+1) resonance enhanced multiphoton ionization spectrum for the (D,3)2Sigma-(upsilon')<--2hnuX 2Piupsilon") transitions, which are compared with experiments by Greenslade et al. [see M. E. Greenslade, M. I. Lester, D. C. Radenovic, J. A. van Roij, and D. H. Parker, J. Chem. Phys. 123, 074309 (2005), preceeding paper]. We use the discrete variable representation-absorbing boundary condition method to incorporate the effect of the dissociative intermediate 1 2Sigma- state. We obtain qualitative agreement with experiment for the line strengths. Radiative and predissociative decay rates of the Rydberg (D,3)2Sigma- states of OH and OD were computed, including spin-orbit coupling effects and the effect of spin-electronic and gyroscopic coupling. We show that the lifetime of the Rydberg 2Sigma- states for rotationally cold molecules is limited mainly by predissociation caused by spin-orbit coupling.

9.
Phys Rev Lett ; 95(1): 013003, 2005 Jul 01.
Artículo en Inglés | MEDLINE | ID: mdl-16090612

RESUMEN

Neutral molecules, isolated in the gas phase, can be prepared in a long-lived excited state and stored in a trap. The long observation time afforded by the trap can then be exploited to measure the radiative lifetime of this state by monitoring the temporal decay of the population in the trap. This method is demonstrated here and used to benchmark the Einstein A coefficients in the Meinel system of OH. A pulsed beam of vibrationally excited OH radicals is Stark decelerated and loaded into an electrostatic quadrupole trap. The radiative lifetime of the upper Lamda-doublet component of the Chi2Pi3/2, v=1, J=3/2 level is determined as 59.0+/-2.0 ms, in good agreement with the calculated value of 58.0+/-1.0 ms.

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