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1.
Phys Rev Lett ; 84(17): 3962-5, 2000 Apr 24.
Artículo en Inglés | MEDLINE | ID: mdl-11019250

RESUMEN

The space group of alpha(')-NaV2O5 turns below T(c) = 34 K from Pmmn with all V sites equivalent, into Fmm2 with three independent vanadium sites per layer. This is incompatible with models of charge ordering into V4+ and V5+. Our structure determination indicates that the phase transition consists of a charge ordering with three distinct valence states, formally V4+, V4.5+, and V5+. The singlet formation is not associated with dimerization on the spin ladder, but with the formation of spin clusters. Finally, we ascribe the quadrupling of the c axis to the large polarizability of the V2O5 skeleton.

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Phys Rev B Condens Matter ; 46(5): 2750-2757, 1992 Aug 01.
Artículo en Inglés | MEDLINE | ID: mdl-10003961
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