RESUMEN
Aeromaterials represent a class of increasingly attractive materials for various applications. Among them, aero-ZnS has been produced by hydride vapor phase epitaxy on sacrificial ZnO templates consisting of networks of microtetrapods and has been proposed for microfluidic applications. In this paper, a cost-effective technological approach is proposed for the fabrication of aero-ZnS by using physical vapor transport with Sn2S3 crystals and networks of ZnO microtetrapods as precursors. The morphology of the produced material is investigated by scanning electron microscopy (SEM), while its crystalline and optical qualities are assessed by X-ray diffraction (XRD) analysis and photoluminescence (PL) spectroscopy, respectively. We demonstrate possibilities for controlling the composition and the crystallographic phase content of the prepared aerogels by the duration of the technological procedure. A scheme of deep energy levels and electronic transitions in the ZnS skeleton of the aeromaterial was deduced from the PL analysis, suggesting that the produced aerogel is a potential candidate for photocatalytic and sensor applications.
RESUMEN
A series of Zn1-xMgxO thin films with x ranging from 0 to 0.8 were prepared by spin coating and aerosol spray pyrolysis deposition on Si and quartz substrates. The morphology, composition, nano-crystalline structure, and optical and vibration properties of the prepared films were studied using scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), X-ray diffraction (XRD), and optical and Raman scattering spectroscopy. The optimum conditions of the thermal treatment of samples prepared by spin coating were determined from the point of view of film crystallinity. The content of crystalline phases in films and values of the optical band gap of these phases were determined as a function of the chemical composition. We developed heterostructure photodetectors based on the prepared films and demonstrated their operation in the injection photodiode mode at forward biases. A device design based on two Zn1-xMgxO thin films with different x values was proposed for extending the operational forward bias range and improving its responsivity, detectivity, and selectivity to UV radiation.
RESUMEN
The optical anisotropy of the Sb2Se3 crystals was investigated at 300 and 11 K. Excitonic features of four excitons (A, B, C, and D) were observed in the optical spectra of the Sb2Se3 single crystals and in the photoelectric spectra of the Me-Sb2Se3 structures. The exciton parameters, such as the ground (n = 1) and excited (n = 2) state positions and the binding energy (Ry), were determined. The effective mass of the electrons at the bottom of the conduction band (m c * = 0.67m 0) as well as the holes at the four top valence bands (m v1 * = 3.32m 0, m v2 * = 3.83m 0, m v3 * = 3.23m 0 and m v4 * = 3.23m 0) were calculated in the Ð-point of the Brillouin zone. The magnitude of the valence band splitting V1-V2 due to the spin-orbit interaction (Δso = 35 meV) and the crystal field (Δcf = 13 meV) were estimated in the Brillouin zone center. The energy splitting between the bands V3-V4 was 191 meV. The identified features were discussed based on both the theoretically calculated energy band structure and the excitonic band symmetry in the Brillouin zone (k = 0) for crystals with an orthorhombic symmetry (Ð nma). The photoelectric properties of the Me-Sb2S3 structures were investigated in the spectral range 1-1.8 eV under E||c and E⟂c polarization conditions and at different applied voltages.