RESUMEN

A novel composite material (nZVI/UiO-66) of nanoscale zero-valent iron (nZVI) with a functionalized metal-organic framework was synthesized by this study via a coprecipitation method, which was used for the efficient removal of U(VI) in the aqueous solution. The nZVI/UiO-66 had an excellent removal capacity of 404.86 mg g-1 with an initial U(VI) concentration of 80 mg L-1, 313 K and pH = 6. The transmission electron microscopy (TEM) revealed that nZVI particles were inhomogeneously distributed on the surface of UiO-66. The analysis by the X-ray diffraction (XRD) has further illustrated that the introduction of nZVI did not change the structure of UiO-66. The adsorption process closely followed the pseudo-second-order kinetic and the Freundlich isotherm model. The removal process of U(VI) by nZVI/UiO-66 was spontaneous and endothermic. Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS) analyses have illustrated that the mechanism was mainly related to adsorption of U(VI) from UiO-66 and reduction of U(VI) by nZVI. The Zr-O bonds were shown to play a vital role in the uranium removal. nZVI/UiO-66 could be recycled. The uptake rate could be maintained at around 80% after 5 cycles of use. Therefore, these results manifested that the nZVI/UiO-66 is a promising sorbent for the efficient and selective removal of U(VI) in radioactive wastewaters.

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RESUMEN

In this work, the thermo-sensitive materials N-isopropylacrylamide (NIPAM) and acrylic acid (AA) were crosslinked with carboxymethyl cellulose (CMC) (CMC/P (NIPAM-co-AA)) via a free radical polymerization method for the removal of U(VI) from aqueous solution. The L16 (45) orthogonal experiments were designed for the optimization of the synthesis condition. The chemical structures of the crosslinking hydrogel were confirmed by FTIR spectroscopy. The microstructural analyses were conducted though scanning electron microscopy (SEM) to show the pore structure of the hydrogel. The adsorption performance of the CMC/P (NIPAM-co-AA) hydrogel for the uptake of U(VI) from simulated wastewater was also investigated. The adsorption reached equilibrium within 1 h. Under the reaction of pH = 6 and a temperature of 298 K, an initial concentration of U(VI) of 5 mg·L-1, and 10 mg of the CMC/P(NIPAM-co-AA) hydrogel, the maximum adsorption capacity was 14.69 mg g-1. The kinetics fitted perfectly with the pseudo-second-order model, and the isotherms for the composite hydrogel adsorption of U(VI) was in accordance with the Langmuir model. The chemical modification confirmed that the acylamino group played an important role in uranium adsorption. The desorption and reusability study revealed that the resolution rate was still available at approximately 77.74% after five alternate heating cycles at 20 and 50 °C of adsorption-desorption.

RESUMEN

Dust devils are common but meteorologically unique phenomena on Earth and on Mars. The phenomenon produces a vertical vortex motion in the atmosphere boundary layer and often occurs in hot desert regions, especially in the afternoons from late spring to early summer. Dust devils usually contain abundant wind energy, for example, a maximum swirling wind velocity of up to 25 m/s, with a 15 m/s maximum vertical velocity and 5 m/s maximum near-surface horizontal velocity can be formed. The occurrences of dust devils cannot be used for energy generation because these are generally random and short-lived. Here, a concept of sustained dust-devil-like whirlwind is proposed for the energy generation. A prototype of a circular shed with pre-rotation vanes has been devised to generate the whirlwind flow by heating the air inflow into the circular shed. The pre-rotation vanes can provide the air inflow with angular momentum. The results of numerical simulations and experiment illustrate a promising potential of the circular shed for generating swirling wind energy via the collection of low-temperature solar energy.

RESUMEN

Triboelectric charging is common in desert sandstorms and dust devils on Earth; however, it remains poorly understood. Here we show a charging mechanism of sands with the adsorbed water on micro-porous surface in wind-blown sand based on the fact that water content is universal but usually a minor component in most particle systems. The triboelectric charging could be resulted due to the different mobility of H(+)/OH(-) between the contacting sands with a temperature difference. Computational fluid dynamics (CFD) and discrete element method (DEM) were used to demonstrate the dynamics of the sand charging. The numerically simulated charge-to-mass ratios of sands and electric field strength established in wind tunnel agreed well with the experimental data. The charging mechanism could provide an explanation for the charging process of all identical granular systems with water content, including Martian dust devils, wind-blown snow, even powder electrification in industrial processes.