RESUMEN
The sorption properties of Na-modified Ukrainian Transcarpathian clinoptilolite towards neodymium aqueous solutions under dynamic conditions have been investigated. The sorption capacity of the Na-from of Transcarpathian clinoptilolite towards Nd(III) significantly depends on the concentration of neodymium salt, the pH of the solution, and the heat treatment temperature of the sorbent. Nd(III) is most efficiently sorbed from slightly alkaline solutions (pH 8.5), mainly by adsorption of neutral hydrolyzed forms of Nd(OH)3 on the surface of Na-clinoptilolite samples preheated at 75 °C. During the passage of an Nd(III) solution with a concentration of 1 µg mL-1 through the sorbent at a rate of 3 mL min-1 under optimal conditions, the sorption capacity of Na-clinoptilolite is 7.2 mg g-1, which is in 4 and 2.3 times higher than that of natural and acid-modified forms of this zeolite. It is shown that under the experimental conditions with an increase in the flow rate, the thickness of the stationary surface layer decreases, which leads to a decrease in the sorption capacity of Na-clinoptilolite. The best Nd(III) desorbents are solutions of mineral acids and acidified solutions of alkali metal salts (except NaCl), which provide 93-98 % extraction of lanthanide from the zeolite matrix. The method for neodymium trace amounts preconcentration from aqueous solutions in a solid-phase extraction mode with a further determination of this rare earth element by a spectrophotometric method was developed. The detection limit of this method is 0.75 ng mL-1 and the linearity was evaluated in the range of 2.5-500 ng mL-1.
RESUMEN
The influence of concentration of nonionic TRITON X-100 and anionic ATLAS G-3300 surfactants, and pH of medium on the size and zeta-potential of TiO2 particles in the water suspensions has been studied. Suspensions have been prepared by mixing of the titanium dioxide in the suitable mediums at 10 min and 6 h correspondingly. It was established, that the duration of mixing of the suspensions has an essential influence on the dependence of zeta-potential and size of particles versus concentration of surfactant. However, the duration of mixing does not influence the dependence of electrical conductivity and pH of the suspensions on concentration of surfactant. It is shown that anionic ATLAS G-3300 surfactant is more effective stabilizator of aqueous suspensions of titanium dioxide, than nonionic surfactants of TRITON X-100. It is found that hydrophobic interaction has important role in the processes of stabilization of suspensions for nonionic surfactant, and for anionic surfactant--moving of psi(delta)-planes into solution's depth.