1.
Chem Commun (Camb)
; 56(58): 8035-8038, 2020 Jul 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-32691780
RESUMEN
Hydride-bridged transition metal complexes have been found to serve as suitable precursors for the activation of small molecules without the use of reducing agents. In this study, we synthesized a dinuclear Mo2H8 complex supported by bulky C5H2tBu3 (Cp) ligands, Cp2Mo2H8 (1), from the reaction of CpMoCl4 with KC8 under H2. The hydrides of complex 1 can be replaced with benzene at 60 °C to afford a µ-benzene complex Cp2Mo2H2(µ-C6H6) (2).