RESUMEN
As a common flexible sensing device, gels are widely used in electronic skin, personalized health monitoring, and smart manufacturing. However, gel suffers from temperature sensitivity, long polymerization times or thickness limitations. Deep eutectic solvents (DESs) have abundant hydrogen bond networks and low saturated vapor pressure, which can accelerate the frontal polymerization of ionic gels, and overcome the temperature sensitivity problem. Here, we showed how choline chloride (ChCl)-glycerol (Gly) DES can be used to create ionic gels with different properties and functions by combining them with different monomers (acrylamide (AM), acrylic acid (AA) and itaconic acid (IA)). Subsequently, we revealed the rapid gelation mechanism of PAM-ChCl-Gly ionic gel from multiple perspectives by density functional theory and molecular dynamics simulation, which was then applied to flexible sensing. The experimental results showed that the PAM-ChCl-Gly ionic gel had excellent tensile properties, high transparency, self-adhesion and stability. In addition, its gelation time was only 90 s without heating. ChCl-Gly DES offered a plentiful and stable hydrogen bonding network. PAM-ChCl-Gly ionic gels can detect tiny pressure and strain changes, making them suitable for flexible sensing. This greatly enriched the theoretical research foundation of DES-based ionic gels and broadened their application areas.
RESUMEN
Lignin, as the aromatic polymer in the world, has attracted more attention because of rich functional groups. In this study, lignin/ZnO composites was prepared by a simple one-pot method rely on urea and ZnCl2-deep eutectic solvent (U/ZnCl2-DES) as solvent and raw material. Through molecular dynamics simulation, the interaction mechanism between lignin functional groups and DES was clarified, and it was blended with waterborne polyurethane (WPU) to form a film, while the feasibility of its application in ultraviolet shielding was evaluated. The results showed that lignin /ZnO composites with excellent ultraviolet shielding properties were successfully prepared. Compared with lignosulfonate (SL), enzymatic hydrolysis lignin (EHL) was easier to combine with ZnO, which was benefit to prepare lignin/ZnO composites. When the addition of EHL/ZnO-N12.5 complex was 1.5 %, the WPU film prepared has good mechanical properties (elongation at break was 25.53 %, tensile strength was 1422 kPa), good light transmission and ultraviolet shielding.
Asunto(s)
Lignina , Óxido de Zinc , Solventes , Disolventes Eutécticos Profundos , HidrólisisRESUMEN
Modifying biodegradable poly (butylene adipate-co-terephthalate) (PBAT) plastic with inorganic fillers is critical for improving its overall performance, lowering the costs, and expanding its application scope. The chemical modification method for the inorganic filler determines the application performance of PBAT composites. In this work, gas-solid fluidization method was developed as a simple, efficient, and scalable strategy for chemically modifying CaCO3 filler. The modified CaCO3 filler was mixed with PBAT and melt extruded to prepare biodegradable PBAT/CaCO3 composites. The characterization results show that gas-solid fluidization method combines the traditional wet modification method's excellent modification effect with the scalability of the traditional dry modification method. The effects of modification methods and amount of CaCO3 filling on the crystallinity, mechanical, and rheological properties of PBAT/CaCO3 composites were compared. The results demonstrated that PBAT/CaCO3 composites containing 30% gas-solid fluidization modified CaCO3 could still maintain excellent overall performance. As a result, this work provides a simple, efficient, and scalable method for chemically modifying inorganic fillers and preparing biodegradable composites.